Maxa Calido 110 User manual

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WALL‐MOUNTEDDOMESTICHOTWATERHEATPUMP

WITHSTORAGETANK

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USER’S‐INSTALLER’SMANUAL

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Model

CALIDO110

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Thismanualhasbeencreatedforinformativepurpose.Thecompanydeclinesanyresponsibilityfortheresultsofanyprojectingoranyinstallationbasedontheexplanationsand/oronthetechnicalspecifications

providedinthismanual.Itisbesidesforbiddenthereproductionunderanyformofthetextsandofthefigurescontainedinthismanual.

"Thismanualisatranslationfromtheofficialitalianlanguageversion.ForreasonsofenvironmentalrespecttheCompanywillnotprovidethehardcopyintheoriginallanguagewhichcouldbedirectlyrequestedor

downloadedfromtheCompanywebsiteatanytime.Incaseofanydispute,theoriginallanguagemanualwillbethetrustedone".

CALIDOSanitarywaterheatpump

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0210‐2020A.R.A.R.Updateoftechnicaldataandproductfiche

0101‐2020A.R.A.R.Phonenumberaddedonthedeclarationofconformity

0004‐2019AL.BA.R.Firstrelease

RevDateEditedbyApprovedbyNotes

Catalogo/Catalogue/Katalog/Catalogue

MUI01110L8420‐02

Serie/Series/Serie/Serie/Série

SANITARYWATERHEATPUMP

Possiblewastedelectricalorelectronicdevices/productsshouldnotbelocatedtogetherwithnormaldomesticwaste,butdisposedaccordingtothe

currentWEEElawincompliancewiththeEuropeanDirective2012/19/UE.PleaseinformyourselfatyourlocalAdministrationoratyourresellerincase

theproductwillbereplacedwithasimilarone.

CALIDOSanitarywaterheatpump

ADVANTIXSPA‐ViaSanGiuseppeLavoratore,24‐Loc.LaMacia‐37040‐Arcole‐Verona‐Italy‐e‐mail:[email protected]t–Tel.+390457636585

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DICHIARAZIONEDICONFORMITÀ

DECLARATIONOFCONFORMITY

UEBEREINSTIMMUNGSERKLAERUNG

DECLARATIONDECONFORMITE

DECLARACIÒNDEHOMOLOGACIÒN 

DICHIARIAMOSOTTOLANOSTRASOLARESPONSABILITÀCHELAMACCHINAWEDECLARE

UNDEROURSOLERESPONSABILITYTHATTHEMACHINE

WIRERKLÄRENAUFUNSEREALLEINIGEVERANTWORTUNG,DAßDIEMASCHINENOUSDECLARONS

SOUSNOTRESEULERESPONSABILITEQUELAMACHINE

ELFABRICANTEDECLARABAJOSUEXCLUSIVARESPONSABILIDADQUELAMÁQUINA

DESCRIZIONE

DESCRIPTION

BESCHREIBUNG

DESCRIPTION

DESCRIPCION

PompadicaloreperACSconserbatoiointegrato

Heatingpumpforhotsanitarywaterproductionwithintegratedtank

Bombadecalorparalaproducciòndeaguacalientecontanqueintegrada

Pompeàchaleurpourproductioneauchaudesanitaireavecréservoirdestockageintégré

WärmepumpefürWarmwasserzeugungmitintegrierteSpeicher



ANNODlFABBRICAZIONE/YEAROFMANUFACTUREBAUJAHR/    MATRICOLA/SERIALNo./LAUFENDENUMMER

ANNEEDEFABRICATION/AÑODEFABRICACIÓNNUMÉRODESÉRIE/NÚMERODESERIE

2020

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MODELLO/MODEL/MODELL/MODÈLE/MODELO



CALIDO110

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- RISULTAINCONFORMITÀCONQUANTOPREVISTODALLESEGUENTIDIRETTIVECOMUNITARIEECONLARELATIVALEGISLAZIONE

NAZIONALEDIRECEPIMENTO:2014/30/UE,2014/35/UE

EVENTUALIALTREDIRETTIVEEUROPEEENORMEARMONIZZATEAPPLICATEALL’ATTREZZATURA:EMC2004/108/EC;IEC60335‐2‐

21;IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11.

