Agilent Technologies 4100 Operating instructions

Agilent 4100
Microwave Plasma
Atomic Emission
Spectrometer
Site Preparation Guide

2 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
Notices
© Agilent Technologies, Inc. 2011
No part of this guide may be
reproduced in any form or by any
means (including electronic storage
and retrieval or translation into a
foreign language) without prior
agreement and written consent from
Agilent Technologies, Inc. as governed
by United States and international
copyright laws.
Guide Part Number
G8000-90001
Edition
First edition, August 2011
Printed in USA
Agilent products must only be used in
the manner described in the Agilent
product user guides. Any other use
may result in damage to the product
or personal injury. Agilent is not
responsible for any damages caused,
in whole or in part, by improper use of
the products, unauthorized alterations,
adjustments or modifications to the
products, failure to comply with
procedures in Agilent product user
guides, or use of the products in
violation of applicable laws, rules or
regulations.
Agilent shall not be liable for errors or
damages on products or performance
due to using non-Agilent genuine
parts.
Warranty
The material contained in this
document is provided “as is,” and is
subject to being changed, without
notice, in future editions. Further, to
the maximum extent permitted by
applicable law, Agilent disclaims all
warranties, either express or implied,
with regard to this guide and any
information contained herein,
including but not limited to the
implied warranties of merchantability
and fitness for a particular purpose.
Agilent shall not be liable for errors
or for incidental or consequential
damages in connection with the
furnishing, use, or performance of
this document or of any information
contained herein. Should Agilent and
the user have a separate written
agreement with warranty terms
covering the material in this
document that conflict with these
terms, the warranty terms in the
separate agreement shall control.
Technology Licenses
The hardware and/or software
described in this document are
furnished under a license and may be
used or copied only in accordance
with the terms of such license.
Restricted Rights Legend
If software is for use in the
performance of a U.S. Government
prime contract or subcontract,
Software is delivered and licensed as
“Commercial computer software” as
defined in DFAR 252.227-7014 (June
1995), or as a “commercial item” as
defined in FAR 2.101(a) or as
“Restricted computer software” as
defined in FAR 52.227-19 (June 1987)
or any equivalent agency regulation or
contract clause. Use, duplication or
disclosure of Software is subject to
Agilent Technologies’ standard
commercial license terms, and non-
DOD Departments and Agencies of the
U.S. Government will receive no
greater than Restricted Rights as
defined in FAR 52.227-19(c)(1-2) (June
1987). U.S. Government users will
receive no greater than Limited Rights
as defined in FAR 52.227-14 (June
1987) or DFAR 252.227-7015 (b)(2)
(November 1995), as applicable in any
technical data.
Safety Notices
A CAUTION notice denotes a hazard.
It calls attention to an operating
procedure, practice, or the like that, if
not correctly performed or adhered to,
could result in damage to the product
or loss of important data. Do not
proceed beyond a CAUTION notice
until the indicated conditions are fully
understood and met.
A WARNING notice denotes a
hazard. It calls attention to an
operating procedure, practice, or the
like that, if not correctly performed
or adhered to, could result in
personal injury or death. Do not
proceed beyond a WARNING notice
until the indicated conditions are
fully understood and met.
WARNING
CAUTION

Contents
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 3
Contents
1. Introduction 7
Installation Guidelines 8
Site Preparation Check-list 9
2. Safety Practices and Hazards 11
General 11
Plasma 12
Heat,VaporsandFumes 13
Compressed Gas Hazards 14
ElectricalHazards 15
OtherPrecautions 15
WarningSymbols 16
ColorCoding 17
CECompliance 18
ICES/NMB-001 18
3. Laboratory Environment 19
Suitability 19
Environmental Conditions 20
Temperaturecontrol 21
Cleanliness 21
Instrument cooling air supply 21
Workbench 22

Contents
4 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
WorkbenchLocation 22
PCRequirements 23
4. Instrument Shipping Information 25
In-houseTransitRoutes 25
InsuranceAfterDelivery 26
WeightsandDimensions 26
TransitDamage 27
Unpacking the Instrument 28
5. Laboratory Facilities 29
ExhaustSystem 29
ElectricalPowerSupplies 30
Electricalrequirements 31
Instrument power connections 31
Other electrical connections 32
Fuses 32
GasSupplies 32
Cylinder storage instructions 34
Cryogenicliquids 34
WasteFluidContainer 35
Guidelines for Software Installation 35

Contents
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 5
6. AccessoriesandOptions 37
Organic Solvents or Hydrofluoric Acid 37
ExternalGasControlModule 38
Gasrequirements 38
Monochromator Optics Air Purge 39
Gasrequirements 40
Sample Preparation System (SPS 3) 40
Environmental conditions 41
Multimode Sample Introduction System (MSIS) 41
Agilent 4107 Nitrogen Generator 42
Environmental requirements 42
Maximum sound power level 42
Gasrequirements 43
Electricalrequirements 44
Weights and dimensions 44
7. Gas Requirements and Configurations 45
Compressed Air Requirements 45
Agilent 4100 MP-AES Gas Configurations 48

Introduction
6 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
This page is intentionally left blank.

