SCHOTT Lab 850 User manual

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Lab 850
Operating manual
Laboratory pH meter
8
4
2
2
9
9
6
pH
°C
TP
Lab 850

Lab 850
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Accuracy when going to
press
The use of advanced technology and the high quality standard of our
instruments are the result of continuous development. This may result
in differences between this operating manual and your instrument.
Also, we cannot guarantee that there are absolutely no errors in this
manual. Therefore, we are sure you will understand that we cannot
accept any legal claims resulting from the data, figures or descriptions.
Warranty We guarantee the instrument described for 3 years from the date of
purchase.
The instrument warranty covers manufacturing faults that are
discovered within the warranty period.
The warranty does not cover components that are replaced during
maintenance work, e. g. batteries.
The warranty claim extends to restoring the instrument to readiness for
use but not, however, to any further claim for damages. Improper
handling or unauthorized opening of the instrument invalidates any
warranty claim.
To ascertain the warranty liability, return the instrument and proof of
purchase together with the date of purchase freight paid or prepaid.
Copyright ©2009, SI Analytics GmbH
Reprinting - even in the form of excerpts - is only allowed with the
explicit written authorization of SI Analytics GmbH.
Printed in Germany.

Lab 850
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KONFORMITÄTSERKLÄRUNG
DECLARATION OF CONFORMITY
DÉCLARATION DE CONFORMITÉ
Wir erklären in alleiniger
Verantwortung, dass das
Produkt
pH-Meter
Lab 850
auf das sich diese Erklärung
bezieht, übereinstimmt mit
den Angaben im Kapitel
We declare under our sole
responsibility that the
product
pH meter
Lab 850
to which thisdeclaration
relatesisin conformity with
the specificationsin the
chapter
Nous déclaronssous notre
seule responsabilité que le
produit
pH-mètre
Lab 850
auquel se réfère cette
déclaration est conforme aux
indicationsduchapitre
30. Oktober, October 30, 30 octobre 2009
AGQSF 0000-A100-01/091030
SI AnalyticsGmbH
Hattenbergstr. 10
D-55122 Mainz
Deutschland, Germany, Allemagne
Technische Daten
pH-Meter Lab 850
30. Oktober 2009

Lab 850
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Lab 850 Contents
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Lab 850 - Contents
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
1.3 Socket field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
2Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
2.2 General safety instructions . . . . . . . . . . . . . . . . . . . . . . . 12
3 Commissioning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.1 Scope of delivery. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
3.2 Initial commissioning . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
4 Operation. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.1 Switching on the meter . . . . . . . . . . . . . . . . . . . . . . . . . . 17
4.2 General operating principles . . . . . . . . . . . . . . . . . . . . . . 18
4.2.1 Operating modes . . . . . . . . . . . . . . . . . . . . . . . . 18
4.2.2 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
4.3 Measuring . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
4.3.1 Measuring the pH value . . . . . . . . . . . . . . . . . . . 20
4.3.2 Measuring the ORP . . . . . . . . . . . . . . . . . . . . . . 21
4.4 Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
4.4.1 Calibration interval (Int.C) . . . . . . . . . . . . . . . . . 27
4.4.2 Automatic calibration (AutoCal) . . . . . . . . . . . . . 28
4.5 Saving . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.5.1 Manual storage . . . . . . . . . . . . . . . . . . . . . . . . . 31
4.5.2 Automatic storage at intervals (AutoStore) . . . . 33
4.5.3 Downloading the data memory . . . . . . . . . . . . . 35
4.5.4 Erasing the data memory . . . . . . . . . . . . . . . . . . 36
4.5.5 Downloading calibration data . . . . . . . . . . . . . . . 36
4.6 Transmitting data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
4.6.1 Options for data transmission . . . . . . . . . . . . . . 39
4.6.2 Automatically downloading measurement
datasets at intervals . . . . . . . . . . . . . . . . . . . . . . 40
4.6.3 Downloading stored measurement datasets . . . 40
4.6.4 Downloading calibration data . . . . . . . . . . . . . . . 40
4.6.5 RS232 interface . . . . . . . . . . . . . . . . . . . . . . . . . 40
4.6.6 Operation with MultiLab pilot . . . . . . . . . . . . . . . 41
4.7 Settings . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
4.7.1 System settings . . . . . . . . . . . . . . . . . . . . . . . . . 43

