Camlab Lovibond MD 610 User manual

Photometer
1
Instruction manual
GB
Lovibond®Water Testing
Tintometer®Group
www.lovibond.com
Distributed By:
Camlab Limited
Camlab House, Norman Way Industrial Estate, Over, Cambridge CB24 5WE, UK
E: [email protected]
T: [phone]

Important stepsbefore usingthe photometer
Pleasecarryout the following stepsasdescribedin the
Instruction manual. Becomefamiliar with your new pho-
tometer before starting with the rst tests:
• Unpacking and inspection of deliverycontents,
seepage 358.
• Installthe batteries, seepage302 and following.
Performthe following settingsin the Mode-Menu;
Instructionmanualfrom page315 and following:
• MODE10: selectlanguage
• MODE12: setdate and time
• MODE 34: perform “Delete data“
• MODE 69: perform “Userm. init” to initialisethe
user polynomial system
If required setother functions.

Wichtige Information
Um die Qualität unsererUmwelt zu erhalten, beschützenund zu verbessern
Entsorgung von elektronischen Geräten in der EuropäischenUnion
Aufgrund der EuropäischenVerordnung 2012/19/EU darf Ihr elektronischesGerät
nicht mit dem normalen Hausmüllentsorgt werden!
Tintometer GmbH entsorgt ihr elektrischesGerät auf eine professionelleund für
die Umwelt verantwortungsvolle Weise.DieserServiceist, die Transportkosten
nicht inbegri󰀨en, kostenlos. DieserServicegilt ausschließlichfür elektrische Geräte
die nach dem 13.08.2005 erworben wurden. SendenSieIhre zu entsorgenden
Tintometer Geräte frei Hausan Ihren Lieferanten.
Important Information
To Preserve,Protectand Improve the Quality of the Environment
Disposalof ElectricalEquipment in the European Union
Becauseof the European Directive2012/19/EU your electrical instrument must not
be disposedof with normal household waste!
Tintometer GmbH will disposeof your electrical instrument in a professional
and environmentally responsiblemanner. Thisservice,excluding the costof
transportation isfree of charge. Thisserviceonly appliesto electrical instruments
purchasedafter 13th August 2005. Sendyour electricalTintometer instruments for
disposalfreight prepaid to your supplier.
Notice importante
Conserver,protéger et optimiser la qualité de l’environnement
Élimination du matériel électrique dans l’Union Européenne
Conformément à la directive européenne nº 2012/19/UE, vous ne devezplus jeter
vos instruments électriques dans les ordures ménagèresordinaires !
Lasociété Tintometer GmbH secharge d’éliminer vosinstruments électriques de
façon professionnelle et dansle respectde l’environnement. Ceservice,qui ne
comprend pas lesfrais de transport, est gratuit. Ceservicen’est valable que
pour desinstruments électriques achetésaprèsle 13 août 2005. Nousvousprions
d’envoyer vos instruments électriques Tintometer usésà vosfrais à votre fournisseur.
Belangrijkeinformatie
Om de kwaliteit van onsleefmilieu te behouden,te verbeteren en te
beschermenisvoor landen binnen de EuropeseUnie de Europeserichtlijn
2012/19/EU voor het verwijderen van elektronischeapparatuur opgesteld.
Volgensdezerichtlijn mag elektronischeapparatuur niet met het huishoudelijk afval
worden afgevoerd.
Tintometer GmbH verwijdert uw elektronisch apparaatop een professioneleen
milieubewuste wijze. Dezeserviceis, exclusief de verzendkosten, gratis en alleen
geldig voor elektrische apparatuur die na 13 augustus2005 is gekocht. Stuur uw te
verwijderen Tintometer apparatuur franco aanuw leverancier.
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Información Importante
Parapreservar,proteger y mejorar la calidad del medio ambiente
Eliminación de equipos eléctricosen la Unión Europea
Con motivo de la DirectivaEuropea2012/19/UE, ¡ningún instrumento eléctrico
deberá eliminarse junto con los residuosdomésticos diarios!
Tintometer GmbH seencargaráde dichos instrumentos eléctricos de una manera
profesional y sin dañar el medio ambiente. Esteservicio, el cual escluye losgastos
de transporte, esgratis y seaplicará únicamente a aquellosinstrumentos eléctricos
adquiridos despuésdel 13 de agosto de 2005. Seruega enviar aquellos instrumentos
eléctricos inserviblesdeTintometer a cargapagada a sudistribuidor.
Informazioni importanti
Conservare,proteggere e migliorare la qualità dell’ambiente
Smaltimento di apparecchiatureelettriche nell’Unione Europea
In basealla Direttiva europea 2012/19/UE, gli apparecchi elettrici non devono essere
smaltiti insiemeai normali riuti domestici!
Tintometer GmbH provvederàa smaltirei vostri apparecchielettrici in maniera
professionale e responsabileversol’ambiente. Questo servizio, esclusoil trasporto,
è completamente gratuito. Il serviziosiapplica agli apparecchielettrici acquistati
successivamenteal 13 agosto 2005. Sietepregati di inviare gli apparecchi elettrici
Tintometer divenuti inutilizzabili a trasporto pagato al vostro rivenditore.
Informação Importante
ParaPreservar,Proteger e Melhorar a Qualidade do Ambiente
Remoçãode Equipamento Eléctricona União Europeia
Devido à Directiva Europeia2012/19/UE, o seu equipamento eléctrico naõ deve ser
removido com o lixo doméstico habitual!
A Tintometer GmbH tratará da remoçãodo seuequipamento eléctrico de forma
prossional e responsávelem termos ambientais. Esteserviço, não incluindo
os custosde transporte, é gratuito. Esteserviçosó éaplicável no casode
equipamentos eléctricos comprados depoisde 13 de Agosto de 2005. Porfavor,
envie os seusequipamentos eléctricos Tintometer que devem ser removidos ao seu
fornecedor (transporte pago).
Istotna informacja
Dla zachowania,ochronyoraz poprawy naszegośrodowiska
Usuwanieurządzeń elektronicznychwUnii Europejskiej
Na podstawie Dyrektywy ParlamentuEuropejskiego 2012/19/UE nie jest
dozwolone usuwanie zakupionych przez Państwourządzeńelektronicznych wrazz
normalnymi odpadami z gospodarstwadomowego!
Tintometer GmbH usunie urządzeniaelektrycznego Państwaw sposób
profesjonalny i odpowiedzialny z punktu widzenia środowiska.Serwisten jest,
zawyjątkiem kosztów transportu, bezpłatny. Serwisten odnosi się wyłączniedo
urządzeń elektrycznych zakupionych po 13.08.2005r. Przeznaczonedo usunięcia
urządzeniarmy Tintometer mogą Państwo przesyłaćna kosztwłasnydo swojego
dostawcy.
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Wichtiger Entsorgungshinweiszu Batterien und Akkus
JederVerbraucherist aufgrund der Batterieverordnung (Richtlinie 2006/66/
EG)gesetzlich zur Rückgabealler ge- und verbrauchten Batterien bzw. Akkus
verpichtet. Die Entsorgungüber den Hausmüll ist verboten. Da auchbei Produkten
ausunseremSortiment Batterien und Akkus im Lieferumgang enthalten sind, weisen
wir Sieauf folgendes hin:
Verbrauchte Batterien undAkkus gehören nicht in den Hausmüll, sondernkönnen
unentgeltlich bei den ö󰀨entlichen SammelstellenIhrer Gemeindeund überall
