3M Designjet H35000 series Operating and maintenance instructions

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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Material Safety Data Sheet
Copyright, 2007, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M Black Inkjet Ink 5495
MANUFACTURER: 3M
DIVISION:
Commercial Graphics
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: [phone] or [phone] (24 hours)
Issue Date: 03/12/2007
Supercedes Date: Initial Issue
Document Group: 22-6739-1
Product Use:
Intended Use: Ink
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
TETRAHYDROFURFURYL ACRYLATE 2399-48-6 10 - 30
ISOOCTYL ACRYLATE 29590-42-9 10 - 25
ISOBORNYL ACRYLATE 5888-33-5 10 - 25
AMINE MODIFIED ACRYLATE OLIGOMER Unknown 5 - 25
ALIPHATIC URETHANE ACRYLATE Unknown 1 - 10
BENZOPHENONE 119-61-9 1 - 10
2,4,6-TRIMETHYLBENZOYLDIPHENYLPHOSPHINE 75980-60-8 1 - 10
1,6-HEXANEDIOL DIACRYLATE 13048-33-4 1 - 10
CARBON BLACK 1333-86-4 1 - 5
ACRYLIC ESTER Unknown 1 - 5
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Acrylate Odor, Black Color
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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explode. Hazardous polymerization may occur. May cause severe eye irritation. May cause allergic skin reaction. May cause
severe skin irritation. Contains a chemical or chemicals which can cause cancer.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Severe Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain.
Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
Carcinogenicity:
Contains a chemical or chemicals which can cause cancer.
Ingredient C.A.S. No. Class Description Regulation
CARBON BLACK 1333-86-4 Group 2B International Agency for Research on Cancer
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical
attention. Wash contaminated clothing and clean shoes before reuse.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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5.1 FLAMMABLE PROPERTIES
Autoignition temperature No Data Available
Flash Point > 200 ºF [Test Method: Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
5.2 EXTINGUISHING MEDIA
Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Water may not effectively extinguish fire; however, it should be used to keep fire-exposed
containers and surfaces cool and prevent explosive rupture. Wear full protective equipment (Bunker Gear) and a self-contained
breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical
ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains
and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and
authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the
resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of
collected material as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors,
mists or spray. Avoid skin contact. Avoid skin contact with hot material. Avoid eye contact with vapors, mists, or spray. Avoid
contact with oxidizing agents.
7.2 STORAGE
Store away from heat. Store out of direct sunlight. Store away from oxidizing agents.

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Provide local exhaust ventilation at transfer points. Provide appropriate local exhaust when product is heated. Use general dilution
ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist,
vapor, or spray. If ventilation is not adequate, use respiratory protection equipment.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact with vapors, mists, or spray.
The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles.
8.2.2 Skin Protection
Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact. Avoid skin
contact with hot material.
Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with
your glove and/or protective clothing manufacturer for selection of appropriate compatible materials.
Gloves made from the following material(s) are recommended: Nitrile Rubber.
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray.
Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with
OSHA regulations: Half facepiece or fullface air-purifying respirator with organic vapor cartridges. Consult the current 3M
Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Not applicable.
8.3 EXPOSURE GUIDELINES
Ingredient Authority Type Limit Additional Information
1,6-HEXANEDIOL DIACRYLATE AIHA TWA 1 mg/m3 Sensitizer
BENZOPHENONE AIHA TWA 0.5 mg/m3
CARBON BLACK ACGIH TWA 3.5 mg/m3 Table A4
CARBON BLACK CMRG TWA 0.5 mg/m3
CARBON BLACK OSHA TWA 3.5 mg/m3 Table Z-1
ISOOCTYL ACRYLATE 3M TWA 5 ppm
ISOOCTYL ACRYLATE AIHA TWA 5 ppm
TETRAHYDROFURFURYL ACRYLATE 3M TWA 0.1 ppm
TETRAHYDROFURFURYL ACRYLATE 3M STEL 0.3 ppm
SOURCE OF EXPOSURE LIMIT DATA:
ACGIH: American Conference of Governmental Industrial Hygienists
CMRG: Chemical Manufacturer Recommended Guideline
OSHA: Occupational Safety and Health Administration
AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL)
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Specific Physical Form: Liquid

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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Odor, Color, Grade: Acrylate Odor, Black Color
General Physical Form: Liquid
Autoignition temperature No Data Available
Flash Point > 200 ºF [Test Method: Closed Cup]
Flammable Limits - LEL No Data Available
Flammable Limits - UEL No Data Available
Boiling point > 200 ºF
Density 1.04 g/ml
Vapor Density > 1 [Ref Std: AIR=1]
Vapor Pressure < 10 mmHg [@ 20 ºC]
Specific Gravity 1.04 [Ref Std: WATER=1]
pH Not Applicable
Melting point Not Applicable
Solubility in Water Negligible
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents; Heat
Hazardous Polymerization: Hazardous polymerization may occur. (Upon depletion of inhibitor or exposure to heat)
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
Not determined.
CHEMICAL FATE INFORMATION
Not determined.

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number(s):
75-3470-7369-6
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
Contact 3M for more information.
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes
STATE REGULATIONS
Contact 3M for more information.
CALIFORNIA PROPOSITION 65
Ingredient C.A.S. No. Classification
CARBON BLACK 1333-86-4 **Carcinogen
** WARNING: contains a chemical which can cause cancer.
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
Contact 3M for more information.

3M MATERIAL SAFETY DATA SHEET 3M Black Inkjet Ink 5495 03/12/2007
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INTERNATIONAL REGULATIONS
Contact 3M for more information.
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 2 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
No revision information is available.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com