Contents Lab 850
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4.7.2 Measurement settings . . . . . . . . . . . . . . . . . . . . 45
4.7.3 Interval for automatic storing (AutoStore) . . . . . . 49
4.7.4 Interval for automatic data transmission . . . . . . . 50
4.8 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
4.8.1 Resetting calibration values . . . . . . . . . . . . . . . . 51
4.8.2 Resetting all meter settings . . . . . . . . . . . . . . . . 52
5 Maintenance, cleaning, disposal . . . . . . . . . . . . . . . . . 53
5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
5.1.1 Replacing the batteries . . . . . . . . . . . . . . . . . . . . 53
5.2 Cleaning. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
5.3 Packing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
5.4 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
7 Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
7.2 Measuring ranges, resolution, accuracy . . . . . . . . . . . . . 61
8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63

Lab 850 Overview
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1Overview
The compact Lab 850 precision pH meter enables you to perform pH
measurements rapidly and reliably. The Lab 850 provides the
maximum degree of operating comfort, reliability and measuring
certainty for all applications.
The proven calibration procedures and special stability control function
(SC) support your work with the pH meter.
Note
The meter is also available as part of individual Sets of equipment.
You will find information on this and other accessories in the SI
Analytics GmbH laboratory catalog or via the Internet.
Note
If you need further information or application notes, you can obtain the
following material from SI Analytics GmbH:
zApplication reports
zpH primers
zSafety datasheets.
1Keypad
2Display
3Socket field
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pH
°C
TP
1
2
3
Lab850

Overview Lab 850
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1.1 Keypad
In this operating manual, keys are indicated by brackets <..> .
The key symbol (e.g. <OK>) indicates a keystroke in this operating
manual.
<On/Off>:
<On/Off_>:
Switch meter on / off
Reset calibration values
<MODE>:
<MODE_>:
Select measured parameter
Open setting menu for calibration and
measurement
<CAL>:
<CAL_>:
Call up calibration procedure
Display calibration data
<SC>:
<SC_>:
Activate / deactivate stability control
Set interval for data transmission
<STO>:
<STO_>:
Store measured value
Set interval for automatic storage in
memory
<RCL>:
<RCL_>:
Display / transmit measured values and
calibration records
Erase stored measured values
<▲>: Increment values, scroll
<▼>: Decrement values, scroll
<OK>:
<OK_>:
Confirm entries
Open setting menu for system settings
STO
RCL
MODE SC
CAL
MODE
CAL
SC
STO
STO
RCL

Lab 850 Overview
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1.2 Display
Function display
indicators
8
88
8
8
18
8
8
°C
°F
U pH
%
LoBat
Auto Store
SC
TP
CalError
Time
Day.Month
Year
Baud
No.
Ident
mV/pH
RCL
SET BUFFER
AutoCal
Status display
indicator
CalClock (calibration
interval and sensor
evaluation)
Measured value
display
Temperature display
and further function
indicators
[SET] During calibration: number of the buffer set
[BUFFER] During calibration: number of the buffer
[AutoCal] Calibration with automatic buffer recognition
[Auto][Store] Automatic storing is switched on
[CalError] An error occurred during calibration
[LoBat] With battery operation: batteries almost empty
[SC] Stability control is active
[RCL] Memory display / memory download
[TP] Temperature measurement active

Overview Lab 850
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1.3 Socket field
CAUTION
Only connect sensors to the meter that cannot return any voltages
or currents that are not allowed (> SELV and > current circuit with
current limiting).
Almost all sensors - in particular SI Analytics GmbH sensors -
fulfill these conditions.
Connectors:
1pH electrode
2Reference electrode
3Temperature sensor
4Power pack
5RS 232 interface
12345

