Analytik Jena multi EA 4000 User manual

multi EA 4000
Elementary analyzer
C, S and Cl solids analysis
Operating manual

Service:
Analytik Jena AG
Customer Services
Konrad
-Zuse-Str. 1
07745 Jena
Germany
Phone:
Hotline: + 49 (0) 3641 / 77-7407
Fax: + 49 (0) 3641 / 77-7449
Email:
[e-mail]
General information about Analytik Jena AG
on the internet: http://www.analytik-jena.com
Copyrights and Trademarks
multi EA and multiWin are registered trademarks of Analytik Jena AG in Germany.
Microsoft, Windows, MS Excel are registered trademarks of Microsoft Corp.
The identification with ® or TM is omitted in this manual.
Documentation number: 11-889.729
Version 01.16
Implementation of the Technical Documentation:
Analytik Jena AG
© Copyright 2016, Analytik Jena AG

Contents
multi EA 4000 Version 01.16 1
Table of Contents
1Basic Information ....................................................................................................7
1.1 User manual notes................................................................................................................. 7
1.2 Intended Use.......................................................................................................................... 7
1.3 Warranty and liability.............................................................................................................. 8
2Technical data..........................................................................................................9
3Safety instructions ................................................................................................11
3.1 Standards and directives...................................................................................................... 11
3.2 Symbols and signal words used........................................................................................... 11
3.3 Safety markings on the analyzer.......................................................................................... 12
3.4 Technical condition .............................................................................................................. 12
3.5 Requirements for the operating personnel........................................................................... 13
3.6 Safety instructions, transport and installation....................................................................... 13
3.7 Safety instructions – operation............................................................................................. 14
3.7.1 General................................................................................................................................ 14
3.7.2 Safety instructions - Protection against explosion and fire................................................... 15
3.7.3 Safety instructions - electrical equipment............................................................................. 15
3.7.4 Safety instructions for compressed gas containers and systems......................................... 15
3.7.5 Handling of auxiliary and operating materials....................................................................... 16
3.7.6 Safety instructions - service and repair................................................................................ 20
3.8 Behavior during emergencies............................................................................................... 20
4System design .......................................................................................................21
4.1 Comprehensive overview..................................................................................................... 21
4.2 Basic device......................................................................................................................... 21
4.2.1 Combustion system.............................................................................................................. 21
4.2.2Pneumatic and hose system................................................................................................ 22
4.2.3 Components for measuring gas drying and cleaning........................................................... 23
4.2.4 Indicator and control elements, connections........................................................................ 24
4.3 C/S module .......................................................................................................................... 26
4.4 Cl module............................................................................................................................. 28
4.4.1 Coulometer assembly and measuring cell............................................................................ 28
4.4.2 Combustion tube and measuring gas drying........................................................................ 30
4.4.3 Measuring gas cleaning....................................................................................................... 31
4.4.4 Connections......................................................................................................................... 32
4.5 Automatic TIC solids module................................................................................................ 33
4.5.1 Technical data...................................................................................................................... 33
4.5.2 Layout.................................................................................................................................. 34
4.6 Manual TIC solids module.................................................................................................... 38
4.6.1 Technical data...................................................................................................................... 38
4.6.2 Layout of the manual TIC solids module.............................................................................. 39

Contents
2 Version 01.16 multi EA 4000
4.7 Other optional accessories ...................................................................................................42
4.7.1 Sampler................................................................................................................................42
4.7.2 Flame sensor........................................................................................................................42
4.7.3 Scales...................................................................................................................................42
5Measuring method.................................................................................................43
5.1 TC/TS analysis .....................................................................................................................43
5.2 TIC analysis..........................................................................................................................43
5.3 TOC analysis........................................................................................................................44
5.3.1 Differential method for the TOC analysis..............................................................................44
5.3.2 Direct method for the TOC analysis......................................................................................44
5.4 Carbon detection after pyrolysis: TC-EC (optional)...............................................................45
5.5 Data analysis in the C/S mode..............................................................................................45
5.5.1 Calibration techniques..........................................................................................................45
5.5.2 Day factor.............................................................................................................................46
5.5.3 Method characteristics..........................................................................................................46
5.5.4 Other calculations.................................................................................................................47
5.6 Cl detection...........................................................................................................................47
5.7 Data analysis in the Cl mode................................................................................................48
5.7.1 End point routine...................................................................................................................48
5.7.2 Measuring with split / split factor...........................................................................................48
5.7.3 Analysis ................................................................................................................................48
6First commissioning..............................................................................................49
6.1 Site requirements..................................................................................................................49
6.1.1 Installation conditions ...........................................................................................................49
6.1.2 Space requirement ...............................................................................................................49
6.1.3 Energy supply.......................................................................................................................49
6.1.4 Gas supply............................................................................................................................50
6.2 Unpacking and placing the analyzer.....................................................................................50
7Operation................................................................................................................51
7.1 Switching on / heat-up phase / setup....................................................................................51
7.2 C/S measurement.................................................................................................................52
7.2.1 Preparing the multi EA 4000 and C/S module......................................................................52
7.2.2 Performing the C/S measurement........................................................................................55
7.3 Carbon detection after pyrolysis ...........................................................................................57
7.3.1 Preparing the multi EA 4000 and C/S module......................................................................57
7.3.2 Performing the carbon detection after pyrolysis....................................................................57
7.4 Cl detection...........................................................................................................................59
7.4.1 Preparing the multi EA 4000 for Cl measurements...............................................................59
7.4.2 Preparing the electrolyte solution..........................................................................................64
7.4.3 Making the measuring cell available.....................................................................................65
7.4.4 End point routine...................................................................................................................66