- ISINCOMPLIANCEWITHTHEFOLLOWINGEECDIRECTIVESANDTHERELEVANTNATIONALGRANTINGREGULATIONSINFORCE:

2014/30/UE,2014/35/UE

OTHERSEUROPEANDIRECTIVESANDHARMONIZEDSTANDARDSAPPLIEDTOTHEEQUIPMENT:EMC2004/108/EC;IEC60335‐2‐21;

IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11.

- ESTCONFORMEAVECLESDIRECTIVESCEESUIVANTESETLESLOISNATIONALESD'ACCUEIL2014/30/UE,2014/35/UE

AUTRESÉVENTUELLESDIRECTIVESEUROPÉENNESETNORMESHARMONISÉESAPPLIQUÉESÀL'ÉQUIPEMENT:EMC2004/108/EC;

IEC60335‐2‐21;IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11.

- ESTÀHOMOLOGADOENCUANTOPREVISTODELASSIGUENTESDIRECTRICESCOMUNITAREASYCONLARELATIVALEGISLACIONNACIONAL

DERECEPCIÒN:2014/30/UE,2014/35/UE

OTRASDIRECTIVASEUROPEASYNORMASARMONIZADASAPLICADASALEQUIPAMIENTO:EMC2004/108/EC;IEC60335‐2‐21; 

IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11.

- NACHDEMCEE‐NORMEN,SOWIEDERENTSPRECHENDENANGEWENDETSTAATSGESEZTGEBUNG,DASSHEISST:2014/30/UE,2014/35/UE

EVENTUELLEWEITEREFÜRDASGERÄTANGEWANDTEEUROPÄISCHERICHTLINIENUNDHARMONISIERTENORMEN:EMC2004/108/EC;

IEC60335‐2‐21;IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11.

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NOME / NAME / VORNAME / NOM / NOMBRE PAOLO

COGNOME / SURNAME / NACHNAME / PRENOM / APELLIDO FERROLI

POSIZIONE / COMPANY POSITION / POSITION / FONCTION / POSICION RESP. TECNICO

ARCOLE, 01.2019

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CODICEABARRE

BARCODE

CALIDOSanitarywaterheatpump

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INDEX

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1PURPOSESANDCONTENTSOFTHEMANUAL......................................................................................................................6

1.1CONSERVATIONOFTHEMANUAL..........................................................................................................................................6

1.2GRAPHICSYMBOLSUSEDINTHEMANUAL............................................................................................................................6

2SAFETYLAWS.....................................................................................................................................................................6

3PERMITTEDUSE.................................................................................................................................................................6

4GENERALSAFETYGUIDELINES............................................................................................................................................7

4.1WORKERS’HEALTHANDSAFETY............................................................................................................................................7

4.2PERSONALSAFETYEQUIPMENTS...........................................................................................................................................7

4.3SAFETYSYMBOLS...................................................................................................................................................................7

4.4REFRIGERANTSAFETYDATASHEET........................................................................................................................................8

5GENERALCHARACTERISTICS..............................................................................................................................................11

5.1FLEXIBILITYANDBENEFITSOFCALIDOINSTALLATION.........................................................................................................11

5.2COMPACTDESIGN................................................................................................................................................................11

5.3AVAILABLEACCESSORIES.....................................................................................................................................................11

6TECHNICALFEATURES.......................................................................................................................................................11

7ITEMSINSIDETHEPACKING‐BOX.......................................................................................................................................12

8OVERVIEWOFTHEUNIT....................................................................................................................................................13

8.1HYDRAULICCONNECTIONS..................................................................................................................................................13

8.2DIMENSIONS........................................................................................................................................................................13

8.3ACCESSTOTHEFRONTPART................................................................................................................................................14

8.4ACCESSTOTHEBOTTOMPART............................................................................................................................................14

8.5HOWTOREPLACETHEMAGNESIUMANODE.......................................................................................................................14

8.6REGULATIONTHERMOSTATOFTHEELECTRICHEATER........................................................................................................15

8.7SCHEMATICOVERVIEWOFTHEWATERANDGASCIRCUIT..................................................................................................15

9INSTALLATION...................................................................................................................................................................15

9.1GENERALITY.........................................................................................................................................................................15

9.2SAFETYINSTRUCTIONS.........................................................................................................................................................15

