Hanna Instruments HI 4221 User manual

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HI 4221 & HI 4222
pH/mV/ISE/Temperature
Bench Meters
Instruction Manual
www.hannainst.com

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HI 4221 and HI 4222 are warranted for two years against defects in workmanship and materials when used
for their intended purpose and maintained according to instructions. Electrodes and probes are guaranteed for
six months. This warranty is limited to repair or replacement free of charge.
Damage due to accidents, misuse, tampering or lack of prescribed maintenance is not covered.
If service is required, contact the dealer from whom you purchased the instrument. If under warranty, report
the model number, date of purchase, serial number and the nature of the failure. If the repair is not covered
by the warranty, you will be notified of the charges incurred. If the instrument is to be returned to Hanna
Instruments, first obtain a Returned Goods Authorization number from the Technical Service Department and
then send it with shipping costs prepaid. When shipping any instrument, make sure it is properly packed for
complete protection.
To validate your warranty, fill out and return the enclosed warranty card within 14 days from the date of
purchase.
Dear Customer,
Thank you for choosing a Hanna Instruments product. This manual will provide you with the necessary
information for correct use of the instrument.
Please read this instruction manual carefully before using the instrument.
If you need additional technical information, do not hesitate to e-mail us at [email protected] or see the
back side of this manual for our worldwide sales and technical service contacts.
These instruments are in compliance with directives.
WARRANTYWARRANTY
WARRANTYWARRANTY
WARRANTY

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TABLE OF CONTENTSTABLE OF CONTENTS
TABLE OF CONTENTSTABLE OF CONTENTS
TABLE OF CONTENTS
WARRANTY ...................................................................................................................................... 2
PRELIMINARY EXAMINATION .............................................................................................................. 4
GENERAL DESCRIPTION ...................................................................................................................... 4
FUNCTIONAL DESCRIPTION ................................................................................................................ 5
SPECIFICATIONS ................................................................................................................................ 8
OPERATIONAL GUIDE ....................................................................................................................... 9
DISPLAYING MODES ......................................................................................................................... 11
SYSTEM SETUP ............................................................................................................................... 14
pH SETUP ...................................................................................................................................... 20
mV SETUP ..................................................................................................................................... 32
ISE SETUP (HI 4222 only) .............................................................................................................. 33
pH CALIBRATION & MEASUREMENTS ................................................................................................. 39
mV & RELATIVE mV MEASUREMENTS ................................................................................................ 44
ISE CALIBRATION & MEASUREMENTS (HI 4222 only) ........................................................................ 46
LOGGING ....................................................................................................................................... 57
PC INTERFACE .................................................................................................................................... 62
pH BUFFER TEMPERATURE DEPENDENCE .......................................................................................... 63
ELECTRODE CONDITIONING & MAINTENANCE ..................................................................................... 64
TROUBLESHOOTING GUIDE .............................................................................................................. 66
TEMPERATURE CORRELATION FOR pH SENSITIVE GLASS ...................................................................... 67
ACCESSORIES .................................................................................................................................. 68

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GENERAL DESCRIPTIONGENERAL DESCRIPTION
GENERAL DESCRIPTIONGENERAL DESCRIPTION
GENERAL DESCRIPTION
Remove the instrument from the packing material and examine it carefully to make sure that no damage has
occurred during shipping. If there is any damage, notify your dealer or the nearest Hanna Service Center.
The meters are supplied complete with:
•HI 1131B Glass-body Combination pH Electrode
•HI 7662-T Temperature probe
•pH 4.01 & 7.01 Buffer solutions, 20 mL each
•HI 700661 Cleaning Solution, 2 x 20 mL
•HI 7071S Electrolyte solution
•HI 76404N Electrode Holder
• 12Vdc Power Adapter
• Instruction Manual
HI 4221 and HI 4222 are supplied with 12 Vdc/230 Vac adapter.
HI 4221-01 and HI 4222-01 are supplied with 12 Vdc/115 Vac adapter.
Note: Save all packing material until you are sure that the instrument works properly. Any defective item
must be returned in the original packing with the supplied accessories.
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
PRELIMINARY EXAMINATIONPRELIMINARY EXAMINATION
PRELIMINARY EXAMINATION
HI 4221 and HI 4222 are professional bench meters with color graphic LCD for pH, ORP (Oxidation Reduction
Potential), ISE (HI 4222 only) and Temperature measurements with Calibration Check.
The display can be configured as a single channel or dual channel display (HI 4222 only) in various modes: Basic
information only, GLP information, Graph mode and Log History mode. Each channel can be configured as pH, mV,
Relative mV or ISE (HI 4222 only).
The main features of the instruments are:
• One (HI 4221), or two (HI 4222) input channels;
• Manual selection, automatic and semiautomatic pH calibration up to five points, with standard (1.68, 3.00,
4.01, 6.86, 7.01, 9.18, 10.01 and 12.45) and custom buffers (up to 5 custom buffers);
• Manual Selection and Custom Standard ISE calibration up to five points, with standard (0.1, 1, 10, 100,
1000 ppm) and custom solutions (up to 5 custom solutions), with or without temperature compensation;
• AutoHold feature to freeze first stable reading on the LCD;
• Two selectable alarm limits;
• Five selectable logging modes: Automatic logging with and without AutoHold feature, Manual logging with
or without AutoHold and AutoHold logging mode;
• Up to 100 logging lots;
• Selectable log interval and log sampling features for Automatic logging;
• GLP feature;
• Online and offline graph;
• User-friendly interface on large color graphic LCD (240x320 pixels);
• PC interface via RS232, and USB.

