wtw pH 330i User manual

ba52311edfs04 06/2004
ba52311edfs
pH 330i
pH 340i
Operating manual
Bedienungsanleitung
Mode d’emploi
Instrucciones de operación
pH/mV Pocket Meter Page 3
pH/mV Taschenmeßgerät Seite 17
pH/ mV- mètres de poche Page 31
pH/ mV Medidor manual Página 45
AR
M
O
PH
6
4
2
992
6
°
C
TP
RCL
STO
CAL

pH 330i/340i
2
Note to this
operating manual This operating manual contains a description of
lall basic functions,
lall instructions for a safe operation, and
lall technical data in a compact form.
A more detailed description with notes for special applications is available as
a pdf document via internet under http://www.WTW.com.
Hinweise zu dieser
Bedienungs-
anleitung
Diese Bedienungsanleitung enthält in kompakter Form
ldie Beschreibung aller Grundfunktionen,
lalle Hinweise für den sicheren Betrieb und
lalle technischen Daten.
Eine ausführlichere Beschreibung mit Hinweisen für besondere Anwendun-
gen ist als pdf-Dokument im Internet unter http://www.WTW.com erhältlich.
Remarque àce
mode d’emploi Ce mode d'emploi contient sous forme compacte
lla description de toutes les fonctions de base et
ltoutes les informations assurant un fonctionnement sûr, ainsi que
ltous les données techniques.
Une description plus étendue contenant les informations sur des emplois
spéciaux peut être obtenue sous forme pdf dans l'internet sous http://
www.WTW.com.
Observación
a estas
instrucciones
Este manual de instrucciones incluye la descripción en forma resumida de
ltodas las funciones básicas,
ltodas las observaciones que le garantizan el
lfuncionamiento normal y seguro, asimismo todo las especificaciones y
datos técnicos.
En el internet, bajo http://www.WTW.com encuentra Ud. una descripción
más detallada, en formato pdf, para aplicaciones especiales.
Copyright ©Weilheim 2004, WTW GmbH

pH 330i/340i List of contents
3
pH 330i/340i - List of contents
Safety . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Display and jack field . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Mains power (pH 340i only) . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Switching on the measuring instrument . . . . . . . . . . . . . . . . . . 5
Measuring. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Calibration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Saving data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Outputting the data memory. . . . . . . . . . . . . . . . . . . . . . . . . . 11
Transmitting data (only pH 340i) . . . . . . . . . . . . . . . . . . . . . . 11
Configuring. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Resetting to default settings. . . . . . . . . . . . . . . . . . . . . . . . . . 13
Technical data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14

Safety pH 330i/340i
4
Safety
Safety
instructions The individual chapter of this operating manual use the following safety in- struction to indicate various types of danger:
Warning
indicates instructions that must be followed precisely in order to avoid the
possibility of slight injuries or damage to the instrument or the environment.
Display and jack field
Display
Jack field
Warning
Only connect electrodes to the measuring instrument that do not return any
unallowed voltages or currents (> SELV and > current circuit with current lim-
iting).
Almost all electrodes - in particular WTW electrodes - fulfill these conditions.
Status display indicator
Measured value display
Function and
Temperature display
Sensor symbol
%
°F
S
TempError
mg/L
% ppm
mol/L
ISE
RCL
8
8.
8
888
8
mV/pH
°C
LoBat
AutoCal DIN
CalError
ARng AR
AutoCal TEC
TP
1
UpH
Time
Baud
Day.Month No.
Ident
Year
Auto Store
ConCal
1pH electrode 4Temperature sensor
2Reference electrode 5RS232 interface or analog output/
recorder (only pH 340i)
3Plug-in power supply (only
pH 340i)
Ref
5
123
4

pH 330i/340i Mains power (pH 340i only)
5
Mains power (pH 340i only)
You can either operate the measuring instrument with batteries or with the
plug-in power supply. The plug-in power supply provides the measuring in-
strument with low voltage (7.5 V ... 12 V DC). This saves the batteries.
Warning
The line voltage at the operating site must lie within the input voltage range
of the original plug-in power supply (see TECHNICAL DATA).
Warning
Only use original plug-in power supplies (see TECHNICAL DATA).
Switching on the measuring instrument
Ref
2
1
3
lPlug the jack (1) into the socket (2) of the measuring instrument.
lConnect the original WTW plug-in power supply (3) to an easily accessi-
ble mains socket.
lPress the <>key.
Display test appears briefly on the display.
After this, the measuring instrument automatically switches to the mea-
suring mode. The display shows the relevant measured value.