dort abgegebenwerden, wo Batterienund Akkus derbetre󰀨enden Art verkauft
werden. Weiterhin besteht für den Endverbraucherdie Möglichkeit, Batterien und
Akkus an den Händler, bei dem sieerworben wurden, zurückzugeben (gesetzliche
Rücknahmepicht).
Important disposalinstructionsfor batteries and accumulators
ECGuideline 2006/66/EC requiresusersto return all usedand worn-out batteries
and accumulators. Theymust not be disposedof in normal domestic waste. Because
our products include batteries and accumulators in the deliverypackageour advice is
asfollows :
Usedbatteries and accumulatorsarenot items of domestic waste. Theymust be
disposedof in a proper manner. Your local authority may havea disposalfacility;
alternatively you can hand them in at any shopselling batteries and accumulators.
You canalsoreturn them to the company which supplied them to you; the company
isobliged to acceptthem.
Information importante pour l'élimination despileset des accumulateurs
Envertu de la Directive européenne 2006/66/CE relative aux piles et accumulateurs,
chaque utilisateur est tenu de restituer toutes lespileset tous lesaccumulateurs
utilisés et épuisés.L'élimination aveclesdéchets ménagersest interdite. Etant donné
que l'étendue de livraisondesproduits de notre gamme contient également despiles
et des accumulateurs, nous vous signalons cequi suit :
lespiles et lesaccumulateurs utilisés ne sont pas desordures ménagères,ils peuvent
être remissansfrais auxpoints de collecte publics de votre municipalité et partout
où sont vendusdespiles et accumulateurs du type concerné. Parailleurs, l'utilisateur
nal a la possibilité de remettre lespiles et lesaccumulateurs au commerçant auprès
duquel ils ont été achetés(obligation de repriselégale).
Belangrijkemededeling omtrent afvoer van batterijen en accu’s
Ledereverbruiker is op basisvan de richtlijn 2006/66/EG verplicht om alle gebruikte
batterijen en accu’sin te leveren. Het isverboden deze af te voeren via het huisvuil.
Aangezienook onze producten geleverdworden met batterijen en accu’swijzen wij
u op het volgende; Legebatterijen en accu’shoren niet in het huisvuil thuis. Men
kan dezeinleverenbij inzamelpunten van uw gemeente of overal daarwaar deze
verkocht worden. Tevensbestaat de mogelijkheid batterijen en accu’sdaar in te
leverenwaar u zegekocht heeft. (wettelijke terugnameplicht)
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Indicaciónimportante acercade la eliminación de pilas y acumuladores
Basadoen la norma relativa a pilas/ baterías (directiva 2006/66/CE), cada consumidor,
está obligado por ley, a la devolución de todas las pilas/ bateríasy acumuladores usadosy
consumidos. Estáprohibida la eliminación en la basuradoméstica. Ya que en productos de
nuestra gama, también seincluyen en el suministro pilas y acumuladores,le sugerimos lo
siguiente:
Laspilas y acumuladores usadosno pertenecen a la basura doméstica, sino que pueden
serentregados en forma gratuita en cadauno de los puntos de recolección públicos de su
comunidad en los cualessevendan pilas y acumuladores del tipo respectivo. Además, para
el consumidor nal existe la posibilidad de devolver laspilas y bateríasrecargablesa los
distribuidores donde sehayanadquirido (obligación legal de devolución).
Indicazioni importanti sullosmaltimento di pile e accumulatori
In basealla normativa concernente le batterie (Direttiva 2006/66/CE) ogni consumatore
è tenuto per legge allarestituzione di tutte le batterie o accumulatori usati ed esauriti.È
vietato lo smaltimento con i riuti domestici. Datocheanchealcuni prodotti del nostro
assortimento sono provvistidi pile e accumulatori, vi diamo di seguito delle indicazioni:
Pilee accumulatori esauriti non vanno smaltiti insieme ai riuti domestici, ma depositati
gratuitamente nei punti di raccoltadel proprio comune o nei punti vendita di pile e
accumulatori dello stessotipo. Inoltre il consumatore nale può portare batterie e
accumulatori al rivenditore pressoil quale li ha acquistati (obbligo di raccolta previsto per
legge).
Instruçõesimportantes para a eliminação residual de pilhas e acumuladores
Osutilizadores nais são legalmente responsáveis,nos termos do Regulamento relativo
a pilhas e acumuladores (Directiva 2006/66/CE), pela entrega de todas as pilhas e
acumuladores usadose gastos. Éproibida a suaeliminação juntamente com o lixo
doméstico. Uma vezque determinados produtos da nossagama contêm pilhas e/ou
acumuladores, alertamos para os seguintes aspectos:
As pilhas eacumuladores usadosnão podem sereliminados com o lixo doméstico,
devendo sim serentregues, sem encargos,junto dos pontos de recolha públicos do seu
município, ou em qualquer ponto de vendade pilhase acumuladores.O utilizador nal
dispõe ainda da possibilidade de entregar aspilhas e/ou acumuladores no estabelecimento
comerciante onde os adquiriu (deverlegal de aceitar a devolução).
Istotna wskazówkadotyczącautylizacji baterii iakumulatorów
Każdyużytkownik na mocy rozporządzenia w sprawie baterii (wytyczna2006/66/WE)
jest ustawowo zobowiązany do oddawania wszystkichrozładowanych i zużytychbaterii
lub akumulatorów. Utylizacjawrazz odpadkami domowymi jest zabroniona. Ponieważ
także w produktach z naszego asortymentu zawarte sąw zakresiedostawy baterie i
akumulatory, zwracamyuwagę na poniższe zasady:
zużytebaterie i akumulatory nie mogą być wyrzucanewrazz odpadkami domowymi,
lecz powinny być bezpłatnie przekazywanew publicznych miejscach zbiórki
wyznaczonychprzezgminę lub oddawane w punktach, gdzie sprzedawanesąbaterie i
akumulatory danego rodzaju. Pozatym użytkownik końcowy ma możliwość zwrócenia
baterii i akumulatorów do przedstawicielahandlowego, u którego je nabył (ustawowy
obowiązek przyjęcia).
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1
MD610_2d 11/2019
Safety precautions
CAUTION
Reagentsare formulated exclusivelyfor chemical analysisand must not be used for
anyother purpose. Reagentsmust not get into the handsof children. Someof the
reagents contain substanceswhich are not entirely harmlessenvironmentally. Be
aware of the ingredients and take proper carewhen disposing of the test solution.
CAUTION
Pleasereadthis instruction manual before unpacking, setting up or using the
photometer. Pleasereadthe method description completely before performing
the test. Beaware of the risks of using the required reagentsby reading the MSDS
(Material SafetyData Sheets).Failurecould result in seriousinjury to the operator or
damageto the instrument.
MSDS:www.lovibond.com
CAUTION
Theaccuracyof the instrument isonly valid if the instrument isusedin an
environment with controlled electromagnetic disturbancesaccording to DIN61326.
Wirelessdevices,e.g. wireless phones, must not be usednear the instrument.
Revision_2d 11/2019