9.2.1Warnings......................................................................................................................................................................16

9.2.2Cautions........................................................................................................................................................................16

9.3HANDLINGOFTHEUNIT.......................................................................................................................................................16

9.3.1Handlingoftheunitwithforklift..................................................................................................................................16

9.3.2Manualhandlingoftheunit.........................................................................................................................................16

9.4WALLMOUNTING................................................................................................................................................................17

9.5REQUIREDSERVICESPACE....................................................................................................................................................18

9.6INSTALLATIONOVERVIEW...................................................................................................................................................19

9.7HYDRAULICCONNECTIONS..................................................................................................................................................20

9.7.1Waterconnections.......................................................................................................................................................20

9.7.2Waterloading...............................................................................................................................................................20

9.7.3Unloadofwaterfromthetank.....................................................................................................................................21

9.8ELECTRICALCONNECTIONS..................................................................................................................................................21

10STARTUP..........................................................................................................................................................................21

11APPLIANCEOPERATION.....................................................................................................................................................22

11.1USERINTERFACE..................................................................................................................................................................22

11.2OPERATION..........................................................................................................................................................................22

11.3LCDICONS..............................................................................................................................................................................24

11.4MAINLOGICSOFOPERATION..............................................................................................................................................24

11.4.1Automode....................................................................................................................................................................25

11.4.2Greenmode..................................................................................................................................................................25

11.4.3Boostmode...................................................................................................................................................................25

11.4.4E‐heatermode..............................................................................................................................................................25

CALIDOSanitarywaterheatpump

11.4.5FanMode.....................................................................................................................................................................25

11.4.6Operationicons............................................................................................................................................................25

11.5AUXILIARYCONTROLLOGICS...............................................................................................................................................25

11.5.1Thermalprotections.....................................................................................................................................................25

11.5.2Disinfectionweeklycycle(Anti‐legionella)...................................................................................................................25

11.5.3ON/OFFcontact............................................................................................................................................................26

11.5.4Contactforphotovoltaicplantintegration...................................................................................................................27

11.5.5Defrostingcycle............................................................................................................................................................27

11.5.6Anti‐freezeprotection..................................................................................................................................................27

11.6PARAMETERS’CONTROLANDSETTING...............................................................................................................................28

11.7MALFUNCTIONINGOFTHEUNITANDERRORCODES..........................................................................................................29

12MAINTENANCEANDPERIODICALCONTROLS.....................................................................................................................30

12.1ENVIRONMENTALPROTECTION...........................................................................................................................................30

13TROUBLESHOOTING..........................................................................................................................................................31

14DISPOSALREQUIREMENTS................................................................................................................................................31

15TECHNICALCHARACTERISTICS...........................................................................................................................................32

16WORKINGLIMITSOFHEATPUMP.....................................................................................................................................33

17WIRINGDIAGRAM............................................................................................................................................................34

18FICHEACCORDINGTOREGULATION(EU)NO812/2013......................................................................................................35

19TECHNICALPARAMETERSACCORDINGTOREGULATION(EU)NO814/2013.......................................................................35

CALIDOSanitarywaterheatpump

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Thismanualcollectsallrelevantinformationfortheuseoftheapparatusinbestwayandunderoperators’safetyconditions.

1PURPOSESANDCONTENTSOFTHEMANUAL

Thismanualprovidestherequiredinformationasfortheinstallation,operationandmaintenanceofCALIDOunits.Itisaddressed

tothemachine’soperatorsenablingthemtousetheequipmentefficiently,evenifwithouthavinganypreviousspecific

knowledgeoftheapparatus.

Thismanualdescribesthecharacteristicsoftheequipmentwhenitisbeingputonthemarket;therefore,itmaynotcapturelater

technologicalimprovementsintroducedbythecompanyaspartofitsconstantendeavourtoenhancetheperformance,

ergonomics,safetyandfunctionalityofitsproducts.

Thecompany,therefore,isnotconstrainedtoupdatethemanualsforpreviousversionsofmachines.

It’srecommendedthattotheusertofollowtheinstructionscontainedinthisbooklet,especiallythoseconcerningthesafetyand

routinemaintenance.

