Hanna Instruments HI 96831 User manual

HI96831
Ethylene Glycol Refractometer
INSTRUCTION MANUAL

All rights are reserved. Reproduction in whole or in part is prohibited
without the written consent of the copyright owner, Hanna Instruments
Inc., Woonsocket, Rhode Island, 02895, USA.
Thank you for choosing a Hanna Instruments product.
Please read this instruction manual carefully before using
this instrument.
This manual will provide you with the necessary informa‑
tion for correct use of this instrument, as well as a precise
idea of its versatility.
If you need additional technical information, do not
hesitate to e‑mail us at [email protected] or view our
worldwide contact list at www.hannainst.com.
Dear
Customer,

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Preliminary Examination ........................................................
General Description................................................................
Specifications........................................................................
Principle of Operation............................................................
Measurement Units...............................................................
Functional Description............................................................
Display Elements...................................................................
Measurement Guidelines........................................................
Calibration Procedure.............................................................
Measurement Procedure.........................................................
To Change Measurement Unit.................................................
To Change Temperature Unit .................................................
Making a Standard Solution..................................................
Battery Replacement.............................................................
Error messages............................................................................
Accessories............................................................................
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5
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9
10
14
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10
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TABLE OF CONTENTS
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11
16
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18
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Remove the instrument from the packing materials and examine
carefully to ensure no damage has occurred during shipping. If any
damage has occurred, please contact your local Hanna Instruments
Office.
Each HI96831 instrument is supplied with:
• 9 V battery
• Instruction manual
• Plastic pipette
• Quality Certificate
Note: Save all packing material until you are sure that the
instrument functions correctly. A defective instrument must be
returned in its original packing.
PRELIMINARY EXAMINATION

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The HI96831 Digital Refractometer is a rugged portable, water
resistant device that utilizes the measurement of refractive index to
determine the % volume and freezing point of ethylene glycol based
coolants or antifreeze.
The HI96831 device benefits from Hanna Instruments’ years of experi‑
ence as a manufacturer of analytical instruments. The digital
refractometer eliminates the uncertainty associated with mechanical
refractometers and is easily portable for use in the field to optimize
your cooling system.
The HI96831 refractometer is an optical device that is simple and
quick to use. Samples are measured after a simple user calibration
with distilled or deionized water. Within seconds, the refractive
index and temperature are measured and converted into one of two
measurement units; % Volume or Freezing Point. The instrument
utilizes internationally recognized references for unit conversion and
temperature compensation for ethylene glycol solutions (e.g. CRC
Handbook of Chemistry and Physics, 87th Edition).
The temperature (in °C or °F) is also displayed on the large dual level
display along with helpful message codes.
Key features include:
• IP65 waterproof protection
• Automatic Temperature Compensation (ATC)
• Battery operation with Low Power indicator (BEPS)
• Automatically turns off after 3 minutes of non‑use
GENERAL DESCRIPTION

Range
% Volume : 0.0 to 100.0 % V/V
Freezing point: 0.0 to ‑50.0 ºC
(32.0 to ‑58.0 ºF)
ºC (ºF): 0.0 to 80.0 ºC (32.0 to
176.0 ºF)
Resolution
% Volume: 0.1 % V/V
Freezing Point: 0.1 ºC (0.1 ºF)
ºC ( ºF): 0.1 ºC (0.1 ºF)
Accuracy
%Volume: ±0.2% V/V
Freezing Point: ±0.5 ºC (±1.0 ºF)
ºC ( ºF): ±0.3 ºC (±0.5 ºF)
Temperature
Compensation
Automatic between 10.0 and 40.0 ºC
( 32.0 ‑ 104.0 ºF)
Measurement Time Approximately 1.5 seconds
Minimum Sample
Volume 100 µL (cover prism totally)
Light Source Yellow Led
Sample Cell Stainless Steel ring and flint glass prism
Case Material ABS
Enclosure Rating IP65
Battery Type / Life 9V/ 5000 readings
Auto‑Off After 3 minutes of non‑use
Dimensions 192 x 102 x 69 mm (7.6 x 4.1 x 2.7 ")
Weight 350 g (12.3 oz.)
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SPECIFICATIONS

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The %Brix determination is made by measuring the refractive index of a
solution. Refractive Index is an optical characteristic of a substance and the
number of dissolved particles in it. Refractive Index is defined as the ratio of
the speed of light in empty space to the speed of light in the substance. A
result of this property is that light will “bend”, or change direction, when it
travelsthroughasubstanceofdifferentrefractiveindex.Thisiscalledrefraction.
When passing from a material with a higher to lower refractive index, there
is a critical angle at which an incoming beam of light can no longer refract,
but will instead be reflected off the interface.
The critical angle can be used to easily calculate the refractive index according
to the equation:
sin (θcritical) = n2/ n1
Wheren2istherefractiveindexofthelower‑densitymedium;n1istherefractive
index of the higher‑density medium.
In the HI96831 refractometer, light from an LED passes through a prism in
contact with the sample. An image sensor determines the critical angle at
which the light is no longer refracted through the sample.
Specialized algorithms then apply temperature compensation to the measu‑
rement and convert the refractive index to: % Volume or Freezing Point.
PRINCIPLE OF OPERATION