Measuring pH 330i/340i
6
Measuring
Overview of the measuring modes:
Special functions:
Select pH
resolution If you press <M> while pressing the <RUN/ENTER> key, the resolution swaps between 0.01 and 0.001.
AutoRead
(drift control) The AutoRead function checks the stability of the measurement signal (ex- cept for the measurement of the ORP voltage). Activate AutoRead with
<AR>. Press <RUN/ENTER> to start the AutoRead measurement. During
the AutoRead measurement, AR flashes on the display until a stable mea-
sured value is reached. This can be terminated at any time taking over the
current measured value with <RUN/ENTER>.
Temperature
measurement
during pH
measurements
You can use pH electrodes with and without temperature sensors. The mea-
suring instrument recognizes which temperature sensors are connected and
switchesautomaticallyto thecorrectmodeforthetemperaturemeasurement
(display TP).
Manual temperature input: Set the temperature value with <▲> <▼>.
pH value Redox-
voltage
mV
<M>

pH 330i/340i Calibration
7
Calibration
AutoCal TEC This process is specially adapted to the WTW technical buffer solutions as a
fully automatic single, two-point or three-point calibration. The buffer so-
lutions are automatically recognized by the measuring instrument. Depend-
ing on the instrument setting, the instrument displays the relevant buffer
nominal value or the current electrode voltage in mV.
Valid buffer (values at 25 °C): 2.00 / 4.01 / 7.00 / 10.01
Note
The calibration for pH 10.01 is optimized for the WTW technical buffer solu-
tion TEP 10 Trace or TPL 10 Trace. Other buffer solutions can lead to an er-
roneous calibration. The correct buffer solutions are given in the WTW
catalog or in the Internet.
AutoCal DIN as AutoCal TEC, but matched to buffer solutions according to DIN 19266.
Valid buffer (values at 25 °C): 1.679 / 4.006 / 6.865 / 9.180
ConCal is the conventional two-point calibration using two buffer solutions (pH 7.0
± 0.5 and any other buffer solution) or a single-point calibration using any
buffer solution and is used as a high-speed method.
Calibration
evaluation After calibrating, the measuring instrument automatically evaluates the cali- bration. The asymmetry and slope are evaluated separately. The worst eval-
uation appears on the display.
Display Asymmetry[mV] Slope [mV/pH]
-15 ... +15 -60.5 ... -58
-20 ... +20 -58 ... -57
-25 ... +25 -61 ... -60.5
or
-57 ... -56
Clean the electrode according
to the electrode operating
manual
-30 ... +30 -62 ... -61
or
-56 ... -50
E3
Invalid calibration
< -30 or > 30 < -62 or > -50