2MD610_2d 11/2019
Tableof contents
Part 1 Methods ...................................................................................................... 9
1.1 Tableof Methods..................................................................................................... 10
Acid demandto pH 4.3..................................................................................................... 16
Alkalinity-total (Alkalinity-m, m-Value)............................................................................... 18
Alkalinity-total HR(Alkalinity-m HR,m-ValueHR).............................................................. 20
Alkalinity-p (p-Value)......................................................................................................... 22
Aluminium with tablets.....................................................................................................24
Aluminium (powder pack)................................................................................................. 26
Ammonia with tablet........................................................................................................28
Ammonia (powderpack)................................................................................................... 30
Ammonia, low range (LR).................................................................................................. 32
Ammonia, high range(HR)................................................................................................ 34
Boron ............................................................................................................................... 36
Brominewith tablet .......................................................................................................... 38
Bromine(powder pack)..................................................................................................... 40
Chloridewith tablet.......................................................................................................... 42
Chloridewith LiquidReagent............................................................................................ 44
Chlorine............................................................................................................................ 46
Chlorinewith tablet.......................................................................................................... 48
freeChlorine................................................................................................................. 48
total Chlorine................................................................................................................ 49
di󰀨erentiated determination (free,combined,total) ...................................................... 50
ChlorineHRwith tablet..................................................................................................... 52
freeChlorine................................................................................................................. 52
total Chlorine................................................................................................................ 53
di󰀨erentiated determination (free,combined,total) ...................................................... 54
Chlorinewith liquid reagent.............................................................................................. 56
freeChlorine................................................................................................................. 56
total Chlorine................................................................................................................ 57
di󰀨erentiated determination (free,combined,total) ...................................................... 58
Chlorine(powder pack)..................................................................................................... 60
freeChlorine................................................................................................................. 60
total Chlorine................................................................................................................ 61
di󰀨erentiated determination (free,combined,total) ...................................................... 62
Chlorine MR(VARIOpowder pack).................................................................................... 64
freeChlorine................................................................................................................. 64
total Chlorine................................................................................................................ 65
di󰀨erentiated determination (free,combined,total) ...................................................... 66
ChlorineHR(powder pack)............................................................................................... 68
freeChlorine................................................................................................................. 68

