wtw inoLab pH/Oxi Level 1 User manual

inoLab
pH/Oxi Level 1
ba12231e03 10/2002 65
Operating Manual
Measuring Instrument
for pH and Dissolved Oxygen

Accuracy when
going to press
The use of advanced technology and the high quality stan-
dard of our instruments are the result of continuous develop-
ment. This may result in differences between this operating
manual and your instrument.
We cannot guarantee that there are absolutely no errors in
this manual. We are sure you will understand that we cannot
accept any legal claims resulting from the data, figures or
descriptions.
Warranty
declaration
The designated instrument is covered by a warranty of three
years from the date of purchase.
The instrument warranty extends to manufacturing faults
that are determined within the period of warranty.
The warranty excludes components that are replaced during
maintenance such as batteries, etc.
The warranty claim extends to restoring the instrument to
readiness for use but not, however, to any further claim for
damages. Improper handling or unauthorized opening of the
instrument invalidates any warranty claim.
To ascertain the warranty liability, return the instrument and
proof of purchase together with the date of purchase freight
paid or prepaid.
Copyright ©Weilheim 2002, WTW GmbH & Co. KG
Reprinting - even as excerpts - is only allowed with the ex-
plicit written authorization of WTW GmbH & Co. KG,
Weilheim.
Printed in Germany.

List of contents
67
1 Overview . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
1.1 Keypad . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .70
1.2 Display . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .71
1.3 Sockets . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .71
1.4 Operating structure . . . . . . . . . . . . . . . . . . . . . .72
2 Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 73
2.1 Authorized use . . . . . . . . . . . . . . . . . . . . . . . . .74
2.2 General safety instructions . . . . . . . . . . . . . . . .74
3 Commissioning . . . . . . . . . . . . . . . . . . . . . . . . 77
4 Operation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
4.1 Switch on the instrument . . . . . . . . . . . . . . . . . .79
4.2 Measuring the pH value/Redox voltage . . . . . .80
4.2.1 Measuring the pH value . . . . . . . . . . . . .82
4.2.2 AutoRead AR (drift control) . . . . . . . . . .82
4.2.3 Measuring the Redox voltage . . . . . . . . .83
4.3 Calibrating for pH measurements . . . . . . . . . . .84
4.3.1 AutoCal TEC . . . . . . . . . . . . . . . . . . . . .86
4.3.2 AutoCal DIN . . . . . . . . . . . . . . . . . . . . . .88
4.3.3 ConCal . . . . . . . . . . . . . . . . . . . . . . . . . .90
4.4 Measuring the dissolved oxygen . . . . . . . . . . . .93
4.4.1 Oxygen concentration . . . . . . . . . . . . . .94
4.4.2 Oxygen saturation . . . . . . . . . . . . . . . . .95
4.4.3 Oxygen partial pressure . . . . . . . . . . . . .96
4.4.4 AutoRead AR (drift control) . . . . . . . . . .96
4.5 Calibrating for D. O. measurements . . . . . . . . .98
4.5.1 Starting the calibration . . . . . . . . . . . . .100
4.5.2 Entering the salt content (salinity) . . . .102
4.6 Configuration . . . . . . . . . . . . . . . . . . . . . . . . . .103
4.7 Reset . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .105
5 Maintenance, cleaning, disposal . . . . . . . . . 107
5.1 Maintenance . . . . . . . . . . . . . . . . . . . . . . . . . .107
5.2 Cleaning . . . . . . . . . . . . . . . . . . . . . . . . . . . . .108

List of contents
68
5.3 Disposal . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .108
6 What to do if... . . . . . . . . . . . . . . . . . . . . . . . . 109
6.1 pH system messages . . . . . . . . . . . . . . . . . . .109
6.2 Oxygen system messages . . . . . . . . . . . . . . .111
6.3 General errors . . . . . . . . . . . . . . . . . . . . . . . . .113
7 Technical Data . . . . . . . . . . . . . . . . . . . . . . . . 115
7.1 General data . . . . . . . . . . . . . . . . . . . . . . . . . .115
7.2 pH/Redox measurement . . . . . . . . . . . . . . . . .117
7.3 Oxygen measurement . . . . . . . . . . . . . . . . . . .118
8 Lists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
9 Appendix . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127

Overview
69
1Overview
The compact inoLab pH/Oxi Level 1 precision measuring in-
strument lets you perform pH, Redox, and D. O. measure-
ments rapidly and reliably. The inoLab pH/Oxi Level 1
provides the highest degree of operating comfort, reliability
and measuring safety for all applications.
The proven OxiCal®and MultiCal®calibration procedures
and special AutoRead function support your work with the
instrument.
Note
The measuring instrument can also be delivered as part of
a set.
Information on this and other accessories is available in the
WTW catalog LABORATORY AND FIELD INSTRUMENTATION or
via the Internet.
1Keypad
2Display
3Sockets
3
2
1