Calibration pH 330i/340i
8
Note
If a printer isconnectedto theinterface, a calibrationprotocol is automatically
printed after a valid calibration.
AutoCal TEC / AutoCal DIN procedure:
The following example shows the AutoCal TEC calibration. In the
AutoCal DIN calibration, Cd... instead of Ct... appears on the display. Other-
wise, both procedures are identical.
lConnect the pH electrode to the measuring instrument.
lPress the <CAL> key repeatedly until the display Ct1 and the function dis-
play AutoCal TEC appears. The sensor symbol displays the evaluation of
the last calibration (or no sensor symbol in the delivery state or after the
measurement parameter has been reset).
lImmerse the pH electrode into the first buffer solution.
lWhen measuring without a temperature sensor:
Enter the temperature of the first buffer solution with <▲> <▼>.
lPress <RUN/ENTER>. The AutoRead measurement begins. The elec-
trode voltage (mV) or the buffer nominal value appears on the display. If
the measured value is stable, Ct2 appears.
Note
At this point, the AutoCal TEC calibration can be terminated with
<M>. This correspondstoasingle-point calibration. To do this,
the instrument uses the Nernst slope (-59.16 mV/pH at 25 °C)
and determines the asymmetry of the electrode.
lImmerse the two-point calibration pH electrode in the second buffer so-
lution to continue.
lWhen measuring without a temperature sensor:
Enter the temperature of the second buffer solution with <▲> <▼>.
lPress <RUN/ENTER>. The AutoRead measurement begins. The elec-
trode voltage (mV) or the buffer nominal value appears on the display.
lIf the measured value is stable, the instrument displays the value of the
slope and the evaluation of the two-point calibration.
lPress <RUN/ENTER>. The instrument displays the value of the asymme-
try.
8
4
2
1C t
°C
TP
pH
AutoCal TEC
8
4
2
2C t
°C
TP
pH
AutoCal TEC
pH
45 9
mV/pH
-
pH
2
mV

pH 330i/340i Calibration
9
Note
At this point, the AutoCal TEC calibration can be terminated with
<M>. This corresponds to a two-point calibration.
lImmerse the pH electrode in the second buffer solution to continue the
two-point calibration.
lWhen measuring without a temperature sensor:
Enter the temperature of the third buffer solution with <▲> <▼>.
lPress <RUN/ENTER>. The AutoRead measurement begins. The elec-
trode voltage (mV) or the buffer nominal value appears on the display.
lIf the measured value is stable, the instrument displays the value of the
slope and the evaluation of the three-point calibration.
lPress <RUN/ENTER>. The instrument displays the value of the asymme-
try.
lSwitch to the measuring mode with <M>.
8
4
2
3C t
°C
TP
pH
AutoCal TEC
pH
85 8
mV/pH
-
pH
0
mV

Calibration pH 330i/340i
10
ConCal procedure:
lConnect the pH electrode to the measuring instrument.
lPress the <CAL> key repeatedly until the display ASY and the function
display ConCal appears. The sensor symbol displays the evaluation of
the last calibration (or no sensor symbol in the delivery state or after the
measurement parameter has been reset).
lImmerse the pH electrode in the first buffer solution
(pH 7.0 ± 0.5 in two-point calibration).
lWhen measuring without a temperature sensor:
Enter the temperature of the first buffer solution
with <▲> <▼>while pressing the <RUN/ENTER> key.
lPress the <RUN/ENTER> key.
The measured pH value appears on the display.
lSet the measured value to the nominal pH value of the buffer solution(at
the current temperature) with <▲> <▼>.
lIfthemeasuredvalueis stable,pressthe<RUN/ENTER> key. Thevalue
of the asymmetry appears.
lPress the <RUN/ENTER> key. SLO appears.
Note
At this point, the ConCal calibration can be terminated with
<M>. This corresponds to a single-point calibration. To do
this, the instrument uses the Nernst slope (-59.16 mV/pH at
25 °C) and determines the asymmetry of the electrode.
lImmerse the two-point calibration pH electrode in the secondbuffer so-
lution to continue.
lWhen measuring without a temperature sensor:
Enter the temperature of the second buffer solution with <▲> <▼>while
pressing the <RUN/ENTER> key.
lPress <RUN/ENTER>.
lSet the measured value to the nominal pH value of the buffer solution(at
the current temperature) with <▲> <▼>.
lWhen the measured value is stable, press the <RUN/ENTER> key. The
instrument displays the value of the slope and the calibration evaluation.
lPress <RUN/ENTER>. The instrument displays the value of the asym-
metry.
lSwitch to the measuring mode with <M>.
YAS
TP
pH
ConCal
8
4
2
°C
307 1
pH
ConCal
TP
8
4
2
°C
5
2
OS L
°C
TP
pH
ConCal
554 7
pH
ConCal
TP
8
4
2
°C
pH
25 9
mV/pH
-
pH
3
mV

