Endress+Hauser Liquiline CA80SI User manual

Products Solutions Services
Operating Instructions
Liquiline System CA80SI
Colorimetric analyzer for silica
BA01650C/07/EN/05.22-00
71593680
2022-09-30
Valid as of version
01.12.00

Liquiline System CA80SI Table of contents
Endress+Hauser 3
Table of contents
1 About this document ................ 5
1.1 Warnings ............................ 5
1.2 Symbols .............................. 5
1.3 Symbols on the device ................... 5
1.4 Documentation ........................ 6
2 Basic safety instructions ............ 7
2.1 Requirements for the personnel ............ 7
2.2 Intended use .......................... 7
2.3 Workplace safety ....................... 7
2.4 Operational safety ...................... 7
2.5 Product safety ......................... 8
3 Product description ................. 9
3.1 Product design ......................... 9
3.2 Measuring system ..................... 10
3.3 Equipment architecture ................. 11
4 Incoming acceptance and product
identification ..................... 13
4.1 Incoming acceptance ................... 13
4.2 Product identification ................... 13
4.3 Scope of delivery ...................... 14
5 Mounting ......................... 15
5.1 Mounting requirements ................. 15
5.2 Mounting the analyzer .................. 18
5.3 Post-mounting check ................... 24
6 Electrical connection .............. 25
6.1 Connecting requirements ................ 25
6.2 Connecting the analyzer ................. 25
6.3 Connecting the sensors and additional
modules ............................ 27
6.4 Hardware settings ..................... 33
6.5 Ensuring the degree of protection .......... 35
6.6 Post-connection check .................. 35
7 System integration ................ 36
7.1 Overview of device description files ......... 36
7.2 Integrating the measuring device into the
system ............................. 36
8 Operation options ................. 40
8.1 Structure and function of the operating
menu .............................. 40
8.2 Access to the operating menu via the local
display ............................. 40
9 Commissioning .................... 43
9.1 Preliminaries ......................... 43
9.2 Function check ....................... 49
9.3 Switching on the measuring device ......... 50
9.4 Setting the operating language ............ 50
9.5 Configuring the measuring device .......... 50
9.6 Starting the measurement ............... 52
10 Operation ......................... 53
10.1 Display ............................. 53
10.2 General settings ....................... 54
10.3 Analyzer ............................ 67
10.4 Current inputs ........................ 73
10.5 Binary inputs and outputs ............... 74
10.6 Signal outputs ........................ 83
10.7 Additional functions ................... 92
11 Diagnostics and troubleshooting .. 117
11.1 General troubleshooting ................ 117
11.2 Diagnostic information on local display ..... 118
11.3 Diagnostic information via web browser .... 118
11.4 Diagnostic information via fieldbus ........ 118
11.5 Adapting the diagnostic information ...... 119
11.6 Overview of diagnostic information ....... 121
11.7 Pending diagnostic messages ............ 127
11.8 Diagnostics list ...................... 127
11.9 Logbooks ........................... 127
11.10 System information ................... 132
11.11 Sensor information ................... 133
11.12 Simulation .......................... 133
11.13 Device test .......................... 135
11.14 Resetting ........................... 136
11.15 Operating time information ............. 137
11.16 Firmware history ..................... 137
12 Maintenance .................... 138
12.1 Maintenance schedule ................. 138
12.2 Maintenance tasks .................... 139
12.3 Decommissioning .................... 146
13 Repair ........................... 149
13.1 General information .................. 149
13.2 Spare parts ......................... 149
13.3 Return ............................. 149
13.4 Disposal ........................... 149
14 Accessories ...................... 151
14.1 Device-specific accessories .............. 151
14.2 Communication-specific accessories ....... 155
14.3 System components ................... 156

Table of contents Liquiline System CA80SI
4 Endress+Hauser
15 Technical data ................... 157
15.1 Input .............................. 157
15.2 Output ............................ 157
15.3 Current outputs, active ................. 159
15.4 Relay outputs ........................ 159
15.5 Protocol-specific data .................. 160
15.6 Power supply ........................ 163
15.7 Performance characteristics ............. 164
15.8 Environment ........................ 165
15.9 Process ............................ 165
15.10 Mechanical construction ............... 166
Index ................................. 168