Contents
multi EA 4000 Version 01.16 3
7.4.5 Performing the Cl measurement .......................................................................................... 67
7.4.6 Checking the splitting ratio................................................................................................... 69
7.4.7 Cauterizing the quartz boat.................................................................................................. 70
7.5 TIC/TOC detection with automatic TIC solids module.......................................................... 71
7.5.1 Preparing the automatic TIC solids module for the analysis................................................. 71
7.5.2 Required reagents................................................................................................................ 74
7.5.3 Performing the TIC detection with the automatic TIC solids module.................................... 74
7.5.4 Performing the TOC detection in accordance with the differential method using the
automatic TIC solids module (recommended method)......................................................... 76
7.5.5 TOC measurement with direct detection.............................................................................. 78
7.6 TIC detection with the manual TIC solids module................................................................ 80
7.6.1 Prepare the manual TIC solids module and analyzer........................................................... 80
7.6.2 Performing the TIC measurement........................................................................................ 80
8Maintenance and care...........................................................................................84
8.1 Basic device multi EA 4000.................................................................................................. 84
8.1.1 Clean and maintain the device............................................................................................. 84
8.1.2 Check the hose connections................................................................................................ 84
8.2 Operation with C/S module.................................................................................................. 85
8.2.1 Check and replace the ceramic tube.................................................................................... 85
8.2.2 Cleaning the dust trap.......................................................................................................... 86
8.2.3 Replacing the desiccant in the drying tube........................................................................... 88
8.2.4 Replacing the halide trap ..................................................................................................... 89
8.3 Operation with Cl module..................................................................................................... 90
8.3.1 Replacing the sulfuric acid/cleaning the sulfuric acid container............................................ 90
8.3.2 Servicing/replacing the quartz glass combustion tube......................................................... 91
8.3.3 Servicing the combination electrode .................................................................................... 92
8.3.4 Servicing the measuring cells............................................................................................... 94
8.3.5 Replacing the adsorption agent............................................................................................ 94
8.4 Operation with automatic TIC solids module........................................................................ 95
8.4.1 Clean the TIC reactor of the automatic TIC solids module................................................... 95
8.4.2 Cleaning the condensation coil ............................................................................................ 97
8.4.3 Removing and replacing the pump hose.............................................................................. 98
8.4.4 Cleaning the condensate container.................................................................................... 100
8.5 Operation with manual TIC solids module.......................................................................... 101
8.5.1 Clean the TIC reactor at the manual TIC solids module..................................................... 101
8.6 Replacing the water traps .................................................................................................. 101
9Fault removal .......................................................................................................103
9.1 General information............................................................................................................ 103
9.2 Error messages in multiWin ............................................................................................... 103
9.3 Indications in the window DEVICE STATE.............................................................................. 109
9.4 Equipment fault.................................................................................................................. 111
9.4.1 Basic device....................................................................................................................... 111