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MD610_2d 11/2019
total Chlorine ................................................................................................................ 69
di󰀨erentiated determination (free,combined,total) ....................................................... 70
Chlorinedioxidewith tablet............................................................................................... 72
in presenceof Chlorine.................................................................................................. 74
in absenceof Chlorine ................................................................................................... 77
Chlorinedioxide(powder pack).......................................................................................... 78
in absenceof Chlorine ................................................................................................... 78
in presenceof Chlorine.................................................................................................. 79
ChlorineHR(KI)................................................................................................................. 82
Chlorite in presenceof Chlorine and Chlorinedioxide........................................................ 84
Chromium with PowderPack............................................................................................. 88
di󰀨erentiated determination .......................................................................................... 90
Chromium (VI)............................................................................................................... 92
Chromium, total (Cr(III)+ Cr(VI))..................................................................................... 93
COD,low range(LR).......................................................................................................... 94
COD,middle range(MR).................................................................................................... 96
COD,high range(HR)........................................................................................................ 98
Colour,true and apparent................................................................................................ 100
Copperwith tablet .......................................................................................................... 102
di󰀨erentiated determination (free,combined,total) ..................................................... 103
freeCopper................................................................................................................. 104
total Copper................................................................................................................ 105
Copperwith liquid reagentand powder .......................................................................... 106
di󰀨erentiated determination (free,combined,total) ..................................................... 107
freeCopper................................................................................................................. 109
total Copper................................................................................................................ 110
Copper(powder pack)..................................................................................................... 112
Cyanide........................................................................................................................... 114
CyA-TEST(Cyanuricacid)................................................................................................. 116
DEHAT............................................................................................................................ 118
DEHAPP......................................................................................................................... 120
Fluoride........................................................................................................................... 122
H2O2with tablet reagent ................................................................................................. 124
H2O2LRwith liquid reagent.............................................................................................. 126
H2O2HRwith liquid reagent............................................................................................. 128
Hardness,Calciumwith Calchecktablet........................................................................... 130
Hardness,Calciumwith Calciotablet ............................................................................... 132
Hardness,total................................................................................................................. 134
Hardness,total HR........................................................................................................... 136
Hydrazine........................................................................................................................ 138
Hydrazinewith liquid reagent.......................................................................................... 140
Hydrazinewith Vacu-vials................................................................................................. 142