1.1 CONSERVATIONOFTHEMANUAL

Themanualhastobealwayskeptasreferenceoftheappliance.Ithastobestoredinasafeplace,awayfromthedustand

moisture.Ithastobeaccessibletoalluserswhoshallconsultitanytimetheyareindoubtonhowtooperatetheequipment.

Thecompanyreservestherighttomodifyitsproductsandrelatedmanualswithoutnecessarilyupdatingpreviousversionsofthe

referencematerial.Itassumesnoresponsibilityforanyinaccuraciesinthemanual,ifduetoprintingortranscription.

Thecustomershallstoreanyupdatedcopyofthemanualorpartsofitdeliveredbythemanufacturerasanattachmenttothis

manual.

Thecompanyisavailabletogiveanydetailedinformationaboutthismanualandtoprovideinformationregardingtheuseandthe

maintenanceofitsownappliances.

1.2 GRAPHICSYMBOLSUSEDINTHEMANUAL

Indicatesoperationsthatcanbedangerousforpeopleand/ordisruptthecorrectoperationoftheequipment.



Indicatesprohibitedoperations.



Indicatesimportantinformationthattheoperatorhastofollowinordertoguaranteethecorrectoperationofthe

equipmentincompletesafety.Itindicatesalsogeneralnotes.

2SAFETYLAWS

CALIDOunitshavebeendesignedincompliancewiththefollowingDirectivesandHarmonisedNorms:

CommunityDirectives:2014/30/UE,2014/35/UE;

Norms:EMC2004/108/EC;IEC60335‐2‐21;IEC60335‐2‐40;EN55014‐1;EN61000‐3‐2;EN61000‐3‐11;

3PERMITTEDUSE

Thecompanyexcludesanycontractualandno‐contractualliabilityfordamagescausedtopersons,animalsorthings,by

incorrectinstallation,adjustmentandmaintenance,improperuseorapartialorsuperficialreadingoftheinformations

containedinthismanual.

Theseunitshavebeendesignedforwaterheating.Adifferentapplication,unlessexpresslyauthorizedbythemanufacturer,is

tobeconsideredimproperandthereforenotallowed.

Thelocationandthehydraulicandelectricplantshouldbedeterminedbythesystemdesignerandmusttakeintoaccount

boththepurelytechnicalneedsasanyapplicablelocallegislationsandspecificauthorizations.

Theexecutionofallworkmustbeperformedbyqualifiedandexperiencedpersonnel,competentintheexistingrulesin

differentcountries

CALIDOSanitarywaterheatpump

4GENERALSAFETYGUIDELINES

Beforebeginningtooperateonthe“CALIDO”units,everyuserhastobeperfectlyknowledgeableaboutthefunctionsofthe

equipmentanditscontrolsandshouldreadandunderstoodtheinformationlistedinthismanual.



It’sstrictlyforbiddentoremoveand/ortamperwithanysafetydevice.

Donotremovethegrillsonthefanoutletandtopcover.

It’forbiddentheusebychildrenandunassisteddisabledpersons.

Donottouchtheappliancewhenbarefootorwithwetordamppartsofthebody.

Donotpull,detachortwisttheelectricalcablescomingfromtheunit,evenifitisdisconnectedfromthemains

supply.

Donotstandwithyourfeetonthedevice,sitdownand/orleanonanytypeofobject.

Donotsprayorpourwaterdirectlyonthedevice.

Notdisposeof,abandonorleavewithinreachofchildrenpackagingmaterials(cardboard,staples,plasticbags,

etc.).becauseitcanbeapotentialsourceofdanger.



Anyroutineornot‐routinemaintenanceoperationshallbecarriedoutwhentheequipmenthasbeenshutdown,

disconnectedfromelectricpowersources.

Theplasticcovercanberemovedonlybyqualifiedoperators.

Donotputneitheryourhandsnorinsertscrewdrivers,spannersorothertoolsintomovingpartsofthe

equipment.

Theequipmentsupervisorandthemaintenancemanhastoreceivesuitabletrainingfortheperformanceoftheir

tasksinsafety.

Operatorshavetoknowhowtousepersonalprotectivedevicesandhavetoknowtheaccident‐prevention

guidelinescontainedinnationalandinternationallawsandnorms.