Contents
4 Version 01.16 multi EA 4000
9.4.2 C/S module.........................................................................................................................111
9.4.3 Cl module............................................................................................................................113
9.5 Device communication errors .............................................................................................114
9.6 Analytical problems.............................................................................................................115
9.6.1C/S detection......................................................................................................................115
9.6.2 Cl detection.........................................................................................................................116
9.6.3 TIC detection (automatic TIC solids module)......................................................................117
9.6.4 TIC detection (manual TIC solids module)..........................................................................117
9.6.5 Measurements in pyrolysis mode (EC)...............................................................................118
10 Transport and storage.........................................................................................119
10.1 Transport ............................................................................................................................119
10.1.1 Preparing the analyzer for transport ...................................................................................119
10.1.2 Transport notes...................................................................................................................120
10.1.3 Moving the analyzer in the laboratory.................................................................................120
10.2 Storage...............................................................................................................................121
10.3 Recommissioning after transport or storage.......................................................................122
10.3.1 Installing the multi EA 4000 C/S .........................................................................................122
10.3.2 Installing the multi EA 4000 Cl............................................................................................125
10.3.3 Installing the multi EA 4000 C/S Cl.....................................................................................127
10.3.4 Installing the automatic TIC solids module..........................................................................131
10.3.5 Installing the manual TIC module .......................................................................................134
10.4 Connecting and using the sampler.....................................................................................137
10.4.1 Installing and adjusting the autosampler FPG 48 ...............................................................137
10.4.2 Filling the sampler FPG 48 .................................................................................................141
10.4.3 Measurement cancellation when using the sampler FPG 48..............................................141
10.4.4 Retrofitting the sampler FPG 48 with a boat sensor ...........................................................141
10.4.5 Retrofitting the sampler FPG 48 with a boat storage..........................................................142
10.4.6 Using the manual sample feed ...........................................................................................144
10.5 Connecting and using the external scales..........................................................................145
11 Disposal................................................................................................................146

Figures
multi EA 4000 Version 01.16 5
Index of Figures
Fig. 1 Horizontal furnace of the basic device multi EA 4000.......................................................... 22
Fig. 2 Flow meters at the basic device multi EA 4000.................................................................... 23
Fig. 3 Dust trap at the combustion furnace .................................................................................... 23
Fig. 4 Drying tube and halide trap.................................................................................................. 24
Fig. 5 Status indicators at the basic device multi EA 4000............................................................. 24
Fig. 6 Control elements behind the front doors of the multi EA 4000............................................. 25
Fig. 7 Connections on the right-hand side of the multi EA 4000 .................................................... 25
Fig. 8 Connections on the rear of the multi EA 4000...................................................................... 26
Fig. 9 Indictors and connections at the C/S module....................................................................... 27
Fig. 10 Cl module............................................................................................................................. 28
Fig. 11 Layout of the measuring cell................................................................................................ 29
Fig. 12 Combination electrode for measuring cell............................................................................ 30
Fig. 13 Quartz combustion tube with gas airlock.............................................................................. 30
Fig. 14 Sulfuric acid containers for measuring gas drying................................................................ 31
Fig. 15 Halide trap and adsorption tube in the Cl module................................................................ 31
Fig. 16Connections of the Cl module in combination with a C/S module........................................ 32
Fig. 17 Connections for the coulometric cell at the inside panel of the Cl module ........................... 32
Fig. 18 Automatic TIC solids module................................................................................................ 33
Fig. 19 TIC reactor........................................................................................................................... 34
Fig. 20 Hose pumps at the automatic TIC solids module................................................................. 35
Fig. 21 Measuring gas drying and cleaning at the automatic TIC solids module.............................. 36
Fig. 22 Dust trap before the measuring gas inlet of the C/S module................................................ 36
Fig. 23 Connections at the automatic TIC solids module................................................................. 37
Fig. 24 Manual TIC solids module.................................................................................................... 38
Fig. 25 TIC reactor of the manual TIC solids module....................................................................... 39
Fig. 26 Flow meter for oxygen flow.................................................................................................. 39
Fig. 27 Metering pump for acid at the manual TIC solids module.................................................... 40
Fig. 28 Components for measuring gas drying and cleaning at the manual TIC solids module....... 41
Fig. 29 Connections at the manual TIC solids module..................................................................... 41
Fig. 30 Checking the halide trap and drying tube............................................................................. 54
Fig. 31 Individual components for the connection between the TIC reactor and ceramic tube........ 71
Fig. 32 Hose connection at the halogen trap.................................................................................... 84
Fig. 33 Window STATUS ANALYZER .................................................................................................. 109
Fig. 34 Hose diagram for multi EA 4000 C/S ................................................................................. 123
Fig. 35 Hose diagram multi EA C/S for measurement in pyrolysis mode....................................... 124
Fig. 36 Hose diagram multi EA Cl.................................................................................................. 126
Fig. 37 Hose diagram multi EA C/S Cl for C/S measurements with ceramic tube
and oxygen airlock............................................................................................................. 128