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Freezing point is displayed as a temperature from 0.0 to ‑ 50.0 °C cor‑
respondingto0‑58%byvolume.Thedisplayblinksthefreezingpointwhenthe
concentrationofEthyleneglycolisgreaterthan78%concentrationbyvolume.
When the display shows “LO”, the freezing point is at a minimum (below
‑50 °C).
MEASUREMENT UNITS

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1. Liquid Crystal Display (LCD)
2. Secondary Display
3. Primary Display
4. READ Key (User Measurement)
5. ZERO Key (User Calibration)
6. RANGE Key (User Measurement Unit)
7. ON/OFF
8. Stainless Steel Sample Well and Prism
TOP VIEW
9. Battery Cover
10. Battery Compartment
BOTTOM
FUNCTIONAL DESCRIPTION

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• Handle instrument carefully. Do not drop.
• Do not immerse instrument under water.
• Do not spray water to any part of instrument except the “sample well”
located over the prism.
• The instrument is intended to measure ethylene glycol solutions. Do
not expose instrument or prism to solvents that will damage it. This
includes most organic solvents and extremely hot or cold solutions.
• Particulate matter in a sample may scratch the prism. Absorb sample
with a soft tissue and rinse sample well with deionized or distilled
water between samples.
• Use plastic pipettes to transfer all solutions. Do not use metallic tools
such as needles, spoons or tweezers as these will scratch the prism.
• Cover sample well with hand if measuring in direct sun.
MEASUREMENT GUIDELINES
1. Battery (blinks when low battery condition detected)
2. Primary Display (displays measurement and error messages)
3. Measurement in Progress Tag
4. SETUP: Factory Calibration Tag
5. CAL: Calibration Tag
6. Measurement Unit
7. Automatic Temperature Compensation
(blinks when temperature exceeds 0.0‑40.0 °C / 32.0‑104.0 °F range)
8. Temperature Units
9. Secondary Display (displays temperature measurements; when
blinking, temperature has exceeded operation range: 0.0‑80.0 °C /
32.0‑176.0 °F)
DISPLAY ELEMENTS

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Calibration should be performed daily, before measurements are made, when
the battery has been replaced, between a long series of measurements, or
if environmental changes have occurred since the last calibration.
1. Press the ON/OFF key, then release. Two instrument test screens will
be displayed briefly; all LCD segments followed by the percentage of
remaining battery life. The meter will then briefly display an indication
of the measurement units set. When LCD displays dashes, the instrument
is ready.
2. Using a plastic pipette, fill the sample well with distilled or deionized
water. Make sure the prism is completely covered.
CALIBRATION PROCEDURE
Note: If the ZERO sample is subject to intense light such as sunlight
or another strong source, cover the sample well with your hand or
other shade during the calibration.
3. Press the ZERO key. If no error messages appear, your unit is calibrated.
(For a description of ERROR MESSAGES see page 17).
Note: The 0.0 screen will remain until a sample is measured or the
instrument is turned off.
4. Gently absorb the ZERO water standard with a soft tissue. Use care not
to scratch the prism surface. Dry the surface completely. The instrument
is ready for sample measurement.
Note: If the instrument is turned off the calibration will not be lost.

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Verify the instrument has been calibrated before taking measurements.
1. Wipe off prism surface located at the bottom of the sample well. Make
sure the prism and sample well are completely dry.
2. Using a plastic pipette, drip sample onto the prism surface. Fill the well
completely.
Note: If the temperature of the sample differs significantly from
the temperature of the instrument, wait approximately 1 minute
to allow thermal equilibration.
MEASUREMENT PROCEDURE
4. Remove sample from the sample well by absorbing with a soft tissue.
5. Using a plastic pipette, rinse prism and sample well with distilled
or deionized water. Wipe dry. The instrument is ready for the next
sample.
3. Press the READ key. The results are displayed as % Volume or Freezing
Point.
Note: The last measurement value will be displayed until the next
sample is measured or the instrument is turned off. Temperature will
be continuously updated.
The ATC tag blinks and automatic temperature compensation
is disabled if the temperature exceeds the 0.0-40.0 ºC /
32.0-104.0 ºF range.

