Thermo Scientific 49iQ User manual

49iQ
Instruction Manual
Ozone Analyzer
117433-00 • 1Sep2019

Thermo Scientific 49iQ Instruction Manual iii
Contents
Introduction........................................................................................................ 1-1
iQ Series Instrument Platform............................................................. 1-1
Principle of Operation ........................................................................ 1-3
Specifications ...................................................................................... 1-8
Dimensions......................................................................................... 1-9
Installation and Setup...................................................................................... 2-1
Unpacking and Inspection .................................................................. 2-1
Cover Removing and Replacing .......................................................... 2-2
Mounting Options.............................................................................. 2-3
Bench Mount................................................................................... 2-3
Rack Mount..................................................................................... 2-4
Setup Procedure .................................................................................. 2-6
Startup ................................................................................................ 2-8
Operation ............................................................................................................ 3-1
Instrument Display ............................................................................. 3-1
Main Menus and Keypads................................................................ 3-5
Numeric Keypad........................................................................... 3-6
Alphanumeric Keypad................................................................... 3-7
Calibration.......................................................................................... 3-9
Calibrate Background..................................................................... 3-11
Calibrate Span Coefficient ............................................................. 3-12
Zero/Span Schedule ....................................................................... 3-14
Custom O3Levels .......................................................................... 3-16
Advanced Calibration..................................................................... 3-17
Manual Calibration..................................................................... 3-18
Calibration History ..................................................................... 3-23
Data.................................................................................................. 3-24
View Data Log (Last Hour)............................................................ 3-25
View Data Log (Last 24 Hours) ..................................................... 3-26
View Data Log (User Defined Time) ............................................. 3-27
Advanced Data Setup..................................................................... 3-29
Data Logging Setup .................................................................... 3-30
Select Data Logging Variables ..................................................... 3-31
Streaming Data Setup ................................................................. 3-32
Select Streaming Variables........................................................... 3-33
Settings ............................................................................................. 3-34
Chapter 1
Chapter 2
Chapter 3

Contents
iv 49iQ Instruction Manual Thermo Scientific
Health Check................................................................................. 3-35
Status and Alarms........................................................................ 3-36
Concentration............................................................................. 3-38
Predictive Diagnostics ................................................................. 3-58
Maintenance ............................................................................... 3-59
Preventive Maintenance .............................................................. 3-60
Change Part ................................................................................ 3-62
Maintenance History................................................................... 3-63
File Sharing and Support............................................................. 3-64
iQ360 ......................................................................................... 3-65
Measurement Settings .................................................................... 3-68
Averaging Time........................................................................... 3-70
Range Mode Selection................................................................. 3-72
Range Setting.............................................................................. 3-74
Gas Mode ................................................................................... 3-75
Gas Units.................................................................................... 3-76
Advanced Measurement Settings ................................................. 3-77
Communications ........................................................................... 3-84
Wired TCP/DHCP .................................................................... 3-86
Serial RS-232/485....................................................................... 3-88
Analog I/O.................................................................................. 3-89
Digital I/O.................................................................................. 3-90
Email Server (SMTP).................................................................. 3-91
Bayern Hessen Settings ............................................................... 3-92
Instrument Settings........................................................................ 3-94
Display Setup.............................................................................. 3-95
Alarm Setpoints........................................................................... 3-96
Clock .......................................................................................... 3-99
Time Zone................................................................................ 3-103
Configuration .............................................................................. 3-106
Security Access Levels................................................................... 3-107
Change Security to View Only Access ....................................... 3-109
Change Full Access Security Password....................................... 3-110
USB Drive ................................................................................... 3-112
Firmware Update Via USB Drive.............................................. 3-113
Download Data To USB Drive................................................. 3-114
Change USB Password.............................................................. 3-117
User Contact Information............................................................ 3-119
Update Bootloader....................................................................... 3-120
Calibration ..........................................................................................................4-1
Equipment Required........................................................................... 4-1
Zero Air Generator........................................................................... 4-1
Calibration Photometer System........................................................ 4-2
Instrument Preparation ....................................................................... 4-3
Calibration Photometer System Preparation........................................ 4-3
Chapter 4