Liquiline System CA80SI About this document
Endress+Hauser 5
1 About this document
1.1 Warnings
Structure of information Meaning
LDANGER
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid the dangerous situation will result in a fatal or serious
injury.
LWARNING
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid the dangerous situation can result in a fatal or serious
injury.
LCAUTION
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid this situation can result in minor or more serious injuries.
NOTICE
Cause/situation
If necessary, Consequences of
non-compliance (if applicable)
‣Action/note
This symbol alerts you to situations which may result in damage to
property.
1.2 Symbols
Additional information, tips
Permitted
Recommended
Forbidden or not recommended
Reference to device documentation
Reference to page
Reference to graphic
 Result of a step
1.3 Symbols on the device
Reference to device documentation
Caution: Hazardous voltage
Do not dispose of products bearing this marking as unsorted municipal waste. Instead, return them
to the manufacturer for disposal under the applicable conditions.

About this document Liquiline System CA80SI
6 Endress+Hauser
1.4 Documentation
The following instructions complement these Operating Instructions and are available on
the product pages on the Internet:
• Brief Operating Instructions Liquiline System CA80SI, KA01281C
• Operating Instructions Memosens, BA01245C
• Software description for Memosens inputs
• Calibration of Memosens sensors
• Sensor-specific diagnostics and troubleshooting
• Guidelines for communication via fieldbus and web server
• PROFIBUS, SD01188C
• Modbus, SD01189C
• Web server, SD01190C
• EtherNet/IP, SD01293C

Liquiline System CA80SI Basic safety instructions
Endress+Hauser 7
2 Basic safety instructions
2.1 Requirements for the personnel
• Installation, commissioning, operation and maintenance of the measuring system may
be carried out only by specially trained technical personnel.
• The technical personnel must be authorized by the plant operator to carry out the
specified activities.
• The electrical connection may be performed only by an electrical technician.
• The technical personnel must have read and understood these Operating Instructions
and must follow the instructions contained therein.
• Faults at the measuring point may only be rectified by authorized and specially trained
personnel.
Repairs not described in the Operating Instructions provided must be carried out only
directly at the manufacturer's site or by the service organization.
2.2 Intended use
The Liquiline System CA80SI is a wet-chemical analyzer for almost continuous
determination of the concentration of silica in ultrapure water and boiler feedwater.
The analyzer is designed for use in the following applications:
• Ultrapure water
• Boiler feedwater
• Steam and condensate analysis
• Reverse osmosis
• Desalination systems
Use of the device for any purpose other than that described poses a threat to the safety of
people and of the entire measuring system, and is therefore not permitted. The
manufacturer is not liable for damage caused by improper or non-designated use.
2.3 Workplace safety
As the user, you are responsible for complying with the following safety conditions:
• Installation guidelines
• Local standards and regulations
• Regulations for explosion protection
Electromagnetic compatibility
• The product has been tested for electromagnetic compatibility in accordance with the
applicable international standards for industrial applications.
• The electromagnetic compatibility indicated applies only to a product that has been
connected in accordance with these Operating Instructions.
2.4 Operational safety
Before commissioning the entire measuring point:
1. Verify that all connections are correct.
2. Ensure that electrical cables and hose connections are undamaged.
3. Do not operate damaged products, and protect them against unintentional operation.
4. Label damaged products as defective.

Basic safety instructions Liquiline System CA80SI
8 Endress+Hauser
During operation:
‣If faults cannot be rectified:
products must be taken out of service and protected against unintentional operation.
LCAUTION
Activities while the analyzer is in operation
Risk of injury and infection from medium!
‣Before you release any hoses, make sure that no actions, such as the pumping of
sample, are currently running or are due to start shortly.
‣Wear protective clothing, goggles and gloves or take other suitable measures to protect
yourself.
‣Wipe up any spilt reagent with a disposable tissue and rinse with clear water. Then dry
the cleaned areas with a cloth.
LCAUTION
Risk of injury from door stop mechanism
‣Always open the door fully to ensure the door stop engages properly.
2.5 Product safety
2.5.1 State-of-the-art technology
The product is designed to meet state-of-the-art safety requirements, has been tested, and
left the factory in a condition in which it is safe to operate. The relevant regulations and
international standards have been observed.
Devices connected to the analyzer must comply with the applicable safety standards.
2.5.2 IT security
We only provide a warranty if the device is installed and used as described in the
Operating Instructions. The device is equipped with security mechanisms to protect it
against any inadvertent changes to the device settings.
IT security measures in line with operators' security standards and designed to provide
additional protection for the device and device data transfer must be implemented by the
operators themselves.