Overview
70
1.1 Keypad
1Measuring instrument ON/OFF
2Select measuring mode
3Call up calibration procedure
4Activate/deactivate AutoRead
5Confirm inputs, start AutoRead
6Select measuring mode, increase values,
scroll
7Select measuring mode, reduce values,
scroll
4
3
2
1
7
6
5

Overview
71
1.2 Display
1.3 Sockets
Caution
Only connect probes to the instrument that cannot feed ex-
cessive voltages or currents (> SELV and > circuit with cur-
rent limiter).
Almost all commercial probes - especially WTW probes -
meet these requirements.
Connectors:
1Dissolved oxygen probe
2pH/Redox electrode
3Temperature probe
4Stirrer (StirrOx G)
5Reference electrode
6Mains power supply (option)
S
tatus
li
ne
Measured value display
Function and
temperature display
Probe symbol
1
5
6

Overview
72
Caution
On socket 4, use the WTW probe StirrOx G only.
1.4 Operating structure
The following overview diagram shows which keys you have
to press to select between the different measuring modes:
Note
The oxygen concentration, oxygen saturation, and oxygen
partial pressure measuring modes only appear if a D. O.
probe with temperature probe is connected to the instru-
ment.
Note
When a D. O. probe with temperature probe is connected,
the measuring instrument recognizes the probe and auto-
matically switches to the previously selected oxygen mea-
suring mode. As soon as the probe is disconnected, the
instrument switches to the pH or Redox measuring mode.

Safety
73
2 Safety
This operating manual contains basic instructions that you
must follow during the commissioning, operation and main-
tenance of the instrument. Consequently, all responsible
personnel must read this operating manual before working
with the instrument.
The operating manual must always be available within the
vicinity of the instrument.
Target group This measuring instrument was developed for use in the lab-
oratory.
Thus, we assume that, as a result of their professional train-
ing and experience, the operators will know the necessary
safety precautions to take when handling chemicals.
Symbols used
Caution
indicates instructions that have to be followed to prevent
damage to your instrument.
Warning
indicates instructions that have to be followed to protect
yourself and the instrument from dangerous electrical volt-
age.
Note
Indicates notes that draw your attention to special features.
Note
Indicates cross-references to other documents, e.g. appli-
cation reports, operating manuals of electrodes, etc.

Safety
74
2.1 Authorized use
This instrument is authorized exclusively for measuring the
pH, Redox, and dissolved oxygen in the laboratory.
The technical specifications as given in the chapter 7 TECH-
NICAL DATA must be observed. Only the operation and run-
ning of the measuring instrument according to the
instructions given in this operating manual is authorized.
Any other use is considered unauthorized.
2.2 General safety instructions
This instrument is constructed and tested in compliance with
the EN 61010-1 safety regulations for electronic measuring
instruments.
It left the factory in a safe and secure technical condition.
Function and opera-
tional safety
The smooth functioning and operational safety of the instru-
ment can only be guaranteed if the generally applicable
safety measures and the specific safety instructions in this
operating manual are followed.
The smooth functioning and operational safety of the instru-
ment can only be guaranteed under the climatic conditions
specified in the chapter 7 TECHNICAL DATA.
If the instrument was transported from a cold environment to
a warm environment, the formation of condensate can lead
to the faulty functioning of the instrument. In this event, wait
until the temperature of the instrument reaches room tem-
perature before putting the instrument back into operation.
Caution
The instrument is only allowed to be opened by personnel
authorized by WTW.

Safety
75
Safe operation If safe operation is no longer possible, the instrument must
be taken out of service and secured against inadvertent op-
eration.
Safe operation is no longer possible if:
lthe instrument has been damaged in transport
lthe instrument has been stored under adverse conditions
for a lengthy period of time
lthe instrument is visibly damaged
lthe instrument no longer operates as described in this
manual
If you are in doubt contact the supplier of the instrument.
Obligations of the
operator
The operator of this measuring instrument must ensure that
the following laws and guidelines are observed when using
dangerous substances:
lEEC directives for protective labor legislation
lNational protective labor legislation
lSafety regulations
lSafety datasheets of the chemical manufacturer

Safety
76

Commissioning
77
3 Commissioning
Note
You can adapt individual parameters to your requirements.
To do so, change the default settings according to section
4.6 CONFIGURATION.
Connecting the
plug-in power
supply (optional)
The measuring instrument works battery-powered. It can,
however, also be supplied by the plug-in power supply
which is available as an accessory.
Warning
The line voltage on site must lie within the input voltage
range of the original plug-in power supply unit (see chapter
7 TECHNICAL DATA).
Caution
Use original plug-in power supplies only
(see chapter 7 TECHNICAL DATA).
Note
If a stirrer is operated via the measuring instrument, it is
essential to use the plug-in power supply.
1Insert the plug (1) into the socket (2) of the meter.
2 Connect the original WTW plug-in power supply (3) to
an easily accessible mains socket.
1
2
3

Commissioning
78
Scope of delivery lLaboratory measuring instrument, inoLab pH/Oxi Level 1
lOperating manual and short manual
l4 x type AA Mignon 1.5 V batteries

Operation
79
4Operation
4.1 Switch on the instrument
Note
The instrument has an energy saving feature to avoid
unnecessary battery depletion.
The energy saving feature switches the instrument off if no
key has been pressed for an hour.
The energy saving feature is not active if the instrument is
supplied by the plug-in power supply.
1Place the instrument on a flat surface and protect it
against intense light and heat.
2 Press the ekey.
The display test appears briefly on the display.
The instrument then switches automatically to the
previously selected measuring mode.

