EST Centurion W User manual

Centurion W and WS Manual
Original Operating Instructions
Rev. 7.6

Notices
No part of this manual may be reproduced in any form or by any means (including electronic
storage and retrieval or translation into a foreign language) without prior agreement and written
consent of EST Analytical.
Version
Rev. 7.6
Printed in USA
EST Analytical
503 Commercial Dr.
Fairfield OH, 45014 USA
Acknowledgements
Encon® is a registered trademark of EST Analytical
Tekmar® LSC2000 and Tekmar® LSC3000 are registered trademarks of Teledyne
Technologies, Inc.
OI®4460, 4560 and 4660 are registered trademarks of OI Analytical, Inc.
Windows®.Net is a registered trademark of the Microsoft Corp.
Trademark information is accurate to the best of our knowledge at the time of printing.
The symbol marked on the product indicates compliance with the requirements of
CAN/CSAC22.2 No.61010.1, 2nd edition, including Amendment 1.

Warranty
The material contained in this document is provided “as is”, and is subject to being changed
without notice, in future editions. EST Analytical warrants the products it manufactures and
distributes, except those specially exempted, to be free from defects for (1) full year from the
date of shipment. This warranty is limited to the original purchaser of the product and is not
transferable. This limited warranty does not extend to any products that have been damaged as a
result of accident, misuse, abuse, or service or modification by anyone.
Except as expressly set forth above, no other warranties are expressed or implied including, but
not limited to, any implied warranties merchantability and fitness for a particular purpose, and
EST expressly disclaims all warranties not stated herein. In the event the product is not free
from defect as warranted above, the purchaser’s sole remedy shall be provided above. Under no
circumstances will EST Analytical be liable to the purchaser or any user for any damages,
including the incidental or consequential damages, expenses, lost profits, lost savings or other
damages arising out of the use or inability to use the product. This warranty shall not be
applicable to the extent that any provision of this warranty is prohibited by any federal, state, or
municipal law that cannot be preempted.
Federal Communications Commissions advisory:
This equipment has not been tested or found to comply with the limits of Class A computing
device, pursuant to part 15 of the FCC Rules. These limits are designed to provide reasonable
protection against harmful interference when the equipment is operated in a commercial
environment. This equipment generates, uses, and can radiate radio frequency energy and, if not
installed and used in accordance with the instruction manual, may cause harmful interference to
radio communications. Operation of this equipment in a residential area is likely to cause
harmful interference in which case the user will be required to correct the interference at his
expense.
CAUTION
A CAUTION notice denotes a hazard. It calls attention to an operating procedure, practice, or
the like that, if not properly performed or adhered to, could result in damage. Do not proceed
beyond a CAUTION notice until the indicated conditions are completely understood and met.
ATTENTION
La mention ATTENTION signale un danger. Il attire l'attention sur une procédure
d'exploitation, la pratique ou la comme ça, s'il n'est pas correctement effectuée ou respectée, peut
entraîner des dommages. Ne pas aller au-delà d'une mention ATTENTION jusqu'à ce que les
conditions indiquées sont complètement comprises et respectées.

WARNING
AWARNING notice denotes a hazard. It calls attention to an operating procedure or practice,
or the like that, if not properly performed or adhered to, could result in personal injury of death.
Do not proceed beyond a WARNING notice until the indicated conditions are completely
understood and met.
AVERTISSEMENT
La mention AVERTISSEMENT signale un danger. Il attire l'attention sur une procédure ou une
pratique exploitation, ou le comme ça, s'il n'est pas correctement effectuée ou respectée, peut
entraîner des blessures de la mort. Ne pas aller au-delà d'une mention AVERTISSEMENT
jusqu'à ce que les conditions indiquées sont complètement comprises et respectées.