Liquiline System CA80SI Product description
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3 Product description
3.1 Product design
1
8
6
2
3
4
7
5
5
A0035815
 1 Example of a Liquiline System CA80SI 1-/2-channel version
1 Controller
2 Sample channel switching (2-channel version)
3 Manifold
4 Dispensers
5 Reagent bottle
6 Bottle tray
7 Peristaltic pump for dosing the standard
8 Cover (in front of overflow cuvette and photometer)
4
2
3
1
A0036341
 2 Example of a Liquiline System CA80SI: sample channel switching, 6-channel version
1 Panel
2 Overflow
3 Sample infeed to analyzer
4 Sample inlets

Product description Liquiline System CA80SI
10 Endress+Hauser
3
1
2
A0036338
 3 Example of a Liquiline System CA80SI 4-/6-channel version: Panel with pressure relief valves and filter
1 Pressure relief valve
2 Panel
3 Filter
3.2 Measuring system
A complete measuring system comprises:
• Analyzer Liquiline System CA80SI with the configuration ordered
• reagents and standard solution (to be ordered separately)
• Filter and pressure relief valve (enclosed separately with angle brackets in 1-/2-channel
version, mounted on panel in 4-/6-channel version)
• Panel for sample channel switching: 4 /6 sample inlets (4-/6-channel version)
SP1 SP2 D
FR
FI
F
Cu
W
A0044806
 4 1-/2-channel version: Measuring
system with upstream pressure
relief valves and filters
F
D
SP4SP3SP2SP1 SP5 SP6
FR
FI
Cu
W
A0044807
 5 4-/6-channel version: Measuring system with upstream
pressure relief valves and filters on panel and external sample
channel switching on panel
Cu Overflow cuvette FR Pressure relief valve
D Sample outlet SPx Sample inlets, x = 1 to n
F Flow sensor W Outlet
FI Filter

Liquiline System CA80SI Product description
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3.3 Equipment architecture
3.3.1 Slot and port assignment
BASE2-E
1
2
1
2
1
2
Slot
Ports
A0044868
 6 Slot and port assignment
A0044869
 7 Slot and port assignment
A0040671
 8 Slots and ports on the
display
* Analyzer measured value
(parameter-specific)
• Inputs are assigned to measuring channels in the ascending order of the slots and ports.
In the example above:
"CH1: 1:1 pH glass" means:
Channel 1 (CH1) is slot 1 (basic module) : Port 1 (input 1), pH glass sensor
• Outputs and relays are named according to their function, e.g. "current output", and are
displayed in ascending order with the slot and port numbers
• Display shows SP1: analyzer measuring channel 1 with sampling point SP1 (measured
value display is parameter-specific; is not illustrated in the example)
3.3.2 Terminal diagram
The unique terminal name is derived from:
Slot no. : Port no. : Terminal
Example, NO contact of a relay
Device with 4 inputs for digital sensors, 4 current outputs and 4 relays
• Base module BASE2-E (contains 2 sensor inputs, 2 current outputs)
• 2DS module (2 sensor inputs)
• 2AO module (2 current outputs)
• 4R module (4 relays)

Product description Liquiline System CA80SI
12 Endress+Hauser
1 2 34
43 42 41
Relay 1
Relay 2
Relay 3
Relay 4
Slot
Slot 4 Port 1 Pin 41
BASE2-E 2DS 4R 2AO
43 42 41 43 42 41
43 42 41
43 42 41
A0039621
 9 Creating a terminal diagram using the example of the NO contact (terminal 41) of a relay