4.1 WORKERS’HEALTHANDSAFETY

TheEuropeanCommunityhasadoptedanumberofdirectivesonworkplace’shealthandsafety,whichinclude89/391/CEE,

89/686/CEE,2009/104/CE,86/188/CEEand77/576/CEEdirectives.Everyemployershallimplementsuchprovisionsandensure

thatworkersrespectthem:



Donottamperwithorreplacepartsoftheequipmentwithoutthespecificconsentofthemanufacturer.The

manufacturershallhavenoresponsibilitywhatsoeverincaseofunauthorisedoperations.



Usingcomponents,expendablematerialsorsparepartsthatdonotcorrespondtothoserecommendedbythe

manufacturerand/orlistedinthismanualmaybedangerousfortheoperatorsand/ordamagetheequipment

Theoperator’sworkplacehastobekeptclean,tidyandfreefromobjectsthatmaypreventfreemovements.

Appropriatelightingoftheworkplaceshallbeprovidedsoastoallowtheoperatortocarryouttherequired

operationssafely.Poorortoostronglightingcancauserisks.

Ensurethatworkplacesarealwaysadequatelyventilatedandthataspiratorsareworking,ingoodconditionandin

compliancewiththerequirementsofthelawsinforce.

4.2 PERSONALSAFETYEQUIPMENTS

WhenoperatingandmaintainingtheCALIDOunits,usethefollowingpersonalprotectiveequipments.



Protectiveclothing:Maintenancemenandoperatorshastowearprotectiveclothingthatcomplieswiththebasic

safetyrequirementscurrentlyinforce.Incaseofslipperyfloors,usershavetowearsafetyshoeswithnon‐slipsoles.



Gloves:Duringmaintenanceorcleaningoperationprotectiongloveshavetobeused



Maskandgoggles:Respiratoryprotection(mask)andeyeprotection(goggles)shouldbeusedduring

cleaningandmaintenanceoperations.

4.3 SAFETYSYMBOLS

Theunitfeaturesthefollowingsafetysigns,whichhastobecompliedwith:

Generalhazards



Electricshockhazard



Presenceofmovingorgans



Presenceofsurfacesthatmaycauseinjures

CALIDOSanitarywaterheatpump



4.4 REFRIGERANTSAFETYDATASHEET

ExtractfromthesafetydatasheetinaccordancewithRegulation(EC)No.1907/2006(REACH)withthemodificationofRegulation

(EU)2015/830.

Denomination:R134a(100%,1,1,2‐Tetrafluoroethane).

ReferenceofSDSNotsubjecttoregistrationobligationsasdownstreamusersofsubstances/preparationsalreadyregistered

IDENTIFICATIONOFTHESUBSTANCE/MIXTUREANDOFTHECOMPANY/ENTERPRISE

1.1.Productidentifier

Chemicalname:133

CASnumber:811‐97‐2

CEnumber:212‐377‐0

Indexnumber:‐‐‐

Registrationnumber:01‐2119459374‐33

Chemicalformula:C2H2F4

1.2.Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst

Identifieduses:Refrigerant

HAZARDSIDENTIFICATION

2.1.Classificationofsubstanceormixture

Regulation(EC)No1272/2008calssification

PhysicalhazardsGasesunderpressure:LiquefiedgasH280

IndicationsofdangerMayexplodeifheated

HealthhazardsAsphyxia

Rapidevaporationcancausefrostbite

Maycausecardiacarrhythmia.

FIRSTAIDMEASURES

4.1.Descriptionoffirstaidmeasures

Generalinformation:Donotgiveanythingtoanunconsciousperson.Getmedicalassistance.

Inhalation:Movethevictimtoanuncontaminatedareawearingtheself‐containedbreathingapparatus.

Keepthepatientrelaxedandwarm.

Proceedwithartificialrespirationifbreathingstops.

Adrenalineandsimilarsubstancesshouldnotbeadministered.

Eyecontact:Rinsecarefullywithplentyofwaterforatleast15minutesandconsultadoctor.

Ingestion:Theingestionisconsideredanunlikelymodeofexposure.

Skincontact:Incaseoffreezingcold,spraywithwaterforatleast15minutes.

Applyasterilegauze.

Takeoffcontaminatedclothingimmediately.

4.2.Mostimportantsymptomsandeffects,bothacuteanddelayed

Highconcentrationcancauseasphyxia.Symptomsmayincludelossofmobilityand/orconsciousness.Victimsmaynotbeawareofasphyxia.