Introduction
…………………………………………………………Chapter 1
1.1 Product Description
1.2 Design Features
1.3 Product Specifications
1.4 Warnings and Symbols
1.5 Disposal and Recycling Information
Centurion W/S Installation and Setup
…………………………………………………………Chapter 2
2.1 General Information
2.2 Work Space Requirements
2.3 Power Requirements
2.4 Unpacking the Centurion
2.5 Centurion Setup/Installation
2.5.1 Connections on the Back of the Centurion
2.5.2 Water Reservoir and Cap Assembly
2.5.3 Feed Gas Installation
2.5.4 Interface Connection
2.5.5 Monitor Setup
2.5.6 Power Connection
2.5.7 Vial Storage Trays
2.5.8 Internal Standard Reservoir Installation
2.5.9 Pressurize System
2.5.10 Instrument Start-up
2.5.11 Water and Soil Axis Calibration
2.5.12 Method Build
2.5.13 System Set-up Complete
Centurion W/S Operation
…………………………………………………………Chapter 3
3.1 Powering on Centurion W/S
3.2 Opening the Centurion W/S Application
3.3 Powering off the Centurion W/S
3.4 Main Screen
3.5 Diagnostics Screen
3.6 Home/Logon Screen
3.7 Exit Icon

3.8 Options Screen
3.8.1 Instrument Tab
3.8.2 System Setup
3.8.3 User Accounts
3.9 Sequence Screen
3.9.1 Concentrator #1
3.9.2 Populating the Sequence Table
3.9.3 Run Setup
3.10 Method Screen
3.10.1 General Setup
3.10.2 Internal Standards Tab
3.10.3 Soil Sample Tab (OPTION)
3.11 Run Status Screen
3.12 Run Log Screen
3.13 Help Screen
User Maintenance and Troubleshooting
……………………………………………………………Chapter 4
4.1 Technical Support Contact Information
4.2 Cleaning the Centurion W/S
4.3 Filling the Water Reservoir
4.4 Diagnostics Screen
4.4.1 E-Stop
4.4.2 Flow Pathway Dropdown Menu
4.4.3 Icons
4.4.4 Vial Position
4.4.5 Manual Heater Control
4.4.6 Manual Movement Control
4.5 Manual Functions
4.5.1 Rinse Functions
4.5.2 Drain Sparge Tube
4.5.3 Internal Standards
4.5.4 Sweep Soil Needle
4.5.5 Mechanical Test
4.5.6 Syringe Maintenance

4.6 Calibration Functions
4.6.1 Auto Calibration
4.6.2 Manual Calibration
4.6.3 Syringe Calibration
4.6.4 Heater Calibration
4.6.5 Digital Input/Output
4.6.6 Internal Standard Calibration
4.6.7 Stirrer Calibration
4.7 Leak Checking the Soil Pathway
4.8 Replacement of Sampling Station Needle
4.9 Removal/Installation of Water Needle
4.10 Fuse Replacement
4.11 Spare Parts
Flow Diagrams
……………………………………………………………Chapter 5
Appendix A Instructions for the Water and Methanol Extraction
Feature
Appendix B Installation of the Centurion W or WS to an OI 4660
Concentrator
Appendix C Installation of the Centurion W or WS to a Tekmar
Stratum Concentrator
Appendix D Installation of the Centurion W or WS to a Tekmar
3000/3100 Concentrator

