Agilent Technologies 5100 ICP-OES User manual

Agilent 5100 and 5110
ICP-OES
User’s Guide

2 Agilent 5100 and 5110 ICP-OES User’s Guide
Notices
© Agilent Technologies, Inc. 2014,
2016, 2017, 2018
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Manual Part Number
G8010-90002
Edition
Sixth edition, July 2018
Printed in Malaysia
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Pty Ltd
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Australia
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Safety Notices
A CAUTION notice denotes a hazard.
It calls attention to an operating
procedure, practice, or the like that, if
not correctly performed or adhered to,
could result in damage to the product
or loss of important data. Do not
proceed beyond a CAUTION notice
until the indicated conditions are fully
understood and met.
A WARNING notice denotes a
hazard. It calls attention to an
operating procedure, practice, or the
like that, if not correctly performed or
adhered to, could result in personal
injury or death. Do not proceed
beyond a WARNING notice until the
indicated conditions are fully
understood and met.
WARNING
CAUTION

Contents
Agilent 5100 and 5110 ICP-OES User’s Guide 3
Contents
1. Safety Practices and Hazards 7
General 7
Verifying Safe State 8
Plasma 8
Heat, Vapors and Fumes 9
Compressed Gas Hazards 10
Electrical Hazards 11
Other Precautions 11
Warning Symbols 13
CE Compliance 14
Electromagnetic Compatibility 15
EN55011/CISPR11 15
ICES/NMB-001 16
South Korean Class A EMC declaration 16
2. Introduction 17
Site Preparation Requirements 17
User Documentation 18
Conventions 18
Notes and tips 18
Specifications 19
Temperature control 19
Environmental conditions 19

Contents
4 Agilent 5100 and 5110 ICP-OES User’s Guide
Electrical Power Supplies 19
Circuit breaker 19
Other Connections 20
Personal Computer Requirements 20
Gas Supplies 20
Exhaust system 21
ICP-OES instrument cooling air supply 21
Water Chiller System 22
Drain Vessel 23
3. Installation 25
Agilent ICP-OES Instrument Overview 26
Instrument Status LED Color Coding 28
Front Power On/Off Button 28
ICP Expert Software 29
Connecting ICP Expert software to the ICP-OES 30
Performing a Detector and Instrument Calibration 30
Saving and viewing the calibration data 32
Hardware Components Replacement 32
ICP-OES torches 33
Torch Assembly and Disassembly 34
Torch assembly 35
Torch disassembly 37
Accessories 38
SPS 4 39

Contents
Agilent 5100 and 5110 ICP-OES User’s Guide 5
SPS 3 39
Advanced Valve System (AVS) — AVS 4, AVS 6 and AVS 7
39
SVS 2 and SVS 2+ 40
5-channel Peristaltic Pump 40
External Inlet Duct Adapter 41
Air inlet dust filter 41
Vapor Generation Accessory (VGA) 41
Multimode Sample Introduction System (MSIS) 41
Argon Humidifier 42
IsoMist Programmable Temperature Spray Chamber 42
4. Operation 43
Analysis Checklist 43
Turning On the Instrument and Software 44
Turning on the instrument for the first time (or from long
term shutdown) 44
Running the instrument from an idle state 45
Preparing for Analysis 46
Performing a Detector and Instrument Calibration 46
Creating/Opening a Worksheet 47
Creating a new worksheet 47
Opening an existing worksheet 47
Creating a new worksheet from a template 47
Developing a Method 47
Running Samples 49
Printing a Report 50

Contents
6 Agilent 5100 and 5110 ICP-OES User’s Guide
Instrument Idle State 50
Setting the instrument to idle 50
Turning off the instrument for long term shutdown 52
5. Maintenance and Troubleshooting 55
Routine 56
Cleaning 58
Torch Cleaning 58
Acid cleaning of the torch for aqueous or acid based
samples 59
Rinsing the torch 61
Drying the torch 62
Additional checks after cleaning 63
Troubleshooting 63
Spare Parts 63
Technical Support 64

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES User’s Guide 7
1. Safety Practices and Hazards
General 7
Verifying Safe State 8
Plasma 8
Heat, Vapors and Fumes 9
Compressed Gas Hazards 10
Electrical Hazards 11
Other Precautions 11
Warning Symbols 13
CE Compliance 14
Electromagnetic Compatibility 15
General
Unless otherwise specified, statements in this manual apply to both
the Agilent 5100 and 5110 ICP-OES instruments.
Operation of an Agilent ICP-OES involves the use of compressed
gases, high voltage radio frequency energy and hazardous materials
including corrosive fluids and flammable liquids. Careless, improper
or unskilled use of this spectrometer or chemicals used with it can
cause death or serious injury to personnel, and/or severe damage to
equipment and property. Only trained personnel should use this
instrument.
The spectrometer incorporates interlocks and covers that are
designed to prevent inadvertent contact with any potential hazards.
If the instrument is used in any manner not specified by Agilent, this
protection provided by the equipment may be impaired. It is good
practice to develop safe working habits that do not depend upon the
correct operation of the interlocks for safe operation. It is essential
that no interlock or cover is bypassed, damaged or removed.