Lab 850 Safety
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2Safety
This operating manual contains basic instructions that you must follow
during the commissioning, operation and maintenance of the meter.
Consequently, all responsible personnel must read this operating
manual before working with the meter.
The operating manual must always be available within the vicinity of the
instrument.
Target group The meter was developed for work in the laboratory.
Thus, we assume that, as a result of their professional training and
experience, the operators will know the necessary safety precautions
to take when handling chemicals.
Safety instructions Safety instructions in this operating manual are indicated by the
warning symbol (triangle) in the left column. The signal word (e.g.
"Caution") indicates the level of danger:
WARNING
indicates instructions that must be followed precisely in order to
avoid possibly great dangers to personnel.
CAUTION
indicates instructions that must be followed precisely in order to
avoid the possibility of slight injuries or damage to the instrument
or the environment.
Further notes
Note
indicates notes that draw your attention to special features.
Note
indicates cross-references to other documents, e.g. operating
manuals.

Safety Lab 850
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2.1 Authorized use
This meter is authorized exclusively for pH and ORP measurements in
the laboratory.
The technical specifications as given in chapter 7 TECHNICAL DATA
(page 59) must be observed. Only the operation and running of the
meter according to the instructions given in this operating manual is
authorized.
Any other use is considered unauthorized.
2.2 General safety instructions
This instrument is constructed and tested in compliance with the IEC
1010 safety regulations for electronic measuring instruments.
It left the factory in a safe and secure technical condition.
Function and
operational safety
The smooth functioning and operational safety of the meter can only be
guaranteed if the generally applicable safety measures and the specific
safety instructions in this operating manual are followed during
operation.
The smooth functioning and operational safety of the meter can only be
guaranteed under the environmental conditions that are specified in
chapter 7 TECHNICAL DATA (page 59).
If the instrument was transported from a cold environment to a warm
environment, the formation of condensate can lead to the faulty
functioning of the instrument. In this event, wait until the temperature of
the instrument reaches room temperature before putting the instrument
back into operation.
CAUTION
The meter is only allowed to be opened by personnel authorized
by SI Analytics GmbH.

Lab 850 Safety
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Safe operation If safe operation is no longer possible, the instrument must be taken out
of service and secured against inadvertent operation!
Safe operation is no longer possible if the meter:
zhas been damaged in transport
zhas been stored under adverse conditions for a lengthy period of
time
zis visibly damaged
zno longer operates as described in this manual.
If you are in any doubt, please contact the supplier of the instrument.
Obligations of the
purchaser
The purchaser of this meter must ensure that the following laws and
guidelines are observed when using dangerous substances:
zEEC directives for protective labor legislation
zNational protective labor legislation
zSafety regulations
zSafety datasheets of the chemical manufacturers.

Safety Lab 850
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Lab 850 Commissioning
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3 Commissioning
3.1 Scope of delivery
zLab 850 laboratory meter
zPower pack
z4 batteries 1.5 V Mignon type AA
zTransparent cover
zOperating manual
3.2 Initial commissioning
Perform the following activities:
zInsert batteries
zSwitch on the meter
zSet the date and time
zConnect the power pack (for line power operation only).
Insert batteries 1Open the battery compartment (1) on the underside of the
meter.
2 Place four batteries (type Mignon AA) in the battery
compartment.
3Close the battery compartment (1).
The date (day) flashes in the display.
4 Set the date and time according to page 43.
1

Commissioning Lab 850
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CAUTION
Make sure that the poles of the batteries are the right way round.
The ±signs on the batteries must correspond to the ± signs in the
battery compartment.
Only use leakproof alkaline manganese batteries.
Switching on the meter
Setting the date and
time
Connecting the power
pack
You can either operate the measuring instrument with batteries or with
the plug-in power supply. The plug-in power supply supplies the mea-
suring instrument with low voltage (12 VDC). This saves the batteries.
CAUTION
The line voltage at the operating site must lie within the input
voltage range of the original power pack (see page 59).
CAUTION
Use original power packs only (see page 59).
Note
You can carry out measurements without the power pack.
1Switch on the meter with <On/Off>.
A display test is briefly displayed.
2See page 43.
3Insert the plug into the socket of the pH meter.
4 Connect the original power pack to an easily accessible power
outlet.