Lowconcentrationcanhaveanarcoticeffect.Thesymptomsmayincludedizziness,headache,nauseaandlossofcoordination.

FIREPREVENTIONMEASURES

5.1.Fireextinguishingmedia

Suitableextinguishingmedia:Waterspray.

Unsuitableextinguishingmedia:Donotusewaterjetstoextinguishthefire.

5.2.Specialhazardsfromthesubstanceormixture

Specifichazards:Theexposuretoflamescancausetheunittobreakorexplodeduetoincreasedpressure.

Hazardouscombustionproducts:

Intheeventofafire,thefollowingproductsmayoriginateduetothermaldecomposition:

Carbonmonoxide

Hydrofluoricacid

Carbonylfluoride

5.3.Recommendationsforfirefighters

Specificmethods:

Coordinatefirefightingaccordingtothesurroundingfire.Exposuretoflamesandheatcancausetheunittobreak.Cooldownwithashowerof

waterfromaprotectedposition.Donotspillcontaminatedfirewaterintothesewagesystem.

Ifpossiblestopproductleakage.

Ifpossible,usewaterspraytoremovethefumes.

Specialprotectiveequipmentfor

firefighters:

Useself‐containedbreathingapparatus.

Standardprotectiveclothingandprotectiveequipment(breathingapparatus)forfirefighters.

EN137‐Respiratoryprotectivedevices‐Self‐containedopen‐circuitcompressedairbreathingapparatuswithfullfacemask.

EN469:Protectiveclothingforfirefighters.EN659:Protectiveglovesforfirefighters.

MEASURESINCASEOFACCIDENTALLEAKAGE

6.1.Personalprecautions,protectiveequipmentandemergencyprocedures

Individualprecautions:

Trytostoptheleakage.

Evacuatethearea.

Useself‐containedbreathingapparatustoenterintotheaffectedareaifthereisnoevidenceofbreathableatmosphere.

Ensureadequateventilation.

Prevententryintosewers,basements,excavationsandareaswhereaccumulationcanbedangerous.

Operateaccordingtothelocalemergencyplan.

Stayupwind.

Evacuateciviliansinsecurityareas.

Usepersonalprotectiveequipment.



CALIDOSanitarywaterheatpump

Environmentalprecautions:Volatile

Cleaningmethods:Volatile

HANDLINGANDSTORAGE

7.1.Safe‐handlingprecautions

Safeuseoftheproduct:

Theproductmustbehandledinaccordancewithgoodindustrialhygieneandsafetypractices.

Onlyexperiencedandproperlyinstructedpersonscanmanipulategasesunderpressure.

Donotsmokewhilehandlingtheproduct.

Useonlyspecificequipmentthataresuitablefortheproductandfortheoperatingpressureandtemperature.Incaseofdoubt,pleasecontact

thesupplier.

Donotbreathethegas.

Don’treleasetheproductintheatmosphere.



Youmustensuresufficientairexchangeand/orsuction.

Donotusedirectflameorelectricheatingtoincreaseinternalpressure.

Donotremoveorrenderillegibletheaffixedsupplieridentificationlabels.

Donotundergoanypressuretestwiththeair/HFC‐134amixtures.

Gas‐aircanformacombustiblemixtureatpressureshigherthantheatmosphericonewhenthevolumeratioexceeds60%.

Storage:Keeptheunitawayfromincompatibleproductssuchas:explosive,flammablematerials,Organicperoxide

EXPOSURECONTROL/INDIVIDUALPROTECTION

8.1.Controlparameters

DNEL:Derivedlevelwithouteffect(workers)

Effectsoflong‐term‐systemiceffects,

inhalation14000mg/m³

PNEC=PredictedNoEffectConcentration

Water(softwater)0,1mg/l

Wate(Seawater)0,01mg/l

Aquatic,intermittentreleases1mg/l

Sediment,softwater0,75mg/kgdryweight

PNECformicroorganismsorwastewatertreatmentplant

73mg/l

8.2.Exposurecontrols

Protectionofeyes:

Totalprotectiveglasses.

Protectivegogglesshouldbewornduringtherefillingoperations.

EN166‐Personaleyeprotection

Protectionofhands:Protectiveglovesshouldbewornwhenhandlinggascontainers.