Introduction
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 7
1. Introduction
Installation Guidelines 8
Site Preparation Check-list 9
This guide contains the information required to successfully prepare
a site for an Agilent 4100 Microwave Plasma Atomic Emission
Spectrometer (MP-AES) instrument installation.
On completion of the site preparation, fill in the check-list on Page 9,
(striking out those entries not applicable), and send this check-list to
your local Agilent agent or Agilent sales and service office. As soon
as it is received, Agilent or its agent will contact you to arrange a
convenient time for installation.
References to the Agilent 4100 MP-AES instrument are applicable to
all models and configurations unless otherwise stated.
In case of difficulty in preparing for the installation, and for details
of operator training courses, please contact your Agilent sales
representative or field service engineer at the address given below:

Introduction
8 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
Installation Guidelines
Allow a minimum of four hours for the installation by an Agilent field
service engineer. If accessories are included, allow a maximum of
eight hours.
The installation and familiarization will include the following
Instrument installation
Instrument software installation and registration
Accessory installation
Instrument installation performance tests
Basic customer training
Maintenance overview

Introduction
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 9
Site Preparation Check-list
I have prepared:
Exhaust system
Gas supplies
Nitrogen (separate supplies for the MP-AES and EGCM)
Air (separate supplies for the MP-AES and nitrogen
generator)
Argon
Electrical power supplies
Power connections
Personal computer with Windows 7 64-bit operating system
installed and printer
Waste container
Cooling air system (if required)
Accessories
SPS 3 – Sample Preparation System
EGCM – External Gas Control Module – including gas supplies
Monochromator Optics Purge – including gas supplies
Agilent 4107 Nitrogen Generator – including gas supplies
All preparations have been completed. Please arrange for the
installation to be completed as soon as possible. I understand that if
the installation site is not prepared in accordance with the enclosed
instructions, additional installation charges may be applicable.
Company name and address: 


Name:
Position:
Telephone: Date:
Preferred Installation date:
Signed:

Introduction
10 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
This page is intentionally left blank.

Safety Practices and Hazards
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 11
2. Safety Practices and Hazards
General 11
Plasma 12
Heat, Vapors and Fumes 13
Compressed Gas Hazards 14
Electrical Hazards 15
Other Precautions 15
Warning Symbols 16
Color Coding 17
CE Compliance 18
ICES/NMB-001 18
General
Operation of an Agilent 4100 Microwave Plasma Atomic Emission
Spectrometer (MP-AES) involves the use of compressed gases,
microwave energy and hazardous materials including corrosive fluids
and flammable liquids. Careless, improper or unskilled use of this
instrument can cause death or serious injury to personnel, and/or
severe damage to equipment and property. Only trained personnel
should use this equipment.
The MP-AES incorporates interlocks and covers that are designed to
prevent inadvertent contact with any potential hazards. If the
MP-AES is used in any manner not specified by Agilent, this
protection may be impaired. It is good practice to develop safe
working habits that do not depend upon the correct operation of the
interlocks for safe operation. It is essential that no interlock or cover
is bypassed, damaged or removed.

Safety Practices and Hazards
12 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
The safety practices described below are provided to help the user
operate the Agilent 4100 MP-AES safely. Read each safety topic
thoroughly before attempting to operate the MP-AES and always
operate the MP-AES in accordance with these safety practices.
If you are unsure of the effects of any liquid, gas or chemical on the
MP-AES, consult your Agilent field service engineer or approved
representative before use.
If the MP-AES is to be used in conjunction with other non-Agilent
equipment, the safety requirements of any system incorporating the
MP-AES is the responsibility of the assembler of the system.
Plasma
The plasma is extremely hot (about 6,000 °C, 11,000 °F) and operates
using high levels of microwave energy. The plasma emits high
intensity light. Always wear appropriate eye protection if viewing the
plasma. Close contact with the operating plasma can result in severe
heat burns to the skin, and exposure to microwave radiation can
cause sub-surface skin burns.
Do not operate the plasma if:
the microwave excitation assembly appears to be damaged
foreign material is present in the viewing port (left end of the
microwave excitation assembly) or the torch aperture (vertical
space for the torch)
the space above the chimney is not clear of objects
the MP-AES exhaust system is not connected or turned on
The microwave excitation assembly is designed to contain microwave
radiation and generate the plasma while still permitting easy
installation of the torch and viewing of the plasma. The MP-AES has
an interlock system that is designed to extinguish the plasma if either
the pre-optics window holder is opened or the torch is unloaded. Do
not attempt to bypass the interlock system.