Contents
Thermo Scientific 49iQ Instruction Manual v
System Check................................................................................... 4-3
Ozone Loss Test............................................................................... 4-3
Linearity Check................................................................................ 4-5
Intercomparability Test.................................................................... 4-7
Calibration Procedure ......................................................................... 4-8
Connect the Instrument................................................................... 4-8
Zero Adjust...................................................................................... 4-9
Span Adjust...................................................................................... 4-9
Additional Concentration Standards .............................................. 4-11
Calibration Curve .......................................................................... 4-11
Periodic Zero and Span Checks......................................................... 4-12
Internal Ozonator Adjustment .......................................................... 4-14
Manual Calibration........................................................................... 4-16
Adjust Background......................................................................... 4-16
Adjust Span Coefficient.................................................................. 4-17
Reset Bkg to 0.000 and Span Coef to 1.000................................... 4-17
Zero/Span Schedule .......................................................................... 4-18
Next Time ..................................................................................... 4-18
Period ............................................................................................ 4-18
Zero/Span/Purge Duration Minutes .............................................. 4-18
Schedule Averaging Time............................................................... 4-19
Background.................................................................................... 4-19
Zero/Span Ratio............................................................................. 4-19
References ......................................................................................... 4-19
Maintenance...................................................................................................... 5-1
Safety Precautions ............................................................................... 5-1
Fan Filter Inspection and Cleaning ..................................................... 5-1
Pump Rebuilding................................................................................ 5-2
Leak Test ............................................................................................ 5-5
Optical Bench Cleaning ...................................................................... 5-6
Troubleshooting ................................................................................................ 6-1
Safety Precautions ............................................................................... 6-1
Troubleshooting Guide....................................................................... 6-1
Servicing............................................................................................................. 7-1
Safety Precautions ............................................................................... 7-1
Firmware Updates............................................................................... 7-3
Replacement Parts List ........................................................................ 7-3
Fuse Replacement ............................................................................... 7-5
Filter Replacement .............................................................................. 7-6
Fan Replacement................................................................................. 7-7
Measurement Side Removal and Replacing ......................................... 7-9
LCD Module Replacement ............................................................... 7-12
Chapter 5
Chapter 6
Chapter 7

Contents
vi 49iQ Instruction Manual Thermo Scientific
I/O Replacement............................................................................... 7-14
Peripherals Support Board and System Controller Board
Replacement ..................................................................................... 7-16
DMC Pressure and Flow Board ........................................................ 7-17
Pump Replacement ........................................................................... 7-19
Capillary Cleaning and or Replacement ............................................ 7-22
Capillary O-Ring Replacement ......................................................... 7-24
Power Supply Replacement............................................................... 7-24
Step POL Board Replacement........................................................... 7-26
49iQ Photometer DMC.................................................................... 7-29
Photometer Lamp Replacement ..................................................... 7-30
Photometer DMC Removal ........................................................... 7-32
Photometer DMC Board Replacement .......................................... 7-33
Detector Assembly Replacement .................................................... 7-34
Detector Board Replacement.......................................................... 7-36
Thermistor Replacement................................................................ 7-37
Scrubber Replacement....................................................................... 7-38
Solenoid Replacement....................................................................... 7-39
Optional DMC Ozonator ................................................................. 7-41
DMC Ozonator Removal............................................................... 7-41
Lamp Replacement ........................................................................ 7-44
Ozonator DMC Board Replacement.............................................. 7-45
Ozonator Replacement................................................................... 7-46
Ozonator DMC Install................................................................... 7-48
Optional Pressure Regulator Replacement...................................... 7-50
Optional Manifold Replacement....................................................... 7-51
System Description...........................................................................................8-1
Photometer DMC with Lamp.......................................................... 8-2
Detector System............................................................................ 8-2
Photometer Lamp Power Supply................................................... 8-2
Ozonator DMC ............................................................................... 8-2
Ozonator Lamp Power Supply ...................................................... 8-2
Common Electronics .......................................................................... 8-2
Power Supply ................................................................................... 8-5
System Controller Board .................................................................. 8-5
Backplane Board .............................................................................. 8-5
Front Panel ...................................................................................... 8-5
I/O and Communication Components ............................................ 8-5
Peripherals Support System................................................................. 8-6
Fan................................................................................................... 8-6
Step POL Board............................................................................... 8-6
Sample Pump................................................................................... 8-6
Flow/Pressure DMC ........................................................................... 8-6
Firmware............................................................................................. 8-6
Chapter 8

