
AB244 LUXEON MultiColor Module 2.5W Application Brief 20200518 ©2020 Lumileds Holding B.V. All rights reserved. 9
6. Packaging Considerations—Chemical Compatibility
The LUXEON emitter package contains a silicone overcoat to protect the LED chip and extract the maximum amount of
light. As with most silicones used in LED optics, care must be taken to prevent any incompatible chemicals from directly or
indirectly reacting with the silicone.
The silicone overcoat used in the LUXEON emitter is gas permeable. Consequently, oxygen and volatile organic compound
(VOC) gas molecules can diuse into the silicone overcoat. VOCs may originate from adhesives, solder uxes, conformal
coating materials, potting materials and even some of the inks that are used to print the PCBs.
Some VOCs and chemicals react with silicone and produce discoloration and surface damage. Other VOCs do not
chemically react with the silicone material directly but diuse into the silicone and oxidize during the presence of heat or
light. Regardless of the physical mechanism, both cases may aect the total LED light output. Since silicone permeability
increases with temperature, more VOCs may diuse into and/or evaporate out from the silicone.
Careful consideration must be given to whether LUXEON emitters are enclosed in an “air tight” environment or not. In an
“air tight” environment, some VOCs that were introduced during assembly may permeate and remain in the silicone. Under
heat and “blue” light, VOCs captured inside the silicone may partially oxidize and create a silicone discoloration, particularly
on the surface of the LED where the ux energy is the highest. In an air rich or “open” air environment, VOCs have a
chance to leave the area (driven by the normal air ow). Transferring the devices which were discolored in the enclosed
environment back to “open” air may allow the oxidized VOCs to diuse out of the silicone and may restore the original
optical properties of the LED.
Determining suitable threshold limits for the presence of VOCs is very dicult since these limits depend on the type of
enclosure used to house the LEDs and the operating temperatures. Also, some VOCs can photo-degrade over time.
Table 3 provides a list of commonly used chemicals that should be avoided as they may react with the silicone material.
Note that Lumileds does not warrant that this list is exhaustive since it is impossible to determine all chemicals that may
aect LED performance.
The chemicals in Table 3 are typically not directly used in the nal products that are built around LUXEON emitters.
However, some of these chemicals may be used in intermediate manufacturing steps (e.g. cleaning agents). Consequently,
trace amounts of these chemicals may remain on (sub) components, such heat sinks. Lumileds, therefore, recommends
the following precautions when designing your application:
– When designing secondary lenses to be used over an LED, provide a suciently large air-pocket and allow for
“ventilation” of this air away from the immediate vicinity of the LED.
– Use mechanical means of attaching lenses and circuit boards as much as possible. When using adhesives, potting
compounds and coatings, carefully analyze its material composition and do thorough testing of the entire xture
under High Temperature over Life (HTOL) conditions.