User Manual
Introduction
Chapter 1

1.1 Product Description
The EST Centurion W and WS Purge and Trap Autosamplers are designed to automate
the tedious sample handling procedures associated with purge and trap analysis for
volatile organic compounds (VOC's) under current EPA methods. The EST Centurion
can be used for water and soil (optional) matrices and is designed as a stand-alone unit
for retrofit to any manufactured purge and trap concentrator. Laboratories in today’s
market have enormous challenges to reduce cost and improve productivity. The EST
Centurion provides the flexibility to meet these needs.
The EST Centurion W and WS are a state-of-the art robotic, X-Y-Z axis autosampler
with a unique Windows XPe™operating platform. The Autosampler has 100 sample
positions, (90 soil), with 2 removable 50 position trays. A vial cooling option is available
which allows the vials to be cooled to below 10°C.
To process a water sample, the 40ml VOA vial is placed in the tray. The Centurion W or
WS robotic arm moves to the programmed vial location and the sample needle is lowered
into the sample vial to a calibrated depth. The sample vial is pressurized, transferring the
sample from the vial through an inert pathway filling a fixed volume sample loop. The
overflow is carried out to waste. The internal standard is injected into the sample stream
and the sample is transferred to the sparge vessel located on the concentrator.
The syringe option for the Centurion W or WS autosampler allows automated sample
dilutions. The dilution range is from 2x to 400x. The Centurion W or WS robotic arm
moves to the vial location as described previously. Next, an aliquot of sample is pulled
from the vial and diluted using the chosen dilution factor, the sample is then sent through
an inert sample pathway, injected with internal standard and transferred to the sparge
vessel on the concentrator. The syringe option also provides the capability to sample
volumes from 5mls to 25mls in 1ml increments.
To process a soil sample, the 40ml VOA vial is placed in the tray. The Centurion WS
robotic arm moves to the programmed vial location. Unlike the water vial which stays in
the sample tray, in the soil mode, the vial is transported to the soil cup. In the soil cup,
internal standard can be transferred into blank water through the fixed volume loop to the
sample. The sample can then be heated, stirred and purged to your specifications.
Finally, the analytes purged out of the sample are transferred to the concentrator through
a heated transfer line.
The Centurion W or WS autosampler will rinse the sample pathway with hot water for
cleaning in preparation of the next sample. The number of rinses and rinse time for the
sample needle and sample loop are programmable. The Centurion W or WS can have two
distinct modes of operation. They are the Single Concentrator and Dual Concentrator
(optional) modes. The single concentrator mode will allow the vial autosampler to run
with one purge and trap concentrator. The optional Dual concentrator mode will allow the
Centurion W or WS autosampler to process and deliver water and soil samples to two
purge and trap concentrators on an efficient alternating basis. The Dual Mode

significantly increases the sample throughput of the Autosampler. There is no need to
purchase a second autosampler. All modes perform per their programmed method.
The EST Centurion W or WS is easily programmed through their own keyboard and
mouse. The Centurion W or WS has two USB ports for the keyboard and mouse.
Programming is menu driven and displayed on a color monitor. Parameters can be read
and altered and the screen displays the function in progress during the run.
The Centurion W or WS when connected to an EST Encon Evolution concentrator
further enhances cost savings and improves sample throughput with the Foam Sensor
option on the Evolution. The Centurion W or WS works with the Evolution to rinse the
sparge tube with a pre-programmed number of hot water rinses whenever a foaming
sample is detected. This option prevents the accidental transfer of a foamed sample to the
GC column which can result in down time and costly repairs.
NOTE: For clarification purposes, the use of the word Centurion throughout the
manual shall refer to both the Centurion W and WS.
1.2 Design Features
Dual 50 position removable sample trays for 40ml VOA vials.
Rugged X-Y-Z platform.
Windows XPe™operating platform.
Runs blanks from its own blank/wash water reservoir.
Sample Loop sizes range from 5, 10, 15, 20 or 25ml.
Syringe Option, allows dilutions from 2x to 400x and sample sizes from 5mls to 25mls
in 1ml increments.
All sample pathways are chemically inert, manufactured from PEEK®, Stainless Steel,
or Teflon.
Separate needles for the soil and water modes thus minimizing carryover between the
two matrices.
Built in Minimizer Valve aiding in the removal of contamination on the soil side by
diverting some of the bake flow from the concentrator through the soil pathway of the
Centurion.
Programmable volume addition of Internal Standards/Surrogates.
Optional sample tray cooling capability. Optional refrigerated chiller is required.
Priority Sample feature allows the current analysis to be interrupted for RUSH
samples.
Fast easy programming from the keyboard/mouse combination.
Programmable methods may be stored for various method configurations.
A sample may be run from any position in the tray.