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Press the RANGE key to select the measurement units. The instrument
toggles between the two measurement scales each time the key is pressed
and the primary display indicates “VoL” % Volume or “FrPt” for Freezing
Point. When the instrument displays the screen with 4 dashes, the instrument
is ready for measurement.
TO CHANGE MEASUREMENT UNIT

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To change the temperature measurement unit from Celsius to Fahrenheit
(or vice versa), follow this procedure.
1. Press and hold the ON/OFF key continuously for approximately
8 seconds. The LCD will display the “all segment” screen followed by a
screen with the model number on the primary display and the version
number on the secondary display. Continue pressing the ON/OFF key.
2. While continuing to hold the ON/OFF key, press the ZERO key. The
temperature unit will change from °C to °F or vice versa.
Note: The selected unit will be used in Freezing Point mode.
°C or °F
8 seconds
TO CHANGE TEMPERATURE UNIT

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•Use distilled or deionized water to bring the flask close to the total
volume, mix, allow time for the solution to return to room temperature.
•Once the solution has returned to room temperature use distilled or
deionized water to bring the total volume to 100 mL. Mix solution well
before use.
Ethylene
Glycol
Total
Volume
Expected Freezing Point
Value
10 % V 10.00 mL 100.00 mL ‑3.8 °C (25.2 °F)
40 % V 40.00 mL 100.00 mL ‑26.3 °C (‑15.4 °F)
To make a Ethylene Glycol Solution, follow the procedure below:
•To make an X % ethylene glycol solution volumetrically add X mL of
high purity ethylene glycol (CAS #: 107‑21‑1; MW 62.068) to a
100 mL Grade A volumetric flask.
MAKING A STANDARD SOLUTION

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To replace the instrument’s battery, follow these steps:
• Make sure the instrument is off.
• Turn instrument upside down and remove the battery cover by turning
it counterclockwise.
• Extract the battery from its location.
• Replace with a new 9V battery making sure to observe polarity.
• Insert the back battery cover and fasten it by turning clockwise to
engage.
BATTERY REPLACEMENT

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Error Code Description
“Err“ General failure. Cycle power to instrument.
If error persists, contact your local Hanna
Instruments Office.
“LO“ primary
display
Sample exceeds minimum measurement
range.
“HI“ primary
display
Sample exceeds maximum measurement
range.
“LO“ primary
display Cal
segment ON
Wrong solution used to zero instrument.
Use deionized or distilled water. Press
ZERO.
“HI“ primary
display Cal
segment ON
Wrong solution used to zero instrument.
Use deionized or distilled water. Press
ZERO.
“t LO“ primary
display Cal
segment ON
Temperature exceeds ATC low limit
(10.0 °C) during calibration.
“t HI“ primary
display Cal
segment ON
Temperature exceeds ATC high limit
(40.0 °C) during calibration.
“Air“ Prism surface insufficiently covered.
“ELt“ Too much external light for measurement.
Cover sample well with hand.
“nLt“ LED light is not detected.
Contact your local Hanna Instruments
Office.
Battery segment
blinking
<5% of battery life is remaining.
Temperature values
are blinking
“0.0°C“or “80.0 °C“
Temperature measurement
out of range (0.0 to 80.0 °C).
ATC segment
blinking
Outside temperature
compensation range
(10.0 to 40.0 °C).
SETUP segment
blinking
Factory calibration lost.
Contact your local Hanna Instruments
Office.
ERROR MESSAGES

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MAN96831 04/17
ACCESSORIES
Code Description
HI740157P Plastic refilling pipette (20 pcs.)
HI740029P 9V battery (10 pcs.)

HI96831 is warranted for two years against defects in
workmanship and materials when used for their intended
purpose and maintained according to instructions.
This warranty is limited to repair or replacement free of
charge.
Damage due to accidents, misuse, tampering or lack of
prescribed maintenance is not covered.
If service is required, contact your local Hanna Instruments
Office. If under warranty, report the model number, date
of purchase, serial number and the nature of the problem.
If the repair is not covered by the warranty, you will be
notified of the charges incurred. If the instrument is to be
returned to Hanna Instruments, first obtain a Returned Goods
Authorization number from the Technical Service department
and then send it with shipping costs prepaid. When ship‑
ping any instrument, make sure it is properly packed for
complete protection.
To validate your warranty, fill out and return the enclosed
warranty card within 14 days from the date of purchase.
Warranty
Hanna Instruments reserves the right to modify the design, construction or
appearance of its products without advance notice.

Printed in ROMANIA
World
Headquarters
Hanna Instruments Inc.
Highland Industrial Park
584 Park East Drive
Woonsocket, RI 02895 USA
www.hannainst.com
Local Office
Hanna Instruments USA
270 George Washington Highway
Smithfield, RI 02917
Phone: [phone]
Fax: [phone]
e‑mail: [email protected]
MAN96831