Figures
6 Edition 01/2016 multi EA 4000
Fig. 38 Hose diagram multi EA C/S Cl for Cl measurements with quartz tube and
argon connection................................................................................................................129
Fig. 39 Hose diagram multi EA C/S Cl for measurement in pyrolysis mode...................................130
Fig. 40 Hose diagram of the automatic TIC solids module .............................................................132
Fig. 41 Hose diagram multi EA C/S with connected automatic TIC solids module.........................133
Fig. 42 Hose diagram multi EA C/S with manual TIC solids module ..............................................135
Fig. 43 Hose diagram multi EA C/S Cl with manual TIC solids module..........................................136
Fig. 44 Retrofit kit for FPG 48 to use the boat storage....................................................................142

Basic Information
multi EA 4000 Version 01.16 7
1 Basic Information
1.1 User manual notes
The analyzer multi EA 4000 is intended for operation by qualified specialist personnel ob-
serving this user manual.
The user manual informs about the design and operation of the analyzer and provides per-
sonnel familiar with elementary analysis the necessary know-how for the safe handling of the
equipment and its components. The user manual further includes notes on the maintenance
and service of the equipment and potential causes and remedies of any faults.
Conventions
Instructions for action which occur in chronological order are numbered and combined into
action units and furnished with the corresponding results.
Lists which are not in chronological order are shown as itemized lists, sub-listings as bullet
points.
Safety notes are indicated by pictographs and signal words. The type and source of the dan-
ger are stated together with notes on preventing the danger. The meaning of the pictographs
and signal words used is explained in section "Safety instructions" p. 11.
The elements of the control and analysis software are indicated as follows:
Menu command, buttons, options etc. are indicated by SMALL CAPS.
Menu commands of a command sequence are separated by slashes ( / ), e.g.
METHOD /EDIT.
Buttons are marked with square brackets, e.g. [SAVE].
1.2 Intended Use
The elementary analyzer multi EA 4000 is a device for the detection of the total carbon con-
tent and/or total sulfur content or for the detection of the total chlorine content in solid and
paste-like samples. After appropriate sample preparation it can also be used for AOX detec-
tion.
The system is configured and expanded in accordance with the specific analytical require-
ments.
The analyzer multi EA 4000 is versatile in its application due to its robust modular design,
ease of operation and expandability.
Waste management
The multi EA 4000 is particularly suited for TIC/TOC detection in waste as well as the total
chlorine detection in surrogate fuels.
Environmental monitoring
The multi EA 4000 enables the simultaneous carbon and sulfur detection in sediment and
soil analysis.

Basic Information
8 Edition 01/2016 multi EA 4000
Power station
An important application area for the multi EA 4000 is both the carbon detection in carbon or
ash residue and the detection of residual carbon in the ash of incineration plants. The chlo-
rine detection in surrogate fuels is also of significance here.
Material testing
The multi EA 4000 enables a rapid sulfur and/or carbon detection in construction materials,
such as cement or plaster, in ceramic materials or glass samples.
Research and teaching
Due to the many specific configuration options the multi EA 4000 is suitable for use in teach-
ing and research.
The analyzer multi EA 4000 must only be used for the methods for the detection of total car-
bon and/or total sulfur content or the detection of the total chlorine content in solid, paste-like
or liquid samples described in this user manual. Any other use is not as intended! Only the
operator is liable for any damages that result from this.
In particular it is prohibited to use the analyzer to analyze flammable liquids or substances
that could farm explosive mixtures. No concentrated acids may be analyzed with the analyz-
er.
The device must only be operated with the carrier gases oxygen 2.5 and argon 4.5 or better.
The operational safety of the analyzer EA 4000 is only ensured during proper use according
to the information in this user manual. The intended use also includes the adherence to the
installation conditions prescribed by Analytik Jena AG which are available from the customer
service address stated on the title page.
1.3 Warranty and liability
The warranty duration and liability comply with the legal requirements and the provisions in
the general terms and conditions of Analytik Jena AG.
Deviations from the intended use described in this user manual result in limitations of war-
ranty and liability during a damage event. Damage to wearing parts is not included in the
warranty.
Warranty and liability claims are excluded for personal injury and property damage due to
one or several of the following causes:
use of the analyzer multi EA 4000 other than intended
improper commissioning, operation and service of the analyzer
modifications of the equipment without prior consultation with Analytik Jena AG
unauthorized intervention in the equipment
operation of the device with faulty safety equipment or improperly fitted safety and
protection equipment
inadequate monitoring of the equipment components subject to wear
use of other than original spare parts, wearing parts or consumables
improper repairs
faults due to the non-observance of this user manual