Contents
Thermo Scientific 49iQ Instruction Manual vii
Optional Equipment .......................................................................................... 9-1
Connecting External Devices .............................................................. 9-1
Communication Board .................................................................... 9-2
RS-232/RS-485 Port..................................................................... 9-2
RS-485 External Accessory Port .................................................... 9-3
Analog I/O Board ............................................................................ 9-4
Analog Voltage Inputs................................................................... 9-4
Analog Voltage Outputs................................................................ 9-5
Analog Output Calibration .............................................................. 9-6
Analog Output Zero Calibration................................................... 9-7
Analog Output Full Scale Calibration ........................................... 9-9
Digital I/O Board........................................................................... 9-11
Digital Inputs.............................................................................. 9-11
Digital Relay Switches................................................................. 9-13
Valve Driver Outputs.................................................................. 9-15
Ozonator........................................................................................... 9-17
Zero Air Source................................................................................. 9-17
PTFE Particulate Filter ..................................................................... 9-17
Safety, Warranty, and WEEE.......................................................................... A-1
Safety ..................................................................................................A-1
Safety and Equipment Damage Alerts ..............................................A-1
Warranty.............................................................................................A-2
WEEE Compliance.............................................................................A-4
WEEE Symbol.................................................................................A-4
Quick Reference .............................................................................................. B-1
List of Figures .....................................................................................B-1
List of Tables.......................................................................................B-3
GNU Lesser General Public License.............................................................C-1
GNU Lesser General Public License................................................... C-1
Chapter 9
Appendix A
Appendix B
Appendix C

Thermo Scientific 49iQ Instruction Manual 1-1
Chapter 1
Introduction
The Thermo Scientific™ 49iQ Ozone (O3) Analyzer utilizes UV
Photometric technology to measure the amount of ozone in the air from
ppb levels up to 200 ppm.
The 49iQ Analyzer is a dual cell photometer, the concept adopted by NIST
for the national ozone standard. Because the instrument has both sample
and reference flowing at the same time, a response time of 20 seconds can
be achieved. Dual range, auto range, temperature correction and pressure
correction are standard features.
The iQ Series Instrument Platform is a smart environmental monitoring
solution for ambient and source gas analysis that affords greater control
over instrument performance and data availability.
●Distributed Measurement and Control (DMC) module design
simplifies serviceability. Each DMC module contains its own
microprocessor control enabling functional performance validation
at the module level.
●Built-in predictive diagnostics and preventive maintenance
schedules identify problems before they occur. The iQ Series
platform sends email notifications directly to Thermo Fisher
Scientific’s world class service support team or locally identified
addressees in order to proactively communicate analyzer
performance conditions and identify spare parts needs before an
operational concern arises.
●The iQ Series platform supports Modbus, streaming and VNC
protocols over serial and Ethernet as well as analog and digital I/O
for easy integration into most data management systems.
●Three standard USB ports afford convenient data download
capability as well as the ability to connect additional hardware, such
as a computer keyboard or mouse.
●The iQ Series GUI runs on a 7” color touchscreen display. The
GUI is highly flexible and can be customized to enable a tailored
experience to simplify daily operations. Custom designed ePort
software allows remote access to the analyzer with a PC. The ePort
iQ Series
Instrument
Platform

Introduction
iQ Series Instrument Platform
1-2 49iQ Instruction Manual Thermo Scientific
control mirrors the same GUI look and feel as the instrument
touchscreen providing a speedy and familiar operational experience.
Figure 1–1. 49iQ Front