Easy hook up and installation to all manufactured purge and trap systems.
Hot water rinse utilizes a cartridge heater to heat blank water to 90C prior to flushing
sample pathways and the purge vessel.
Optional Dual concentrator mode for both water and soil matrices.
Optional Dual GC mode.
1.3 Product Specifications
Tray Capacity: 100 sample vials. 40 ml EPA VOC
Sample Volume: 5, 10, 15, 20, 25ml sample loop, 5 to 25ml volume
syringe (1ml increments for syringe)
Indoor Use
Altitude: Up to 2000 m
Operating
Temperature: 15C to 25C; Storage Temperature 5C to 85C
Relative Humidity: 10 to 90%
Voltage: 115/230VAC (10%), 50/60Hz
Current: Model115VAC230VAC
Current(A)Current(A)
CenturionW4.02.0
CenturionWS8.05.0
Battery:
Installation Category:
CR2032 battery contained on SBC (CPU) board
II
Pollution Degree: 2
Weight: Approximately 80 lbs; 36.5 Kilograms
Size: 24.5”W (62.2 cm) x 27”D (68.6 cm) x 25” H (63.5 cm)
Gas Requirements: Helium or Nitrogen 60-80 PSI (414-552kPa) 99.999%
GC/MS grade purity; BTU/hr. = NA (compressed gas
used for pressurization only)

1.4 Warnings and Symbols
English
Warnings in the manual or on the Centurion to be observed during installation, operation,
service and/or repair of the instrument. EST Analytical will assume no responsibility for
customers failing to comply with the safety precautions stated.
Use of the Centurion for something other than the intended use of the instrument is
prohibited.
The use of the Centurion is for trained personnel only.
Personnel operating the Centurion should wear safety glasses and gloves where
appropriate.
The Centurion is not intended for use in a hazardous environment.
Installation of the Centurion requires that there is nothing blocking the vents of the
system.
Installation of the Centurion requires that the instrument be placed on a non-flammable
surface capable of handling the weight of the instrument.
Heaters and heated transfer line(s) require surrounding space to be non-combustible
material.
Sound pressure level of the Centurion is 65db (A).
When cleaning the Centurion please refer to section 4.2 of the User Manual. No other
cleaning agents may be used other than what is specified in this section.
Français
Les avertissements dans le manuel ou sur le Centurion à respecter lors de l'installation , le
fonctionnement , le service et / ou la réparation de l'instrument . EST analytique n'assume
aucune responsabilité pour les clients qui ne respectent pas les consignes de sécurité
indiquées .
Utilisation du Centurion pour autre chose que l'utilisation prévue de l'instrument est
interdite.
L'utilisation du Centurion est de personnel qualifié seulement .
Le personnel d'exploitation du Centurion doivent porter des lunettes de sécurité et des
gants le cas échéant .
Le Centurion n'est pas destiné à être utilisé dans un environnement dangereux .
L'installation du Centurion exige que rien ne bloque les évents du système .
Montage du Centurion nécessite que l'instrument est placé sur une surface non
inflammable capable de supporter le poids de l'instrument.
Chauffe et ligne de transfert chauffée (s) nécessitent de l'espace environnant à un
matériau incombustible .
le niveau de la Centurion de pression sonore est de 65db ( A) .
Lors du nettoyage du Centurion s'il vous plaît se référer à la section 4.2 du Manuel de
l'utilisateur . Pas d'autres agents de nettoyage peuvent être utilisées autrement que ce qui
est spécifié dans cette section.

