
ProMinent®Page 11
1Description of chlorine dioxide system,
chemical principle and functional mode of system
Chemical principle of system
Hydrochloric acid chlorite process:
Sodium chlorite + hydrochloric acid →chlorine dioxide + sodium chloride + water
5NaClO2+ 4HCl →4ClO2+ 5NaCl + 2H2O
The Bello Zon®CDKa systems generate a 2 % chlorine dioxide solution (20 g/l ClO2) by combining
concentrated hydrochloric acid and concentrated sodium chlorite together with water (see
ch. 1.2.10). Immediately after production, the sodium chloride is fed to the water to be treated.
The dosage can be set both manually (internal control) or automatically (external control), by
using a flow signal and/or control setting.
Function of the system:
Three metering pumps driven by a programmed microprocessor control feed the components
acid, chlorite and water by way of hoses and three-way valves to the reactor. There they mix and
react, forming a 2 % chlorine dioxide solution. The feeding of the components to the reactor is
checked by flow monitors.
The chlorine dioxide solution flows through the metering valve into the bypass. From there the
pre-diluted ClO2is fed to the metering station.
Control of the metering pumps is carried out in the order “water”- “acid”- “chlorite”; the three
pumps work independently of each other and do not have to be adjusted for equal rates of
metering.
Flow monitors register when the metering pumps start stroking and this is indicated at the control.
If the flow monitor pulses fail, this is indicated after eight successive strokes and metering is
stopped. Should high excess pressure occur during correctly functioning flow monitoring, the
metering rate decreases and the system switches to “fault”.
Changes in parameters relevant to operation such as stroke length, pressure at metering valve,
etc. necessitate re-calibrating the rate of flow of the metering pumps.
Metering can be arrested at the control. Input signals are ignored in the arrest position “Standby”,
the pumps are not driven, and it is possible to change settings.
The intake lances or intake fittings (referred to below as “intake lances”in either case) leading
from the acid and chlorite tanks are equipped with a two-stage level switch. If the level of one of
the components falls, then a float in the level switch sinks to the middle position, and the control
displays the message “acid level low”or “chlorite level low”. If the float sinks to the lowest
position, then the system shuts down, and the control displays the message “Acid Cont. EMPTY”
or “Chlorite Cont. EMPTY”. In addition, there is a hose connected between the intake lance
“acid”and the reactor housing for venting (option: CDKa xA...). In this way acid fumes are
conducted to the reactor housing and do not pollute room air.
For the water supply tank there are two one-stage level monitoring devices. The refill time is
entered into the configuration menu. The level monitoring device “FULL”serves as a safety
device. After the level monitor switch “EMPTY”activates the refilling of water, there is a five-
second span of time until the system shuts down. This is a safety factor, in case, for example,
water fails to flow or the float gets caught.
There is an optional flow rate monitor built into the bypass (turbine wheel flow meter or variable-
area flow meter). If the rate of flow sinks below a minimal level, metering is stopped until the rate
of flow again exceeds the minimum rate. In case the system delivered does not contain a bypass
monitor (see ch. 1.1.1 “Identification code”), the user must ensure that during metering a
sufficient rate of flow through the bypass is guaranteed.
Description and Function