EN388‐Protectiveglovesagainstmechanicalrisks.

Genericprotection:Safetyshoesshouldbewornwhenhandlingcontainers

ENISO20345‐Personalprotectiveequipment‐Safetyfootwear

Respiratoryprotection:Under‐oxygenatedenvironments,abreathingapparatusormaskbreathingairsupplysystemmustbeused.

EN137‐Respiratoryprotectivedevices‐Self‐containedopen‐circuitcompressedairbreathingapparatuswithfullfacemask.

Hygienemeasures:Don’tsmoke.

8.2.3.Environmentalexposurecontrols

Refertolocallegislationforrestrictionstoemissionsintheatmosphere.

Seethesectiononspecificgastreatment/disposalmethods.

PHYSICALANDCHEMICALPROPERTIES

9.1.BasicinformationaboutthePhysicalandChemicalproperties.

Aspet:Physicalstateat20°C/101.3kPa:Colorlessliquefiedgas.

Odor:Similartoether.

Olfactorythreshold:Theolfactorythresholdissubjectiveandinadequatetowarnofoverexposure.

Meltingpoint‐101°C

Boilingpoint:‐26.5°C

Ignitionpoint:Notflammable

Criticaltemperature[°C]101°C

Relativedensity,gas(air=1):3,6

Watersolubility:1930mg/l

9.2.Otherinformation

Gas/vapormoreheavierthanair.Mayaccumulateinconfinedspaces,particularlyatorbelowgroundlevel.

STABILITYANDREACTIVITY

Stability:Noreactivityifusedwiththeappropriateinstructions.

Incompatiblematerials:Humidity.

RefertoISO11114standardforfurtherinformationonmaterialcompatibility.

Hazardousdecompositionproducts:Halogenacids,carbondioxide(CO2),carbonmonoxide,fluorocarbons,carbonylhalides.



Dangerousreactions:Theproductisnotflammableincontactwithairundernormalconditionsoftemperatureandpressure.Underpressurewithairoroxygen,the

mixturecanbecomeflammable.SomemixturesofHCFCorHFCandchlorinemaybecomeflammableorreactiveundercertainconditions.

TOXICOLOGICALINFORMATION

Acutetoxicity:

LC50/inhalation/4hours/onrat>567000ppm/4h

EC5048h‐Daphniamagna>930mg/l

LC5096h‐Fish>450mg/l

Noknowneffectofthisproduct.

Localeffects:ConcentrationssubstantiallyabovetheTLV(1000ppm)valuemaycausenarcoticeffects.

Inhalationofdecompositionproductsinhighconcentrationmaycauseshortnessofbreath(lungoedema)

Long‐termtoxicity:Didnotshowcarcinogenic,teratogenicormutageniceffectsonanimalexperiments.Cancausecardiacarrhythmia.

Limitthresholdforcardiacsensitivity:312975mg/m3.Limitthresholdforanestheticeffects:834600mg/m3



CALIDOSanitarywaterheatpump



ECOLOGICALINFORMATION

Noteasilybiodegradable.

NotconsideredsusceptibletobioaccumulationduetoalowlogKow(logKow<4).

Becauseofitshighvolatility,theproductisunlikelytocausesoilandgroundwaterpollution.

NotclassifiedasPBTorvPvB.

12.6.Otheradverseeffects

EffectsontheozonelayerAny

GlobalWarmingPotential1430

GWP(CO2=1):

EffectsonglobalwarmingIfdischargedinlargequantitiesitcancontributetothegreenhouseeffect

ItcontainsfluorinatedgreenhousegasesregulatedbytheKyotoprotocol

DISPOSALCONSIDERATIONS

13.1.Wastetreatmentmethods



Refertothesuppliergasrecoveryprogram.

Avoiddirectdischargeintotheatmosphere.

Donotdischargewheretheaccumulationcanbedangerous.

Makesurethattheemissionlimitssetbylocalregulationsorindicatedintheauthorizationsarenotexceeded.

Forfurtherinformationregardingthesuitabledisposalmethods,consulttheEIGACodeofPractice

Doc30"Disposalofgases",availableathttp://www.eiga.org

Listofhazardouswaste140601*:chlorofluorocarbons,HCFC,HFC



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