4.1.1 Calibrated Gas Mixtures Technique
Gas product suppliers, such as Matheson Gas Products and Scott Specialty Gases, can supply high-
pressure cylinders containing calibrated mixtures of tracer gas and air. Purchase several different
calibrated gas mixtures, regulators, a flow meter, and a needle valve. The calibrated gas mixtures can be
delivered directly to the sensor inlet via a regulator and flow control needle valve. The flow meter, a
simple rotameter is sufficient, allows the calibration flow rate to be set at 1.1 times the sensor sample
flow rate. Perform the following procedure to calibrate the sensor.
1. Turn on the sensor and allow it to warm up.
2. Deliver zero air (air with very low concentrations of hydrocarbons in it) to the sensor inlet needle
at a flow rate 1.1 times the sensor suction flow rate.
3. Zero the sensor.
4. Record the output voltage.
5. Deliver a low gas concentration to the sensor and record the output voltage.
6. Repeat step (5) with successively higher calibration gas concentrations. It is recommended to
calibrate the sensor over the expected range of concentrations expected during the experiment.
For more accurate calibration we suggest a minimum of 4 data points be collected (including the
zero value).
7. Plot the voltage versus concentration and fit a 2nd order polynomial to the data. To eliminate
the zero offset we suggest that the zero-output voltage be subtracted from all measurements
prior to fitting the polynomial.
4.1.2 Simple Gas Mixing Technique
When a multipoint calibration of more than 3 or 4 points is required then it is more cost effective to
create your own concentrations by diluting calibrated gas mixtures with zero air. A simple dilution system
can be constructed using a gas proportioning rotameter system (commercially available from Omega,
Matheson Gas Products, etc.) and selected calibrated gas concentrations. A gas proportioning rotameter
consists of two flow meters, two needle valves and a mixing tube. The calibration is performed by mixing
zero air with a calibrated gas mixture to produce any desired concentration between zero concentration
and the concentration of the calibrated mixture. For example, mixing zero air and 100 ppm tracer in air
will allow you to generate any concentration between 0 and 100 ppm (within the tolerance of the
rotameters). At the factory we use three calibrated gas mixtures plus zero air to perform calibrations.
The concentrations we use are 10, 100 and 1000ppm propylene in zero air. Due to accuracy limitations of
the rotameters, we typically don’t attempt to reduce the concentration to less than 20% of the nominal
concentrations (i.e., for the 100ppm cylinder we would set concentrations in the range of 20ppm to
100ppm during a calibration). For concentrations less than 20ppm we would switch to the 10ppm
mixture. Likewise for concentrations above 100ppm, we would use the 1000ppm mixture in the range of
200ppm to 1000ppm. Note that the total flow must be maintained at approximately 1.1 times the inlet
flow rate of the sensor. Also note that this method is a volumetric mixing operation and therefore the
pressures and temperatures of the two gases must be the same in order to maintain accuracy. Use the
calibration procedure outlined in section 4.1.1.