Safety Practices and Hazards
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 13
Before opening the pre-optics window holder or unloading the torch,
extinguish the plasma by:
pressing SHIFT and F5 on the keyboard
selecting the ‘Plasma off’ option from the ‘Plasma’ drop-down
arrow on the MP Expert software toolbar
pressing the Plasma Enable switch on the front of the Agilent
4100 MP-AES
The torch remains hot for up to five minutes after the plasma is
extinguished. Touching this area before it has cooled sufficiently may
result in burns. Allow the torch to cool before removing it from the
loader.
The plasma system has been carefully designed to operate safely and
effectively when using torches and related components that conform
to Agilent’s design criteria. Use of non-approved components in the
MP-AES may render the system inoperative and/or hazardous. It may
also invalidate the warranty on the MP-AES. Use only torches and
related components supplied or authorized by Agilent.
Heat, Vapors and Fumes
Heat, ozone, vapors and fumes generated by the plasma can be
hazardous, and must be extracted from the MP-AES by means of an
exhaust system. Ensure that an exhaust system of the appropriate
type is fitted and operational (as specified in the site preparation
guide). The system must be vented to the outside in accordance with
local regulations and never within the building. Regularly check the
exhaust system by smoke test to ensure that the exhaust system is
functioning correctly. The exhaust fan must always be switched on
before igniting the plasma.

Safety Practices and Hazards
14 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
Compressed Gas Hazards
All compressed gases (other than air) can create a hazard if they leak
into the atmosphere. Even small leaks in gas supply systems can be
dangerous. Any leak (except that of air) can result in an oxygen-
deficient atmosphere which can cause asphyxiation. The storage area
must be adequately ventilated and must comply with the rules and
regulations imposed by the local authorities responsible for such use
in the workplace.
Gas cylinders must be stored and handled strictly in accordance with
local safety codes and regulations. Cylinders must be used and stored
only in a vertical position and secured to an immovable structure or
a properly constructed cylinder stand. Move cylinders only by
securing them to a properly constructed trolley.
If gases are to be plumbed from a remote storage area to the
instrument site, ensure that the local outlets are fitted with stop
valves, pressure gauges and suitable regulators that are easily
accessible to the instrument operator. The gas outlets must be
provided within 1.5 meters (5 feet) of the Agilent 4100 MP-AES.
Use only approved regulator and hose connectors (refer to the gas
supplier’s instructions). Keep gas cylinders cool and properly
labeled. (All cylinders are fitted with a pressure relief device that will
rupture and empty the cylinder if the internal pressure is raised
above the safe limit by excessive temperatures.) Ensure that you have
the correct cylinder before connecting it to the MP-AES.
If using cryogenic (liquid) gases (for example, liquid nitrogen or
argon) prevent severe burns by wearing suitable protective clothing
and gloves.

Safety Practices and Hazards
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 15
Electrical Hazards
The Agilent 4100 MP-AES and some accessories contain electrical
circuits, devices and components operating at dangerous voltages.
Contact with these circuits, devices and components can cause death,
serious injury or painful electric shock. Panels or covers that are
retained by screws on the MP-AES and accessories may be opened
only by Agilenttrained, Agilent-qualified or Agilentapproved field
service engineers (unless specifically instructed). Consult the
documentation or product labels supplied with your personal
computer (PC), monitor and printer to determine which parts are
operator-accessible.
Other Precautions
Use of the MP-AES and accessories may involve materials, solvents
and solutions that are flammable, corrosive, toxic or otherwise
hazardous. Careless, improper or unskilled use of such materials,
solvents and solutions can create explosion hazards, fire hazards,
toxicity and other hazards that can result in death, serious personal
injury or damage to equipment.
Always ensure that laboratory safety practices governing the use,
handling and disposal of hazardous materials are strictly observed.
These safety practices should include wearing appropriate safety
clothing and safety glasses.
Air flow to the MP-AES and accessories must be unobstructed. Do
not block the ventilation grill on the instrument. Consult the
documentation supplied with your PC, monitor and printer for their
specific ventilation requirements.
Great care should be taken when working with glass or quartz parts
to prevent breakage and cuts. This is especially important when
attaching plastic tubing to glass barbs, or removing and replacing
pieces of broken torch.
The MP-AES weighs approximately 73 kg (161 lb). To avoid injury to
personnel or damage to the MP-AES or property, always use a forklift
or other suitable mechanical lifting device to move the MP-AES.
Use only Agilent-supplied spares with your MP-AES.