pH 330i/340i Saving data
11
Saving data
Saving data
manually Press the <STO> key in the measuring mode (display No. with the number of thenextfree memory location).Then,press<RUN/ENTER> and enter theID
number with <▲> <▼>. Terminate the save with <RUN/ENTER>. The instru-
ment changes to the measuring mode.
Saving data
automatically
Int 1
The portable measuring instrument pH 330i/340i has an internal data mem-
ory. It can store up to 800 datasets. The save interval (Int 1) determines the
chronological interval between automatic save processes.
To set up the save interval, press <STO> while pressing the <RUN/ENTER>
key (display Int 1) and set the interval with <▲> <▼>key. Then, press
<RUN/ENTER> and enter the ID number with <▲> <▼>. Change to the last
activemeasuringmodewith<RUN/ENTER>.Theautomaticsaveisswitched
on (display Auto Store).
Outputting the data memory
You can output the data memory with the <RCL> key. By repeatedly press-
ing the <RCL> key, you reach the following functions:
Start the output with <RUN/ENTER>.
Transmitting data (only pH 340i)
Transmitting data
manually Press the <RUN/ENTER> key in the measuring mode. This manually triggers a data transmission of the current measured value to
the serial interface at any time - independently of the selected intervals.
Transmitting data
automatically
Int 2
The interval to the data transmission (Int 2) determines the chronological in-
terval between automatic data transmissions. After the selected interval ex-
pires, the current data record is transmitted to the interface. To set up the
transmission interval, press <RCL> while holding down the <RUN/ENTER>
key (display Int 2). Then, set the interval with <▲> <▼>.
StO dISP Output stored data on the display
StO SEr Output stored data via the serial interface (only pH 340i)
CAL dISP Output calibration data on the display
CAL SEr Output calibration data via the serial interface (only pH 340i)

Configuring pH 330i/340i
12
Configuring
Note
You can leave theconfiguration menu at any time with <M>. The parameters
already changed are stored.
Procedure for configuring (factory settings appear in bold typeface):
lSwitch off the measuring instrument.
lWhile pressing the <M> key, press <>.
lSelect the required Baud rate with <▲> <▼>.
Selection: 1200, 2400, 4800, 9600 Baud.
lThen press the <RUN/ENTER> key.
lSelect the required display during the pH calibration with <▲> <▼>.
Selection:Buffer nominal value (/pH) or current electrode voltage (mV).
lThen press the <RUN/ENTER> key.
lSet the required calibration interval with <▲> <▼>.
Selection: 1... 7... 999 d.
lThen press the <RUN/ENTER> key.
lSelect the date and time step-by-step with <▲> <▼>. In between, press
the <RUN/ENTER> key each time.
lWhen the last <RUN/ENTER> key has been pressed, the instrument
changes to the last active measuring mode.
Baud
0
40
8
LC A
pi sd
/pH
7
3n t
pH
Time
I
d
Day.Month
4
00
9

pH 330i/340i Resetting to default settings
13
Resetting to default settings
You can reset the measurement parameters and the configuration to the de-
livery status separately from one another (initialization).
Measurement
parameters The following measurement parameters can be reset to the delivery status:
Configuration
parameters The following configuration parameters (InI) can be reset to the delivery sta- tus:
Procedure of the reset:
pH/ORP (pH InI)
Measuring mode pH
Slope -59.16 mV/pH
Asymmetry 0 mV
Manual temperature input 25 °C
Resolution (pH display) 0.01
Baud rate 4800
Display during pH calibration Buffer nominal value
Interval 1
(automatically saved) OFF
Interval 2
(for data transmission) OFF
lTo switch it off, press <CAL> while pressing the <RUN/ENTER> key.
lTo reset the measurement parameters with <▲> <▼>, select YES and
confirm with <RUN/ENTER>, or
lContinue to the configuration parameters without resetting (InI) with the
<RUN/ENTER> key.
lAfter the configuration parameters, InI changes the instrument to the last
active measurement mode.
o
n
ni
i
pH