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HI 4221 DESCRIPTION
FRONT PANEL
REAR PANEL
1) Liquid Crystal Display (LCD)
2) Main Keyboard
3) USB connector
4) ON/OFF switch
5) Power adapter socket
6) RS232 serial communication connector
7) Temperature probe socket
8) BNC electrode connector for pH/ORP measurements
9) Reference input socket
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTIONFUNCTIONAL DESCRIPTION
FUNCTIONAL DESCRIPTION

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HI 4222 DESCRIPTION
FRONT PANEL
REAR PANEL
1) Liquid Crystal Display (LCD)
2) Main Keyboard
3) USB connector
4) ON/OFF switch
5) Power adapter socket
6) RS232 serial communication connector
7) Temperature probe socket (Channel 2)
8) BNC electrode connector for pH/ORP/ISE measurements (Channel 2)
9) Reference input socket (Channel 2)
10) Temperature probe socket (Channel 1)
11) BNC electrode connector for pH/ORP/ISE measurements (Channel 1)
12) Reference input socket (Channel 1)

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KEYBOARD DESCRIPTION
FUNCTION KEYS
VIRTUAL KEYS
The upper row keys are assigned to the virtual keys placed on the bottom of the LCD, which allow you to
perform the displayed function, depending on the current menu (e.g. ,
and in
Measure mode).
Note: All the virtual keys are assigned to the focused channel (HI 4222 only).
LCD GENERAL DESCRIPTION
To enter/exit calibration mode.
To select the desired measurement mode, pH, mV, Rel mV (or ISE – HI 4222 only).
To enter Setup (System, pH, mV or ISE) and to access Log Recall function.
To obtain general informations about the selected option/operation.

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SPECIFICATIONSSPECIFICATIONS
SPECIFICATIONSSPECIFICATIONS
SPECIFICATIONS
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POWER CONNECTION
Plug the 12 Vdc adapter into the power supply socket.
Notes: • These instruments use non volatile memory to retain the pH, Ion calibrations and all other
settings, even when unplugged.
• Make sure a fuse protects the main line.
ELECTRODE AND PROBE CONNECTIONS
For pH or ORP measurements connect a pH/ORP electrode with internal reference to the BNC connector
located on the rear panel of the instrument (for the desired channel – HI 4222 only).
For ISE measurements (HI 4222 only) connect, to the desired channel, an ISE electrode with internal
reference to the BNC connector located on the rear panel of the instrument.
For electrodes with a separate reference connect the electrode’s BNC to the BNC connector and the electrode’s
reference to the reference input socket.
For temperature measurements and automatic temperature compensation connect the temperature probe to the
appropriate socket (for the desired channel – HI 4222 only).
INSTRUMENT START UP
• Turn the instrument on from the power switch located on the rear panel of the instrument.
• Please wait until the instrument finishes the initialization process.
Note: It is normal for the loading process to take a few seconds. If the instrument doesn’t display the next
screen, restart the meter using the power switch. If the problem persists, contact your dealer.
OPERATIONAL GUIDEOPERATIONAL GUIDE
OPERATIONAL GUIDEOPERATIONAL GUIDE
OPERATIONAL GUIDE

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CHANNEL SELECTION (HI 4222 only)
• Press while in
Measure mode to access channel
selection menu. Four available options will be displayed:
Channel 1, Channel 2, or multi-channel with the first or the
second channel focused. The “Choose Channel Configuration”
message is displayed in the Reminder messages area.
• Select the desired option by pressing the appropriate key: ,
, or . The instrument will enter in the
selected option
Measure mode.