4MD610_2d 11/2019
HydrogenperoxideseeH2O2.......................................................................................... 144
Iodine............................................................................................................................. 144
Iron................................................................................................................................. 146
Ironwith tablet ...........................................................................................................148
Iron(powder pack)...................................................................................................... 150
Iron TPTZ(powderpack).............................................................................................. 152
Iron (Fein Mo, powder pack) ...................................................................................... 154
Iron LRwith liquid reagent .......................................................................................... 156
Iron LR2 with liquid reagent ....................................................................................... 160
Iron HRwith liquid reagent ......................................................................................... 164
Manganesewith tablet ................................................................................................... 168
ManganeseLR(powder pack)......................................................................................... 170
ManganeseHR(powder pack) ........................................................................................ 172
Manganesewith liquid reagent....................................................................................... 174
Molybdate with tablet..................................................................................................... 176
Molybdate LR(powder pack)........................................................................................... 178
Molybdate HR(powder pack).......................................................................................... 180
Molybdate HRwith liquid reagent................................................................................... 182
Nickelwith tablet............................................................................................................ 184
Nitratewith tablet and powder....................................................................................... 186
Nitrate (tubetest)............................................................................................................ 188
Nitrite with tablet............................................................................................................190
Nitrite LR(powder pack).................................................................................................. 192
Nitrogen, total LR............................................................................................................ 194
Nitrogen, total HR........................................................................................................... 196
Oxygen,active................................................................................................................ 200
Oxygen,dissolved........................................................................................................... 202
Ozone............................................................................................................................. 204
in presenceof Chlorine ............................................................................................... 206
in absenceof Chlorine ................................................................................................ 208
PHMB(Biguanide)........................................................................................................... 210
Phosphate....................................................................................................................... 212
Phosphate,ortho LRwith tablet .................................................................................. 214
Phosphate,ortho HRwith tablet ................................................................................. 216
Phosphate,ortho (powder pack) ................................................................................. 218
Phosphate,ortho (tube test)........................................................................................ 220
Phosphate1, ortho C.................................................................................................. 222
Phosphate2, ortho C.................................................................................................. 224
Phosphate,hydrolyzable(tube test)............................................................................. 226
Phosphate,total (tube test)......................................................................................... 228
PhosphateLRwith Liquid reagent ............................................................................... 230
PhosphateHRwith Liquidreagent............................................................................... 234

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MD610_2d 11/2019
Phosphonates ................................................................................................................. 238
pH valueLRwith tablet ................................................................................................... 242
pH valuewith tablet......................................................................................................... 244
pH valuewith liquid reagent ........................................................................................... 246
pH valueHRwith tablet .................................................................................................. 248
Polyacrylatewith liquid reagent ....................................................................................... 250
Potassium ....................................................................................................................... 254
Silica ............................................................................................................................... 256
SilicaLRPP...................................................................................................................... 258
SilicaHRPP..................................................................................................................... 260
Silicawith liquid reagentand powder ............................................................................. 262
Sodiumhypochlorite ....................................................................................................... 264
Sulfatewith tablet .......................................................................................................... 266
Sulfate(powder pack) ..................................................................................................... 268
Sulde ............................................................................................................................ 270
Sulte............................................................................................................................. 272
Surfactants,anionic ........................................................................................................ 274
Surfactants,nonionic ...................................................................................................... 276
Surfactants,cationic ........................................................................................................ 278
SuspendedSolids............................................................................................................. 280
TOCLR ........................................................................................................................... 282
TOCHR .......................................................................................................................... 284
Turbidity ......................................................................................................................... 286
Triazole/ Benzotriazole(powder pack).............................................................................. 288
Urea ............................................................................................................................... 290
Zincwith tablet ............................................................................................................... 292
Zincwith liquid reagentand powder............................................................................... 294
1.2 Important notes.........................................................................................296
1.2.1 Correctuseof reagents................................................................................. 296
1.2.2 Cleaning of vialsand accessoriesforanalysis .................................................. 297
1.2.3 Guidelinesfor photometric measurements.................................................... 297
1.2.4 Sampledilution techniques............................................................................ 299
1.2.5 Correctingfor volumeadditions ................................................................... 299
Part 2 Instrument Manual .......................................................................301
2.1 Operation ...................................................................................................302
2.1.1 Setup .......................................................................................................... 302
2.1.2 Savingdata –Important Notes ...................................................................... 302
2.1.3 Replacementof batteries............................................................................... 302
2.1.4 Instrument (explosiondrawing) ..................................................................... 303
2.2 Overview of function keys....................................................................... 305

6MD610_2d 11/2019
2.2.1 Overview...................................................................................................... 305
2.2.2 Displayingtime and date............................................................................... 306
2.2.3 Usercountdown........................................................................................... 306
2.3 Operation mode ........................................................................................307
2.3.1 Automatic switch o󰀨 ................................................................................... 307
2.3.2 Selectinga method ....................................................................................... 307
2.3.2.1 Method Information (F1) ............................................................................... 307
2.3.2.2 ChemicalSpeciesInformation........................................................................ 308
2.3.3 Di󰀨erentiation............................................................................................... 308
2.3.4 PerformingZero............................................................................................ 308
2.3.5 PerformingTests............................................................................................. 309
2.3.6 Ensuringreactionperiods(countdown).......................................................... 309
2.3.7 Changing chemicalspecies............................................................................. 310
2.3.8 Storingresults............................................................................................... 310
2.3.9 Performadditional measurements ................................................................. 311
2.3.10 Selectinga new method................................................................................ 311
2.3.11 Measureabsorbance..................................................................................... 312
2.4 Bluetooth®..................................................................................................313
2.5 Internet Updates........................................................................................... 314
2.6 Mode Functions ......................................................................................... 315
Schema ....................................................................................................... 315
2.6.1 Instrumentbasicsettings............................................................................... 316
2.6.2 Datatransferof storedresults........................................................................ 324
2.6.3 Recall/ deletestoredresults............................................................................ 328
2.6.4 Calibration..................................................................................................... 333
CalciumHardnessMethod 191 ...................................................................... 333
FluorideMethod 170...................................................................................... 335
UserCalibration ............................................................................................. 337
Storeusercalibration...................................................................................... 339
Deleteusercalibration.................................................................................... 340
2.6.5 Labfunction.................................................................................................. 341
Pro-Mode.................................................................................................... 341
OneTimeZero .............................................................................................. 342
2.6.6 Useroperations.............................................................................................. 343
Usermethod list............................................................................................. 343
UserConcentrationMethods.......................................................................... 345
UserPolynomials............................................................................................ 347
DeleteUserMethods...................................................................................... 350
PrintDataof UserMethods............................................................................ 351
InitialiseUserMethod System......................................................................... 352
2.6.7 LangelierSaturationIndex ............................................................................. 353
Selectionof temperature unit ........................................................................ 354