Technical data pH 330i/340i
14
Technical data
Dimensions
and weight
Mechanical
structure
Electrical safety
Test certificates
Ambient
conditions
pH/ORP
measuring ranges
Precision of
pH/ORP
(± 1 digit)
Length [mm] 172
Width [mm] 80
Height [mm] 37
Weight [kg] approx. 0.3
Type of protection IP 66
Protective class III
cETLus, CE
Storage - 25 °C ... + 65 °C
Operation -10 °C ... + 55 °C
Climatic class 2
Measuring range Resolution
pH - 2.000 ... + 19.999
- 2.00 ... + 19.99 0.001 0.01
U [mV] - 999.9 ... + 999.9
- 1999 ... + 1999 0.1 1
T [°C] - 5.0 ... + 105.0 0.1
pH
(± 2 pH units from the
calibration point)
± 0.003 at + 15 °C ... + 35 °C
± 0.01
U [mV] ± 0.2 at + 15 °C ... + 35 °C
T [°C] NTC 30:
± 0.1
PT 1000:
± 0.5 at 0 °C ... 15 °C
± 0.1 at 15 °C ... 35 °C
± 1 at 35 °C ... 55 °C

pH 330i/340i Technical data
15
pH correction
function
Analog output
( pH 340i only) Automatic switchover when the recorder is connected by the cable, AK 323.
Serial interface
(only pH 340i) Automatic switchover when a PC or a printer is connected via the cable, AK 340/B or AK 325/S.
Temperature input
Manually [°C] - 20 ... + 130
Output signal corresponds to the electrode voltage,
i.e. 50-62 mV/pH unit
Accuracy ± 0.1 % of the measured value ± 4 mV
Internal resistance < 5 Ohm (current limited to max. 0.2 mA
output current)
Type RS232, data output
Baud rate Can be set to
1200, 2400, 4800, 9600 Baud
Data bits 8
Stop bit 2
Parity None
Handshake RTS/CTS + Xon/Xoff
Cable length Max. 15m

Technical data pH 330i/340i
16
Power supply
Guidelines
and norms used
Batteries 4 x 1.5 V alkali-manganese batteries, Type AA
Operational life approx. 3000 operating hours
Power supply (only
pH 340i) The following applies to all plug-in power supplies: Connection max. Overvoltage category II
Plug-in power supply unit
(Euro, US , UK, Australian plug)
FRIWO FW7555M/09, 15.1432
Friwo Part. No. 1822089
Input: 100 ... 240 V ~ / 50 ... 60 Hz / 400 mA
Output: 9 V = / 1,5 A
EMC EG guideline 89/336/EWG
EN 61326 A1:1998
EN 61000-3-2 A14:2000
EN 61000-3-3:1995
FCC Class A
Instrument safety EG guideline 73/23/EWG
EN 61010-1 A2:1995
Climatic class VDI/VDE 3540
Type of protection EN 60529:1991
FCC Class A Equipment Statement
Note: This equipment has been tested and found to comply with the
limits for a Class A digital device, pursuant to Part15 of the FCC Rules.
These limits are designed to provide reasonable protection against
harmful interference when the equipment is operated in a commercial
environment. This equipment generates, uses, and can radiate radio
frequency energy and, if not installed and used in accordance with the
instruction manual, may cause harmful interference to radio
communications. Operation of this equipment in a residential area is
likely to cause harmful interference in which case the user will be
required to correct the interference at his own expense.

pH 330i/340i Inhaltsverzeichnis
17
pH 330i/340i - Inhaltsverzeichnis
Sicherheit . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Display und Buchsenfeld . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Netzbetrieb (nur pH 340i). . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Meßgerät einschalten. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Messen. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Kalibrieren . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Speichern . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
Datenspeicher ausgeben . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
Daten übertragen (nur pH 340i) . . . . . . . . . . . . . . . . . . . . . . . 25
Konfigurieren . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
Rücksetzen (Reset) auf Grundeinstellungen . . . . . . . . . . . . . 27
Technische Daten . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28

