
2.2 Quality Of Effluent
If the hard water contains less than 500 ppm (about 30 grains) of calcium, magnesium and
sodium salts, all expressed as CaCO3, it will be found that the effluent from a softener will
contain an average of not more that 2 ppm actual total hardness (zero hardness by the soap
test). However, as the total cation concentration in the hard water increases above 500 ppm, the
average hardness in the effluent will also increase proportionately
The reason for this is that when the sodium salt - those present in the raw water plus those
formed by the exchange reactions - are present in high enough concentrations, they cause a
“back-regeneration” effect at the same time as the softening process is taking place. This effect
prevents as complete a removal of calcium and magnesium as would otherwise be possible.
It is often possible to reduce the average hardness in the effluent below normally expected
concentrations, by using a greater amount of salt than usual for regeneration. Normal Softening
Cycle - At the start of a normal softening cycle, the hardness in the effluent drops rapidly as
the residue of hardness ions left in the bed at the end of the rinse are forced out. The effluent
hardness reaches a certain minimum value and remains at approximately this concentration for
the major part of the softening run.
2.3 Capacity Of Ion Exchanger
The capacity for the removal of calcium and magnesium depends mainly upon the type of ion
exchanger which is used. It is further influenced by the amounts of hardness and sodium ions
in the raw water, and by the amount of salt used for regeneration.
Raw Water - The effect of the amounts of hardness and sodium ions in the raw water, is
expressed in terms of compensated hardness. The hardness of the raw water is considered
to be greater than it actually is for capacity determinations, whenever: (a) the total hardness is
greater than 400 ppm (as CaCO3), or (b) the sodium salts are over 100 ppm as (CaCO3). This
“greater-than-actual” hardness is referred to as compensated hardness.
Salt Dosage - The capacity, which will be obtained from a cation exchanger, is also determined
by the amount of salt used during regeneration. The grains of hardness, which can be removed
by each cubic foot of ion exchange, resin increases as more salt is used for regeneration.
At the same time, the efficiency of salt usage decreases with the higher regenerant dosages.
That is, a greater number of grains of hardness are removed for each pound of salt used at the
lower salt dosages, (and consequently, at the lower capacities). Thus, greater economy may
be obtained at the expense of the number of gallons of water softened between regenerations.