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MD610_2d 11/2019
2.6.8 Photometer-Information................................................................................. 355
Part 3 Enclosure............................................................................................... 357
3.1 Unpacking.................................................................................................... 358
3.2 Delivery contents...................................................................................... 358
3.3 Technicaldata ............................................................................................. 359
3.4 Abbreviations............................................................................................. 360
3.5 Troubleshooting......................................................................................... 361
3.5.1 Operating messagesinthe display/ error display............................................ 361
3.5.2 General.......................................................................................................... 363
3.6 Declaration of CE-Conformity .................................................................. 364
3.7 Copyright and TrademarkNotice ............................................................. 365

8MD610_2d 11/2019

9
MD610_2d 11/2019
Part 1
Methods

10 MD610_2d 11/2019
1.1 Tableof Methods
* = free, combined, total; PP= powder pack; T= tablet;
L = liquid; TT= tube test; LR= low range; MR = middle range; HR= high range;
Vacu-vial®is a registered trade mark of CHEMetricsInc.
No. Analysis Reagent Range Displayed
as Method [nm] OTZ Page
20 Aciddemand to
pH 4.3 T tablet 0.1-4 mmol/l
Acid/Indicator 1,2,5
610 16
30
Alkalinity,total T
tablet 5-200 mg/l CaCO3
Acid/Indicator 1,2,5
610 18
31
Alkalinity HR,
total T
tablet 5-500 mg/l CaCO3
Acid/Indicator 1,2,5
610 20
35 Alkalinity-p T tablet 5-300 mg/l CaCO3
Acid/Indicator 1,2,5
560 22
40 Aluminium T tablet 0.01-0.3 mg/l Al Eriochrome
Cyanine R2530 24
50 Aluminium PP PP+liquid 0.01-
0.25 mg/l Al Eriochrome Cyanine R2530 – 26
60 Ammonia T tablet 0.02-1 mg/l N
Indophenol blue 2,3
610 28
62 Ammonia PP PP 0.01-0.8 mg/l N Salicylate2660 – 30
65
Ammonia LRTT
tube test 0.02-2.5 mg/l N Salicylate2660 – 32
66
Ammonia HRTT
tube test 1-50 mg/l N Salicylate2660 – 34
85 Boron T tablet 0.1-2 mg/l B Azomethine 3430 36
80 Bromine T tablet 0.05-13 mg/l Br2DPD5530 38
81 Bromine PP PP 0.05-4.5 mg/l Br2DPD1,2 530 40
90 Chloride T tablet 0.5 -25 mg/l Cl-Silvernitrate/
turbidity 530 42
92 Chloride L liquid 0.5-20 mg/l Cl-
Mercurythiocyanate/
Ironnitrate
430 44
100 Chlorine T * tablet 0.01-6 mg/l Cl2DPD1,2,3 530 46,
73
103 Chlorine HR T* tablet 0.1-10 mg/l Cl2DPD1,2,3 530 46,
52
101 Chlorine L * liquid 0.02-4 mg/l Cl2DPD1,2,3 530 46,
56
110 Chlorine PP* PP 0.02-2 mg/l Cl2DPD1,2 530 46,
60
113 Chlorine MR PP* PP 0.02-3.5 mg/l Cl2DPD1,2 530 46,
60
111 Chlorine HR PP* PP 0.1-8 mg/l Cl2DPD1,2 530 –46,
68
120 Chlorine dioxide T tablet 0.02-11 mg/l ClO2DPD,Glycine1,2 530 72
122
Chlorine dioxide PP
PP 0.04-3.8 mg/l ClO2DPD1,2 530 78
105 Chlorine HR (Kl) T tablet 5-200 mg/l Cl2KI/Acid 5530 – 82
125 Chromium PP PP 0.02-2 mg/l Cr 1,5-Diphenyl-
carbohydrazide1,2 530 – 82
130 COD LR TT tube test 3 -150 mg/l O2
Dichromate/H2SO41,2
430 – 94
131 COD MR TT tube test 20 -1500 mg/l O2
Dichromate/H2SO41,2
610 – 96
132 COD HR TT tube test 0.2 -15 g/l O2
Dichromate/H2SO41,2
610 – 98