Safety Practices and Hazards
8 Agilent 5100 and 5110 ICP-OES User’s Guide
The safety practices described below are provided to help the user
operate the instrument safely. Read each safety topic thoroughly
before attempting to operate the instrument and always operate the
spectrometer in accordance with these safety practices.
Verifying Safe State
The following general safety precautions must be observed during all
phases of operation, maintenance and service of this instrument.
To ensure continued safety of the instrument after maintenance or
service procedures verify the instrument is returned to a safe state
for the user. This includes running performance checks to verify the
instruments safety systems are functioning correctly. Check the
general condition of the instrument during operation for wear or
signs of corrosion that are likely to inhibit function or safety.
Failure to comply with these precautions or with specific warnings
elsewhere in this manual violates safety standards of design,
manufacture, and intended use of the instrument. Agilent
Technologies assumes no liability for the customer’s failure to
comply with these requirements.
Plasma
The plasma is extremely hot (about 10,000 °C) and radiates
dangerous levels of radio frequency (RF) and ultraviolet (UV) energy.
The work coil operates at 1,500 V RMS and about 27 MHz. Exposure
to the RF and UV energy can cause severe skin damage and cataracts
of the eyes, while close contact with the operating plasma can result
in severe heat burns to the skin, and an electrical discharge that can
jump a considerable distance and may cause death, severe electric
shock or sub-surface skin burns.
The plasma must never be operated unless:
the plasma compartment door is closed, with the door handle
fully closed; and
the space above the chimney and air intake is clear of objects.

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES User’s Guide 9
The shielding around the torch compartment is designed to reduce
UV, visible and RF radiation to safe levels while still permitting easy
access to, as well as installation and viewing of, the torch. The
spectrometer has an interlock system that is designed to extinguish
the plasma if the mains supply fails, the handle on the torch
compartment door is opened, or the torch loading handle is open. Do
not attempt to bypass the interlock system.
Before opening the torch compartment door, always extinguish the
plasma by pressing SHIFT + F5 on the keyboard or by clicking the
‘Plasma Off’ icon on the ICP Expert software toolbar.
The torch and its surroundings remain hot for up to five minutes
after the plasma is extinguished. Touching this area before it has
cooled sufficiently may result in burns. Allow the torch and torch
compartment to cool before carrying out any work in this area, or
wear heat-resistant gloves.
The plasma system has been carefully designed to operate safely and
effectively when using torches and related components that conform
to Agilent’s design criteria. Use of non-approved components in the
plasma compartment may render the system inoperative and/or
hazardous. It may also invalidate the warranty on the instrument.
Use only torches and related components supplied or authorized by
Agilent.
Heat, Vapors and Fumes
Heat, ozone, vapors and fumes generated by the plasma can be
hazardous, and must be extracted from the instrument by means of
an exhaust system. Ensure that an exhaust system of the appropriate
type is fitted (as specified in the Site Preparation Guide). The system
must be vented to the outside air in accordance with local regulations
and never within the building. Regularly check the exhaust system by
smoke test to ensure that the exhaust system is functioning correctly.
The exhaust system must always be switched on before igniting the
plasma.

Safety Practices and Hazards
10 Agilent 5100 and 5110 ICP-OES User’s Guide
Compressed Gas Hazards
All compressed gases (other than air) can create a hazard if they leak
into the atmosphere. Even small leaks in gas supply systems can be
dangerous. Any leak (except that of air or oxygen) can result in an
oxygen-deficient atmosphere, which can cause asphyxiation. The
area in which cylinders are stored and the area surrounding the
instrument must be adequately ventilated to prevent such gas
accumulations.
Gas cylinders must be stored and handled strictly in accordance with
local safety codes and regulations. Cylinders must be used and stored
only in a vertical position and secured to an immovable structure or
a properly constructed cylinder stand. Move cylinders only by
securing them to a properly constructed trolley.
Use only approved regulator and hose connectors (refer to the gas
supplier’s instructions). Keep gas cylinders cool and properly
labeled. (All cylinders are fitted with a pressure relief device that will
rupture and empty the cylinder if the internal pressure is raised
above the safe limit by excessive temperatures.) Ensure that you have
the correct gas before connecting it to the instrument.
The primary gas used with the spectrometer is argon, which is the
conductive gas for the plasma. Argon or nitrogen can be used as the
polychromator purge gas. Other gases may be required for future
options and accessories. Use only ‘instrument grade’ gases with your
spectrometer.
If using cryogenic gases (for example, liquid argon), prevent severe
burns by wearing suitable protective clothing and gloves.