Operation
80
4.2 Measuring the pH value/Redox voltage
Preparatory
activities
Perform the following preparatory activities when you want
to measure:
Note
Incorrect calibration of the pH electrode will result in
incorrect measured values. Therefore, regularly perform
calibration before measuring.
Temperature probe Measurements can be performed with and without a
temperature probe. A connected temperature probe is
indicated by TP on the display.
Note
If you use a pH electrode without a temperature probe, the
instrument is able to use the temperature probe of a D. O.
probe that is also connected to the instrument and is
immersed in the test sample. You have to set up this as
described in section 4.6 CONFIGURATION. The TP display
indicator flashes when the temperature probe of the D. O.
probe is used.
1Press the mkey repeatedly until the pH/Redox
measurement appears on the display.
2 Connect the electrode to the instrument.
3Adjust the temperature of the buffer or test solutions
or measure the current temperature if the
measurement is made without a temperature probe.
4 Calibrate or check the instrument with the electrode.
5Select the measuring mode by pressing m.

Operation
81
The temperature measurement is absolutely essential for a
reproducible pH measurement. If the measurement is made
without a temperature probe, proceed as follows:
Note
When calibrating without a temperature probe, set up the
current temperature of the respective buffer solution
manually using the u d keys while pressing and holding
down the gkey.
1Determine the current temperature using a
thermometer.
2 Press and hold down the gkey and set up the
temperature using u d.

Operation
82
4.2.1 Measuring the pH value
4.2.2 AutoRead AR (drift control)
The AutoRead function (drift control) checks the stability of
the measurement signal. The stability has a considerable
effect on the reproducibility of the measured values.
For identical measurement conditions, the following criterion
applies:
lpH value: better than 0.02 (response time: > 30 s)
1Perform the preparatory activities according to
section 4.2.
2 Immerse the pH electrode into the test sample.
3Press the uor dkey until pH appears in the status
display. The pH value appears on the display.
1Call up the pH measuring mode by pressing u d.
2 Immerse the pH electrode into the test sample.
3Activate the AutoRead function by pressing a.
The current measured value is frozen (Hold function).
4 Start the AutoRead function by pressing g.
AR flashes on the display until a stable measured
value is reached.
5If necessary, start the next AutoRead measurement
by pressing g.
6 To terminate the AutoRead function: Press a.

Operation
83
Note
The current AutoRead measurement (with acceptance of
the current value) can be terminated at any time by pressing
g. It is only possible to change to another measuring mode
after AutoRead has been terminated.
4.2.3 Measuring the Redox voltage
The instrument can measure the Redox voltage (mV) of a
solution when connected with a Redox electrode, e.g.
SenTix ORP.
Note
The AutoRange function is always active and automatically
switches to the measuring range with the highest resolution.
Note
Redox electrodes are not calibrated. However, you can
check Redox electrodes using a test solution.
1Perform the preparatory activities according to
section 4.2.
2 Immerse the Redox electrode into the test sample.
3Press the u d key repeatedly until U appears in the
status line.
The Redox voltage (mV) of the sample appears on
the display.
4 Wait for a stable measured value.

Operation
84
4.3 Calibrating for pH measurements
Why calibrate? pH electrodes age. This changes the asymmetry (zero
point) and slope of the pH electrode. As a result, an inexact
measured value is displayed. Calibration determines the
current values of the asymmetry and slope of the electrode
and they are stored in the instrument.
Thus, you should calibrate at regular intervals.
Note
Always calibrate after connecting another pH electrode.
You can choose between 3 calibration procedures:
AutoCal TEC is specially adapted to the WTW technical buffer solutions
as a fully automatic two-point calibration. The buffer
solutions are automatically recognized by the instrument.
AutoCal DIN is specially adapted to permanently programmed buffer
solutions according to DIN 19266 as a fully automatic two-
point calibration. The buffer solutions are automatically
recognized by the instrument.
ConCal is the conventional two-point calibration with 2 freely
selectable buffer solutions or single-point calibration as the
rapid method.
AutoRead In calibration using AutoCal TEC and AutoCal DIN, the
AutoRead function is automatically activated.
The current AutoRead measurement (with acceptance of
the current value) can be terminated at any time by pressing
g.
Calibration
evaluation
After the calibration, the instrument automatically evaluates
the current status. The asymmetry and slope are separately
evaluated. The worst evaluation appears on the display.