11
MD610_2d 11/2019
* = free, combined, total; PP= powder pack; T= tablet;
L = liquid; TT= tube test; LR= low range; MR = middle range; HR= high range;
Vacu-vial®is a registered trade mark of CHEMetricsInc.
No. Analysis Reagent Range Displayed
as Method [nm] OTZ Page
204 Colour direct
reading 0-500 Pt-Co units Pt-Co-Scale1,2
(APHA) 430 – 100
150 Copper T * tablet 0.05-5 mg/l Cu Biquinoline 4560 102
151 Copper L* liquid +
powder 0.05-4 mg/l Cu Bicinchoninate 560 106
153 Copper PP PP 0.05-5 mg/l Cu Bicinchoninate 560 112
157 Cyanide Powder+
liquid 0.01-0.5 mg/l CN Pyridine- barbituric acid 1580 114
160
CyA-TEST T
tablet 0-160 mg/l CyA Melamine 530 116
165 DEHA T tablet +
liquid 20-500 μg/l DEHA PPST3560 118
167 DEHA PP PP+liquid 20-500 μg/l DEHA PPST3560 – 120
170 Fluoride L liquid 0.05-2 mg/l F SPADNS2580 122
210 H2O2Ttablet 0.03-3 mg/l H2O2DPD/catalyst5530 124
213 H2O2LRL liquid 1-50 mg/l H2O2Titanium
tetrachloride/acid 430 – 126
214 H2O2HR L liquid 40-500 mg/l H2O2Titanium
tetrachloride/acid 530 – 128
190
Hardness, CalciumT
tablet 50-900 mg/l CaCO3Murexide 4560 – 130
191 Hardness, Calcium tablet
2 T 0-500 mg/l CaCO3Murexide 4560 132
200
Hardness,total T
tablet 2-50 mg/l CaCO3Metallphthalein 3560 134
201 Hardness,total
HRT tablet 20-500 mg/l CaCO3Metallphthalein 3560 136
205 Hydrazine P powder 0.05-0.5 mg/l N2H44-(Dimethyl-
amino)-
benzaldehyde 3
430 138
206 Hydrazine L liquid 0.005-
0.6 mg/l N2H44-(Dimethyl-
amino)-
benzaldehyde 3
430 – 140
207 Hydrazine C Vacu-vial 0.01-0.7 mg/l N2H4PDMAB 430 – 142
215 Iodine T tablet 0.05-3.6 mg/l I DPD5530 144
220 Iron T tablet 0.02-1 mg/l Fe PPST3560
146,
148
222 Iron PP PP 0.02-3 mg/l Fe 1,10-Phenan-
troline 3530
146,
150
223 Iron (TPTZ)PP PP 0.02-1.8 mg/l Fe TPTZ 580 –
146,
152
224 Iron (Fe in Mo) PP PP 0.01-1.8 mg/l Fe Fein Mo 580 –
146,
154
225 Iron LRL liquid 0.03-2 mg/l Fe Ferrozine /
Thioglycolate 560
146,
156

12 MD610_2d 11/2019
* = free, combined, total; PP= powder pack; T= tablet;
L = liquid; TT= tube test; LR= low range; MR = middle range; HR= high range;
Vacu-vial®is a registered trade mark of CHEMetricsInc.
No. Analysis Reagent Range Displayed
as Method [nm] OTZ Page
226 Iron LR2 L liquid 0.03-2 mg/l Fe Ferrozine /
Thioglycolate 560 146,
160
227 Iron HRL liquid 0.1-10 mg/l Fe Thioglycolate 530 146,
164
240 Manganese T tablet 0.2-4 mg/l Mn Formaldoxime 530 168
242 Manganese LRPP PP+liquid 0.01-0.7 mg/l Mn PAN 560 – 170
243 Manganese HR PP PP+liquid 0,1-18 mg/l Mn Periodate
oxidation 2530 172
245 Manganese L liquid 0.05-5 mg/l Mn Formaldoxime 430 174
250 Molybdate T tablet 1-50 mg/l MoO4Thioglycolate4430 176
251 Molybdate LRPP PP 0,05-5 mg/l MoO4TernaryComplex 610 178
252 Molybdate HR PP PP 0.5-66 mg/l MoO4Mercaptoacetic
acid 430 180
254 Molybdate HRL liquid 1-100 mg/l MoO4Thioglycolate 430 182
257 Nickel T tablet 0.1-10 mg/l Ni Nioxime 560 184
260 Nitrate tablet +
powder 0.08-1 mg/l N Zincreduction
/ NED 530 186
265 Nitrate TT tube test 1-30 mg/l N
Chromotropic acid
430 – 188
270 Nitrite T tablet 0.01-0.5 mg/l N N-(1-Naphthyl)-
ethylendiamine2,3 560 190
272 Nitrite LRPP PP 0.01-0.3 mg/l N Diazotization 530 192
280 Nitrogen,
total
LRTT
tube test 0.5-25 mg/l N Persulfate
digestion method
430 – 194
281 Nitrogen,
total
HRTT
tube test 5-150 mg/l N Persulfate
digestion method
430 – 196
290
Oxygen, active T
tablet 0.1-10 mg/l O2DPD 530 200
292 Oxygen, dissolved Vacu-vial 10-800 μg/l O2Rhodazine DTM 530 – 202
300
Ozone (DPD) T
tablet 0.02-2 mg/l O3DPD/Glycine5530 204
70 PHMB T tablet 2-60 mg/l PHMB Bu󰀨er/Indicator 560 210
320 Phosphate, T
ortho LR tablet 0.05-4 mg/l PO4Ammonium-
molybdate
2,3
660 212,
214
321 Phosphate, ortho
HRT tablet 1-80 mg/l PO4Vanado
-
molybdate
2
430 212,
216
323 Phosphate, PP
ortho PP 0.06-2.5 mg/l PO4
Molybdate/
Ascorbic acid2
660 212,
218
324 Phosphate,ortho
TT tube test 0.06-5 mg/l PO4
Molybdate/
Ascorbic acid2
660 – 212,
220
327 Phosphate 1 C,
ortho Vacu-vial 5-40 mg/l PO4Vanado-
molybdate2430 – 212, 222
328 Phosphate 2 C,
ortho Vacu-vial 0.05-5 mg/l PO4Stannous
chloride2660 – 212, 224

