
ProMinent®Page 11
Introduction
1Introduction
The use of ozone has undergone a history of ups and downs since its discovery (by Schönbein
in 1840). In 1857 the ozone tube was invented by W. von Siemens. In 1873 Fox detected the
germ-killing effect of ozone, necessary for the use of this substance in the treatment of water.
At the turn of the century ozone was first introduced in waterworks for disinfection (at waterworks
in Schierstein, Wiesbaden, Paderborn). The ozone process was slowly becoming accepted; the
first large waterworks using ozone were constructed (Nizza in 1906, St. Maur, Paris in 1909,
St. Petersburg in 1910).
In the 1920s, use of ozone was replaced by the more economical and technically simpler indirect
chlorination. Although understood by then, the technological advantages of the ozone process
were slowly forgotten.
It was only in the 1950s that the “old” procedure was rediscovered. It came back into use not
only as a disinfectant, but also as an oxidation agent inside of treatment plants. At first it was
used in drinking water treatment, then it spread to the production of mineral water, and in the
1960s it became part of swimming pool technology.
Today ozone is used in many areas of water treatment, in processing exhaust and sewage and as
an oxidation agent in chemical reactions.
ProMinent recognised the significance of ozone technology very early and has been for years one
of the leading manufacturers of small and mid-sized ozone systems. Above all, new standards
have been set in the area of control technology and in the manufacturing of compact systems.
The systems in the Bono Zon®and OZONFILT®product lines stand for modern ozone technology.
1.1 Ozone
1.1.1 Properties of ozone
Ozone is an energy-rich modification of oxygen. In concentrated form it is a noticeably blue gas
that is about 1.5 times heavier than air. In the event of leakage, it can accumulate for this reason
in rooms located at a lower level.
Characteristic is the smell of ozone (Greek: “ozein” - to smell), which is perceptible even in
concentrations as small as 1 to 500,000. One notices the typical ozone smell often after powerful
flashes of lightening or near frequently used copying machines.
Ozone can be used to oxidise many chemical compounds, and this can be utilised in the treatment
and disinfection of drinking water, water for industrial use, swimming pool water and sewage.
A significant advantage of ozone as a disinfectant and oxidant is that it decomposes into oxygen,
which is already present in water.
Ozone in a gaseous state has a half-life of between 30 to 40 min., depending on the temperature.
When ozone is dissolved in water, its half-life is reduced to a few minutes.
DANGER
Ozone is poisonous! Concentrations of 10 g/m3are life-endangering and lead to difficulties
in breathing, irritation of the throat, unconsciousness within a short period of time.
The maximum concentration at place of work allowed by German regulations is 0.2 mg/m3.
1.1.2. Generation
Ozone is generated by silent electrical discharge. Using the ozonisator technique developed by
Siemens, air is lead between the two poles of a high voltage field. The oxygen in the air is
transformed into ozone in the presence of blue-violet light. Using common air as the input gas
mixture, it is possible to reach concentrations of approx. 20-35 g ozone/m3.
Necessary conditions for the faultless generation of ozone are dry air free of dust and a satisfactory
means of eliminating heat.
See fig. 1a: Principle of ozone generation and fig. 4: Mixing equipment.
The generation of ozone is influenced by the following factors:
•Volume flow of gas used (this also affects the concentration of ozone)
•high-voltage applied
•temperature of cooling water
•dewpoint of gas used