Liquiline System CA80SI Incoming acceptance and product identification
Endress+Hauser 13
4 Incoming acceptance and product
identification
4.1 Incoming acceptance
1. Verify that the packaging is undamaged.
 Notify the supplier of any damage to the packaging.
Keep the damaged packaging until the issue has been resolved.
2. Verify that the contents are undamaged.
 Notify the supplier of any damage to the delivery contents.
Keep the damaged goods until the issue has been resolved.
3. Check that the delivery is complete and nothing is missing.
 Compare the shipping documents with your order.
4. Pack the product for storage and transportation in such a way that it is protected
against impact and moisture.
 The original packaging offers the best protection.
Make sure to comply with the permitted ambient conditions.
If you have any questions, please contact your supplier or your local Sales Center.
NOTICE
Incorrect transportation can damage the analyzer
‣Always use a lifting truck or a fork-lift to transport the analyzer.
4.2 Product identification
4.2.1 Nameplate
Nameplates can be found:
• On the inside of the door on the bottom right or on the front in the lower right-hand
corner
• On the packaging (adhesive label, portrait format)
The nameplate provides you with the following information on your device:
• Manufacturer identification
• Order code
• Extended order code
• Serial number
• Firmware version
• Ambient and process conditions
• Input and output values
• Measuring range
• Activation codes
• Safety information and warnings
• Certificate information
• Approvals as per order version
‣Compare the information on the nameplate with the order.
4.2.2 Product identification
Product page
www.endress.com/ca80si

Incoming acceptance and product identification Liquiline System CA80SI
14 Endress+Hauser
Interpreting the order code
The order code and serial number of your product can be found in the following locations:
• On the nameplate
• In the delivery papers
Obtaining information on the product
1. Go to www.endress.com.
2. Page search (magnifying glass symbol): Enter valid serial number.
3. Search (magnifying glass).
 The product structure is displayed in a popup window.
4. Click the product overview.
 A new window opens. Here you fill information pertaining to your device,
including the product documentation.
4.2.3 Manufacturer address
Endress+Hauser Conducta GmbH+Co. KG
Dieselstraße 24
D-70839 Gerlingen
4.3 Scope of delivery
Scope of delivery
• 1 analyzer in the version ordered with optional hardware
• 1 x Brief Operating Instructions (hard copy)
•Accessories enclosed:
• Wall holder unit
• Magnetic stir bar (for installation in cuvette)
• 10 ml dispenser with hose (for draining cuvette and sample channel)
• SD card (optional)
• Supply hose
• Sample outlet hose (for sample overflow)
• Outlet hose (for overflow at cuvette)
• 2 m Norprene hose ID 1.6 mm (for large reagent set)
• Cable gland M32 PA (for large reagent set)
• Counter nut M32 PA (for large reagent set)
• O-ring ID 29.00 W 3.00 (for large reagent set)
• Drain plug M32x1.5 with hole 4.9 (for large reagent set)
1-channel 2-channel 4-channel 6-channel
Filters and
pressure relief
valves
1 filter, 1 pressure
relief valve with
angle bracket
2 filters, 2 pressure
relief valves with
angle brackets
Panel with 4 pre-
installed filters and 4
pre-installed pressure
relief valves
Panel with 6 pre-
installed filters and 6
pre-installed pressure
relief valves
Sample channel
switching
in analyzer in analyzer pre-installed on panel pre-installed on panel
‣If you have any queries:
Please contact your supplier or local sales center.

Liquiline System CA80SI Mounting
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5 Mounting
LCAUTION
Incorrect transportation can cause injury and damage the device
‣Always use a lifting truck or a fork-lift to transport the analyzer. Two people are
needed for the installation.
‣Lift the device by the recessed grips.
5.1 Mounting requirements
The device can be installed in the following ways:
• Mounted on a wall
• Mounted on a base
5.1.1 Dimensions
530 (20.87)463 (18.23)
793 (31.22)
A0028820
 10 Liquiline System CA80 closed version, dimensions in mm (in)
417 (16.42)
793 (31.22)
530 (20.87)
A0030419
 11 Liquiline System CA80 open version, dimensions in mm (in)