Sicherheit pH 330i/340i
18
Sicherheit
Sicherheits-
hinweise In den einzelnen Kapiteln dieser Bedienungsanleitung weisen die folgenden Sicherheitshinweise auf verschiedene Stufen von Gefahren hin:
Achtung
kennzeichnet Hinweise, die genau beachtet werden müssen, um mögliche
leichteVerletzungenoder Schäden am Gerät oderder Umwelt zu vermeiden.
Display und Buchsenfeld
Display
Buchsenfeld
Achtung
Schließen Sie an das Meßgerät nur Meßketten an, die keine unzulässigen
Spannungen oder Ströme (> SELV und > Stromkreis mit Strombegrenzung)
einspeisen können.
Nahezu alle Meßketten - insbesondere WTW-Meßketten - erfüllen diese Be-
dingungen.
Statusanzeige
Meßwertanzeige
Funktions- und
Temperaturanzeige
Sensorsymbol
%
°F
S
TempError
mg/L
% ppm
mol/L
ISE
RCL
8
8.
8
888
8
mV/pH
°C
LoBat
AutoCal DIN
CalError
ARng AR
AutoCal TEC
TP
1
UpH
Time
Baud
Day.Month No.
Ident
Year
Auto Store
ConCal
1ph-Meßkette 4Temperaturmeßfühler
2Referenzelektrode 5RS232 Schnittstelle bzw. Analog-
ausgang/Schreiber (nur pH 340i)
3Steckernetzgerät (nur pH 340i)
Ref
5
123
4

pH 330i/340i Netzbetrieb (nur pH 340i)
19
Netzbetrieb (nur pH 340i)
Sie können das MeßgerätwahlweisemitBatterienodermitdem Steckernetz-
gerät betreiben. Das Steckernetzgerät versorgt das Meßgerät mit Kleinspan-
nung (7,5 V ... 12 V DC). Die Batterien werden dabei geschont.
Achtung
Die Netzspannung am Einsatzort mußinnerhalb des Eingangs-Spannungs-
bereichs des Original-Steckernetzgeräts liegen (siehe TECHNISCHE DATEN).
Achtung
Verwenden Sie nur Original-Steckernetzgeräte (siehe TECHNISCHE DATEN).
Meßgerät einschalten
Ref
2
1
3
lStecker (1) in die Buchse (2) des Meßgeräts stecken.
lOriginal WTW-Steckernetzgerät (3) an eine leicht zugängliche Steckdo-
se anschließen
lTaste <>drücken.
Im Display erscheint kurz der Displaytest.
Das Meßgerät schaltet danach automatisch in den Meßmodus. Das Dis-
play zeigt den zugehörigen Meßwert an.

Messen pH 330i/340i
20
Messen
Überblick über die Meßmodi:
Spezialfunktionen:
pH-Auflösung
wählen Wenn Sie <M> bei gedrückter Taste <RUN/ENTER> drücken, wechselt die Auflösung zwischen 0,01 und 0,001.
AutoRead
(Driftkontrolle) Die Funktion AutoRead prüft die Stabilität des Meßsignals (außer bei der Messung bei Redoxspannung). AutoRead mit <AR> aktivieren. Zum Starten
der AutoRead-Messung <RUN/ENTER> drücken. Während der AutoRead-
Messung blinkt die Anzeige AR, bis ein stabiler Meßwert vorliegt. Ein Ab-
bruch mit Übernahme des aktuellen Meßwerts ist jederzeit mit
<RUN/ENTER> möglich.
Temperaturmessu
ng bei pH-
Messungen
Sie können pH-Meßketten mit und ohne Temperaturmeßfühler verwenden.
Das Meßgerät erkennt den Temperaturmeßfühler automatisch und schaltet
in den richtigen Modus der Temperaturmessung (Anzeige TP).
Manuelle Temperatureingabe: Temperaturwert mit <▲> <▼>einstellen.
pH-Wert Redox-
spannung
mV
<M>