Safety Practices and Hazards
16 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
Warning Symbols
The following is a list of symbols that appear in conjunction with
warnings in this guide and on the Agilent 4100 MP-AES. The hazard
they describe is also shown. The beginning of the warning text is
noted by a warning icon:
WARNING
A triangular symbol indicates a warning. The meanings of the
symbols that may appear alongside warnings in the documentation
or on the MP-AES itself are as follows:
Corrosive liquids
Electrical shock
Eye hazard
Fire hazard Heavy weight
(danger to feet)
Heavy weight
(danger to hands)
Hot surface
Moving parts
Non-ionizing radiation
Noxious gases
Sharp object
The following symbol may be used on warning labels attached to the
MP-AES. When you see this symbol, refer to the relevant operation or
service documentation for the correct procedure referred to by that
warning label.

Safety Practices and Hazards
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 17
The following symbols appear on the Agilent 4100 MP-AES for your
information.
I Mains power on
0 Mains power off
Single phase alternating current
When attached to the rear of the instrument, it indicates that
the product complies with the requirements of one or more
EU directives.
Color Coding
The various indicator lights appearing on Agilent instruments and
associated accessories are color coded to represent the status of the
instrument or accessory.
 A green light indicates the instrument is in normal/standby
mode.
 An orange light indicates that a potential hazard is present.
 A blue light indicates that operator intervention is required.
 A red light warns of danger or an emergency.

Safety Practices and Hazards
18 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
CE Compliance
Your Agilent 4100 MP-AES has been designed to comply with the
requirements of the Electromagnetic Compatibility (EMC) Directive
and the Low Voltage (electrical safety) Directive (commonly referred
to as the LVD) of the European Union. Agilent has confirmed that
each product complies with the relevant Directives by testing a
prototype against the prescribed EN (European Norm) standards.
Proof that a product complies with these directives is indicated by:
the CE Marking appearing on the rear of the product, and
the documentation package that accompanies the product
containing a copy of the Declaration of Conformity. The
Declaration of Conformity is the legal declaration by Agilent that
the product complies with the directives listed above, and shows
the EN standards to which the product was tested to
demonstrate compliance.
ICES/NMB-001
This ISM device complies with Canadian ICES- 001.
Cet appareil ISM est conforme à la norme NMB-001 du Canada.

Laboratory Environment
Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide 19
3. Laboratory Environment
Suitability 19
Environmental Conditions 20
Temperature control 21
Cleanliness 21
Instrument cooling air supply 21
Workbench 22
Workbench Location 22
PC Requirements 23
This section includes information on laboratory requirements for the
Agilent 4100 MP-AES instrument including:
Environmental conditions
Workbench construction and location
Guidelines for software installation
Suitability
The instrument is only suitable for indoor use and is classified
suitable under the following categories (EN 61010-1):
Installation category II
Pollution degree 2
Equipment class I

Laboratory Environment
20 Agilent 4100 Microwave Plasma Atomic Emission Spectrometer Site Preparation Guide
Environmental Conditions
The area selected for the operation of an Agilent 4100 MP-AES
instrument must be free from drafts, corrosive atmospheres and
vibration. Sample preparation areas and materials storage facilities
should be located in a separate room.
The area should be a dust free, low humidity environment. Air-
conditioning is strongly recommended for control of the
environment.
Table 1. Suitable environmental conditions
Condition Altitude Temp (°C) Humidity
(%RH) non-
condensing
Max Rate Of
Change (°C)
Non-operating
(Transport)
0–4,000 m
(0–13100 ft)
-40–70 °C
(-40–158 °F)
<90
Operating and
complying with
performance
specifications
0–3,000 m
(0–9,800 ft)
5–35 °C
(41–95 °F)
50–80 ≤2 °C /hr
≤±10°C since
calibration
3,000–4,000 m
(9,800–13,100 ft)
5–25 °C
(41–77 °F)
50–80 ≤2 °C /hr
≤±10 °C since
calibration
NOTE For optimum analytical performance, it is recommended that the ambient
temperature of the laboratory be between 20–25 °C (68–77 °F). The ambient
temperature must be constant, with the maximum acceptable temperature
change being 2 °C (3.6 °F) per hour to comply with performance specifications.
The maximum temperature change before a recalibration is required is ±10 °C
(±18 °F).