Mounting Liquiline System CA80SI
16 Endress+Hauser
930 (36.61)
654 (25.74)
1723 (67.83)
A0028821
 12 Liquiline System CA80 with base, dimensions in mm (in)
41
(1.61)
86 (3.39)
11 (0.43)
56
(2.20)
38
(1.50)
A0036334
 13 CA80SI 1-/2-channel version: Filter (left), pressure-reducing valve (right), dimensions in mm (in)
12
(0.47)
40 (1.57)
50 (1.97)
A0036665
 14 Dimensions of angle bracket for filter
--- Fasteners (2 x M5)

Liquiline System CA80SI Mounting
Endress+Hauser 17
54 (2.13)
49 (1.93) 15,5
(0.61)
63,5 (2.5)
A0036664
 15 Dimensions of angle bracket for pressure relief valve
--- Fasteners (2 x M5)
196 (7.72)
355 (13.98)
8 (0.31)
95
(3.74)
335 (13.19)
176 (6.93)
A0036389
 16 CA80SI 4-/6-channel version: Panel with pressure-reducing valves and filters, dimensions in mm (in)
230 (9.06)
255 (10.04) 8 (0.31)
74
150
(5 91)
235
(9.25) (2.91)
A0036390
 17 CA80SI 4-/6-channel version: Panel with sample channel switching, dimensions in mm (in)
5.1.2 Mounting location
Note the following when erecting the device:
‣If mounting on a wall, make sure that the wall has sufficient load-bearing capacity and
is fully perpendicular.
‣If mounting on a base, erect the device on a level surface.
‣Protect the device against additional heating (e.g. from a heating system).
‣Protect the device against mechanical vibrations.
‣Protect the device against corrosive gases, e.g. hydrogen sulfide (H2S) and chlorine
gases.
‣Make sure to pay attention to the maximum height difference and the maximum
distance from the sampling point.
‣Ensure that sample outlet hose "D" and outlet hose "W" can drain freely , without any
siphoning effects.
‣Make sure air can circulate freely at the front of the housing.
‣Open analyzers (i.e. analyzers that are supplied without a door) may only be erected in
closed areas or in a protective cabinet or similar facility.

Mounting Liquiline System CA80SI
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5.1.3 Spacing requirements when mounting
Spacing required for installing analyzer
≥330(12.99)
≥100 (3.94)
A0036774
 18 Minimum spacing required for mounting.
Engineering unit mm (in).
≤116 °
A0036775
 19 Maximum opening angle
Spacing required for installing wall-mount version
750 (29.53)
120 (4.72)
Ø 11 (0.43)
Ø 10.7 (0.42)
A0036779
 20 Holder unit dimensions. Engineering unit mm (in)
5.2 Mounting the analyzer
5.2.1 Mounting the analyzer on a wall
LCAUTION
Incorrect installation can cause injury and damage the device
‣If mounting on a wall, check that the analyzer is fully hooked into the wall holder unit
at the top and bottom, and secure the analyzer to the upper wall holder unit using the
securing screw.
The mounting materials required to secure the device to the wall are not supplied.
1. Provide the mounting materials to secure the device to the wall (screws, wall plugs)
onsite.
2. Mount the wall holder unit (2 parts) on the wall.

Liquiline System CA80SI Mounting
Endress+Hauser 19
3.
Secure the mount on the housing.
4.
1.
2.
A0036781
Hook the analyzer into the wall holder unit (1).
5. Fix the mount and wall holder unit in place with the screw supplied (2).
5.2.2 Installing version with analyzer stand
LCAUTION
Incorrect installation can cause injury and damage the device
‣If using the version with analyzer stand, make sure that the analyzer stand is secured
to the floor.

Mounting Liquiline System CA80SI
20 Endress+Hauser
624 (24.57)
417 (16.42)
530 (20.87)
297 (11.70)
A
AA
A
A0036783
 21 Foundation plan
A Fasteners (4 x M10)
--- Dimensions of Liquiline System CA80
A0036785
 22 Securing the base
1. Screw the base to the ground.
2. With 2 people, lift the analyzer and fit it on the base. Use the recessed grips.
3. Secure the base to the analyzer using the 6 screws supplied.