Lab 850 Operation
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4 Operation
4.1 Switching on the meter
Note
The meter has an energy saving feature to avoid unnecessary battery
depletion during battery operation.
The energy saving feature switches off the meter if no key was pressed
during the specified interval (setting the switch-off interval, see
page 43).
The energy saving feature is not active:
zif the meter is supplied via the power pack
zif the automatic storing function is active (see page 33)
zif a PC is connected (with communication cable to RS232 interface)
zif the printer cable is connected (for external printers).
1Place the meter on a flat surface and protect it from intense
light and heat.
2 Press the <On/Off> key.
A display test is briefly displayed.
Subsequently, the meter switches to the measuring mode
(measured value display).

Operation Lab 850
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4.2 General operating principles
This section contains basic information on the operation of the Lab 850.
4.2.1 Operating modes
The instrument has the following operating modes:
zMeasurement
The display indicates the measurement data in the measured value
display
zCalibration
The display guides you thru a calibration procedure with calibration
information
zStorage
The meter stores measuring data automatically or manually
zTransmitting data
The meter transmits measuring data and calibration records to a
serial interface automatically or manually.
zConfiguration
The system menu or a sensor menu with submenus, settings and
functions is displayed
4.2.2 Operation
Keys The meter is operated via keys. The keys can have different functions
with long or short keystrokes.
Functions Generally, with a short keystroke a function is carried out. A long
keystroke opens a setting menu.
In a setting menu, settings are selected with the <▲><▼> keys.
A setting is confirmed with <OK>. With confirming, the setting is
finished and the next setting is displayed.
Representation In this operating manual, keys are indicated by brackets <..> .
The key symbol (e.g. <OK>) generally indicates a short keystroke
(under 2 sec) in this operating manual. A long keystroke (approx.
2 sec) is indicated by the underscore behind the key symbol (e.g.
<OK_>).

Lab 850 Operation
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4.3 Measuring
Preparatory activities Perform the following preparatory activities when you want to measure:
Note
Incorrect calibration of pH electrodes leads to incorrect measured
values. Calibrate regularly before measuring.
CAUTION
When connecting an earthed PC/printer, measurements cannot be
performed in earthed media as incorrect values would result.
The RS232 interface is not galvanically isolated.
Temperature sensor You can measure with or without a temperature sensor. If a
temperature sensor is connected, it is indicated on the display by TP.
Note
The pH meter automatically recognizes the type of the temperature
sensor used. Therefore, you can connect electrodes with an NTC30 or
Pt1000.
The temperature measurement is absolutely essential for a
reproducible pH measurement. If the measurement is made without a
temperature sensor, proceed as follows:
Note
When calibrating without temperature sensor, also set the current
temperature of each buffer solution manually (see <▲><▼>).
1Connect an electrode to the meter.
2 Adjust the temperature of the buffer solutions or test solutions,
or measure the current temperature, if you measure without a
temperature sensor.
3Calibrate or check the meter with the electrode.
4 Select the measured parameter with <MODE>.
1Measure the current temperature using a thermometer.
2 Set the temperature value with <▲><▼>.

Operation Lab 850
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4.3.1 Measuring the pH value
Stability control SC
(drift control)
The stability control function (drift control) checks the stability of the
measurement signal. The stability has a considerable effect on the
reproducibility of the measured value.
For identical measurement conditions, the following criteria apply:
Drift within 15 sec < 0.02 pH units.
Note
The current measurement with stability control can be terminated at
any time (accepting the current value) by pressing <OK>.
1Perform the preparatory activities according to page 19.
2 Immerse the pH electrode in the test sample.
3Using <MODE>, scroll as necessary until the measured
parameter pH is displayed.
8
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6
pH
°C
TP
1If necessary, call up the measured variable pH with <MODE>.
2With<SC>, activate the stability control function.
The SC function display indicator appears.
The current measured value is frozen (hold function).
3Start measurement with stability control with <OK>.
SC flashes until a stable measured value is reached.
This measured value is downloaded to the interface.
4 If necessary, start the next measurement with stability control
with <OK>.
5To terminate the stability control function: Press the <MODE>
or <SC> key.