See Accompanying Instructions for more Information
Voir les instructions d'accompagnement pour plus d'informations
Indicates an Electrical Hazard
Indique un danger électrique
Indicates Hot Surface
Indique surface chaude
Indicates a Risk of Hand Entanglement
Indique un risque d'étranglement pour les mains
Indicates a Sharp Point
Indique une pointe acérée

Indicates Bulky/Heavy Item, Use Two Person Lift
Indique objet volumineux / lourds, utilisez deux personnes ascenseur
1.5 Disposal and Recycling Information
United States:
This symbol indicates that your product must be disposed of properly according
to local laws and regulations. When your product reaches its end of life, contact
your local authorities to learn about recycling options.
European Union:
This symbol above means that according to local laws and regulations your product should be
disposed of separately from household waste. When this product reaches its end of life, take it to
a collection point designated by local authorities. Some collection points accept products for
free. The separate collection and recycling of your product at the time of disposal will help
conserve natural resources and ensure that it is recycled in a manner that protects human health
and the environment.

User Manual
Installation and Setup
Chapter 2

2.1 General Information
The system setup and installation section is intended to be as thorough as possible. If in-
doubt at any point, please contact EST Analytical toll free at [phone]. If
installation is not directed or performed by EST Analytical personnel, the operator must
be thoroughly familiar with setup and installation sections of this manual.
NOTE: Failure to follow the installation instructions as set forth could result in
damage to the product and nullify the warranty.
2.2 Work Space Requirements
The Centurion foot print is 24.5”W (62.2 cm) x 27”D (68.6 cm) x 25” H (63.5 cm).
NOTE: Allow for added space on all sides of the instrument for proper ventilation.
2.3 Power Requirements
Voltage:
115/230 VAC (+/- 10%)
50/60 Hz
8.0/5.0 Amps
15/20A circuit breaker
2.4 Unpacking the Centurion
Figure 2a: Shipping Container
The Centurion is packaged in one Carton containing all components necessary for
instrument installation and operation.
NOTE: Retain all shipping material.

Before un-strapping the Centurion Box, visually inspect the shipping carton for any
damage. Call EST Analytical at [phone] immediately if visual damage is present.
Cut the strapping and lift the top box cover off the box and put aside. Lift the outer box
shell off the Centurion and put aside. Remove the excess foam packing material from the
top of the Centurion and put aside.
Figure 2b: Instrumentation Packing 1
Remove the two boxes inside of the Centurion main body. Box #1 contains the vial
storage trays. Box #2 will contain the installation kit, I/O cable, keyboard, mouse,
internal standard vessel, and power cord.
Figure 2c: Instrumentation Packing 2

With the help of another person tilt the Centurion on one side and remove the
foam inserts. The Centurion in now ready to place on the bench. With one person on
EACH side of the Centurion transfer the Centurion to the bench.
NOTE: The Centurion needs to be lifted from the base of the instrument.
WARNING: The Centurion needs enough space on all sides of the instrument to
ensure proper cooling of instrument components AND to ensure that the power cord
can be easily disconnected.
AVERTISSEMENT: Le Centurion besoin de suffisamment d'espace sur tous les
côtés de l'appareil pour assurer le bon refroidissement des composants de
l'instrument et de veiller à ce que le cordon d'alimentation peut être facilement
déconnecté.
2.5 Centurion Setup/Installation
2.5.1 Install all connections at the rear of the instrument:
Keyboard-grey USB cable, see Figure 2d.
Mouse-white USB cable, see Figure 2d.
Figure 2d: Centurion Keyboard, Mouse and Interface Connections
Waste (W)-Black Tubing, see Figure 2e.
oFlangeless Nut-Green
oFlangeless Ferrule-PEEK

Figure 2e: Waste Line
Concentrator (1)-PEEK Tubing, see Figure 2e and 2f
oSuper Flangeless Nut-black
oSuper Flangeless Ferrule-ring/PEEK ferrule
oConnect to Concentrator (1) three way valve-green nut and
natural ferrule.
Figure 2f: Water Transfer Line Connection to Concentrator
Concentrator (2)-if applicable, same connections as Concentrator (1).
Concentrator (1)-Soil Purge Gas Line Connections – If Applicable.
(Note: Shipped as an assembly.)
oConnect PEEK tubing (red) to Concentrator (1) purge bulkhead
with Upchurch nut and Ferrule. See Figure 2g.