13
MD610_2d 11/2019
No. Analysis Reagent Range Displayed
as Method [nm] OTZ Page
325 Phosphate, hydr.
TT tube test 0.02-1.6 mg/l P
Acid digestion,
Ascorbic acid2
660 – 212,
226
326 Phosphate,total
TT tube test 0.02-1.1 mg/l P
Acid persulf digestion,
Ascorbic acid2
660 – 212,
228
334 Phosphate LRL liquid 0.1-10 mg/l PO4
Phosphomolybdic
acid/Ascorbic acid
660 212,
230
335 Phosphate HR L liquid 5-80 mg/l PO4Vanado-
molybdate 430 212,
234
316
Phosphonate PP
PP 0-125 mg/l Persulfate
UV-Oxidation 660 – 238
329
pH-Value LRT
tablet 5.2-6.8 —
Bromocresolpurple5
560 242
330 pH-Value T tablet 6.5-8.4 — Phenolred5560 244
331 pH-Value L liquid 6.5-8.4 — Phenolred5560 246
332
pH-Value HRT
tablet 8.0-9.6 — Thymolblue5560 248
338 Polyacrylate L liquid 1-30 mg/ l
Polyacryl Turbidity 660 250
340 Potassium T tablet 0.7-16 mg/l K
Tetraphenylborate-
Turbidity4430 254
350 Silica T tablet 0.05-4 mg/l SiO2
Silicomolybdate
2,3
660 256
351 Silica LRPP PP 0.1-1.6 mg/l SiO2Heteropolyblue2660 – 258
352 Silica HR PP PP 1-90 mg/l SiO2Silicomolybdate2430 260
353 Silica L liquid +
powder 0.1-8 mg/l SiO2Heteropolyblue2660 262
212 Sodium
hypochlorite T tablet 0.2-16 % NaOCl Potassium iodide5530 264
355 Sulfate T tablet 5-100 mg/l SO4Bariumsulfate-
Turbidity 610 266
360 Sulfate PP PP 5-100 mg/l SO4Bariumsulfate-
Turbidity2530 268
365 Sulde tablet 0.04-0.5 mg/l S DPD/Catalyst3,4 660 270
370 Sulte T tablet 0.1-5 mg/l SO3DTNB 430 272
376 Surfactants, TT
(anionic) tube test 0.05-2 mg/l SDSA methylene blue6,1 660 – 274
377 Surfactants TT
(nonionic) tube test 0.1-7.5 mg/l Triton®X-100 TBPE6610 – 276
378 Surfactants TT
(cationic) tube test 0.05-1.5 mg/l CTAB disulne blue6,1 610 – 278
384 Suspended Solids direct
reading 0-750 mg/l TSS photometric 660 – 280
380 TOC LRTT tube test 5.0-80.0 mg/l TOC
H2SO4/Persulfate/
Indicator6610 – 282
* = free, combined, total; PP= powder pack; T= tablet;
L = liquid; TT= tube test; LR= low range; MR = middle range; HR= high range;
Vacu-vial®is a registered trade mark of CHEMetricsInc.

14 MD610_2d 11/2019
No. Analysis Reagent Range Displayed
as Method [nm] OTZ Page
381 TOC HRTT tube test 50-800 mg/l TOC
H2SO4/Persulfate/
Indicator6610 – 284
386 Turbidity direct
reading 10-1000 FAU
Attenuated
RadiationMethod
530 – 286
388 Tolyltriazole PP PP 1-16 mg/l Benzo
triazole
Catalysed UV
photolysis
430 288
390 Urea T tablet +
liquid 0.1-2.5 mg/l Urea Indophenol/ Urease 610 290
400 Zinc T tablet 0.02 -0.9 mg/l Zn Zincon 3610 – 292
405 Zinc L liquid +
powder 0.1 -2.5 mg/l Zn Zincon /EDTA 610 294
* = free, combined, total; PP= powder pack; T= tablet;
L = liquid; TT= tube test; LR= low range; MR = middle range; HR= high range;
Vacu-vial®is a registered trade mark of CHEMetricsInc.