Introduction
Principle of Operation
Thermo Scientific 49iQ Instruction Manual 1-3
The 49iQ operates on the principle that ozone (O3) molecules absorb UV
light at a wavelength of 254 nm. The degree to which the UV light is
absorbed is directly related to the ozone concentration as described by the
Beer-Lambert Law:
KLC
e
o
I
I
where:
K = molecular absorption coefficient, 308 cm-1 (at 0°C and 1
atmosphere)
L = length of cell, 38 cm
C = ozone concentration in parts per million (ppm)
I = UV light intensity of sample with ozone (sample gas)
Io= UV light intensity of sample without ozone (reference gas)
The sample is drawn into the 49iQ through the sample bulkhead and is
split into two gas streams, as shown in Error! Reference source not found..
One gas stream flows through an ozone scrubber to become the reference
gas (Io). The reference gas then flows to the reference solenoid valve. The
sample gas (I) flows directly to the sample solenoid valve. The solenoid
valves alternate the reference and sample gas streams between cells A and B
every 10 seconds. When cell A contains reference gas, cell B contains
sample gas and vice versa.
The UV light intensities of each cell are measured by detectors A and B.
When the solenoid valves switch the reference and sample gas streams to
opposite cells, the light intensities are ignored for several seconds to allow
the cells to be flushed. The 49iQ calculates the ozone concentration for
each cell and outputs the average concentration to both the front panel
display and the analog outputs, and also makes the data available over the
serial or Ethernet connection.
Principle of
Operation

Introduction
Principle of Operation
1-4 49iQ Instruction Manual Thermo Scientific
Figure 1–2. 49iQ Flow Diagram—No Sample/Cal Valve

Introduction
Principle of Operation
Thermo Scientific 49iQ Instruction Manual 1-5
Figure 1–3. 49iQ Flow Diagram—Internal Sample/Cal Valve

Introduction
Principle of Operation
1-6 49iQ Instruction Manual Thermo Scientific
Figure 1–4. 49iQ Flow Diagram—Internal Ozonator, Manifold, Sample Cal Valve

Introduction
Principle of Operation
Thermo Scientific 49iQ Instruction Manual 1-7
Figure 1–5. 49iQ Flow Diagram—Internal Ozonator, Sample/Cal & Zero/Ozone
Valves

Introduction
Specifications
1-8 49iQ Instruction Manual Thermo Scientific
Table 1–1 lists the specifications for the 49iQ.
Table 1–1. 49iQ Specifications
Range 0–200 ppm
0–400 mg/m3
Zero Noise 0.25 ppb RMS (60 second averaging time)
Lower Detectable Limit 0.50 ppb
Zero Drift <1.0 ppb (24 hour)
<2.0 ppb (7 day)
Span Drift <1% full-scale (1 month)
Response Time 20 seconds (10 second averaging time)
Linearity ±1% full-scale
Flow Rate 1–3 LPM
Operating Temperature Range 0–45 °C
Power Requirements
100–240 VAC 50/60 Hz
275 Watts
Physical Dimensions 24 in (D) x 16.75 in (W) x 8.72 in (H) [609 mm (D) 425.45 mm
(W) x 221.48 mm (H)]
Weight 31.67 lbs (std)
35.6 lbs (with ozonator)
Analog I/O 4 Isolated voltage inputs 0–10 V
6 Isolated analog voltages outputs, with 4 selectable ranges
6 Isolated analog current outputs, with 2 selectable ranges
Digital I/O 16 Digital inputs (TTL)
8 Solenoid driver outputs
10 Digital reed relay contact outputs
Serial Ports 1 RS-232/485 port
1 RS-485 External Accessory port
Other Ports 3 Full speed USB ports (one in front, two in rear)
1 Gigabit Ethernet port
Communication Protocols MODBUS, Streaming, Bayern Hessen
Approvals and Certifications CE, TUV-SUD Safety, EPA
Specifications

Introduction
Dimensions
Thermo Scientific 49iQ Instruction Manual 1-9
Figure 1–6. Bench Mount Assembly (dimensions in inches [mm])
Dimensions

Introduction
Dimensions
1-10 49iQ Instruction Manual Thermo Scientific
Figure 1–7. Rack Mount Assembly (dimensions in inches [mm])

Introduction
Dimensions
Thermo Scientific 49iQ Instruction Manual 1-11
Figure 1–8. Rack Mount Requirements
Figure 1–9. Rack Requirements Part 2