Technical data
multi EA 4000 Version 01.16 9
2 Technical data
General characteristics
Designation/type Analyzer multi EA 4000
Dimensions Basic device (W x H x D) 550 x 500 x 550 mm
per module: 300 x 500 x 550 mm
Sampler: 520 x 500 x 700 mm
Mass approx. 35 kg
Procedural data
Digestion principle oxidative combustion
Digestion temperature dependent on application 1000 – 1500 °C
(lower temperatures also possible)
Measuring method TC, TIC, TOC, TS, EC, TCl
C and S detection NDIR (coupled with VITA method)
Cl detection Coulometry
Sample volume Up to 3000 mg
Sample Feed Weighted sample in porcelain and quartz glass boats
Automatic sampler or manual feed
Gas supply Oxygen min. 2.5 and argon 4.5
with system pressure 2 – 4 bar
Control/analysis (control and
analysis software multiWin) Real-time graphics, status indication during analysis, graphical display of the measured results, result print-out
Electrical variables
Connection 230 V AC (+ 10%, -15%), 50/60 Hz
Protection T16 A H
Typical average power con-
sumption 3700 VA
PC interface USB
Interference suppression (elec-
tromagnetic compatibility) in accordance with the provisions of
EN 55022 class A interference-protected and
BMPT version 243/1991
Environmental conditions
Temperature during storage 5 – 55 °C
Temperature during operation 10 – 35 °C
Humidity during operation max. 90% at +30 °C
Humidity during storage (10 – 30) % (use desiccant)
Air pressure 0.7 1.06 bar

Technical data
10 Edition 01/2016 multi EA 4000
Minimum equipment for the control and analysis unit
Operating system: Windows XP Professional with Service Pack 2.0 or better
Processor: Pentium IV or better
Working memory: 2 GB
Free hard disk space: 40 GB
Drive: CD-ROM drive
Monitor resolution: 1024 x 768
Interfaces USB 2.0
Technical data for the Cl module
Measuring range
(* with measuring gas splitting) 1 – 100 µg / 10 µg – 20 mg* absolute total chlorine
Furnace temperature up to 1000 °C
Heat-up period up to 30 min.
Analysis time up to 10 min. – dependent on the combustion time and
concentration
Sample weight
(dependent on consistency
and matrix)
Up to 3000 mg

Safety instructions
multi EA 4000 Version 01.16 11
3 Safety instructions
For your own safety and to ensure error-free and safe operation of the analyzer multi
EA 4000, please read this chapter carefully before using the appliance.
Observe all safety notes listed in this user manual and all messages and displayed by the
multiWin control and analysis software on the monitor.
3.1 Standards and directives
The analyzer was manufactured according to the currently valid technology regulations and
the approved safety related regulations.
During the construction of the analyzer the relevant safety and health requirements of the
applicable laws, standards and regulations were applied. The safety of the analyzer is con-
firmed by the CE mark and the declaration of conformity.
Information regarding safety corresponds to the currently valid regulations of the European
Union. In other countries the applicable laws and country specific regulations have to be
complied with.
Besides the safety instructions in this user manual and the local safety regulations that apply
to the operation of the analyzer the general applicable regulations regarding accident pre-
vention, occupational health and safety and environmental protection have to be observed
and complied with.
References to potential dangers do not replace the work protection regulations which must
be observed.
3.2 Symbols and signal words used
The user manual uses the following symbols and signal words to indicate hazards or instruc-
tions. The safety instructions are always placed before an action.
WARNING
Indicates a potentially hazardous situation.
If it is not prevented death or most serious injuries (incapacita
tion) can result.
CAUTION
Indicates a potentially hazardous situation.
If it is not prevented light or minor injuries and material damage can result.
CAUTION! HOT SURFACE!
Touching the hot surface can cause burns.
WARNING! DANGER OF E
LECTRIC SHOCK IF TOUCHED!

Safety instructions
12 Edition 01/2016 multi EA 4000
IMPORTANT
Indicates application hints and other especially useful information without any resulting ha
z-
ardous or damaging situations.
ENVIRONMENTAL PROTEC
TION
Indicates application hints and information to aid the proper disposa
l and handling of the
substances and materials used.
3.3 Safety markings on the analyzer
Safety symbols have been attached to the analyzer and accessories whose content must
always be observed.
Damaged or missing safety symbols can cause incorrect actions leading to personal injury or
material damage! The safety symbols must not be removed! Damaged safety symbols must
be replaced without delay!
The following safety symbols have been attached to the analyzer and accessories:
Warning against hot
surface
Warning against dangerous
electrical voltage
Warning against hand injury
from crushing
Warning against substanc-
es hazardous to health
Warning against corrosive
substances
3.4 Technical condition
The analyzer corresponds in its design and construction to the current state of the art tech-
nology. Unauthorized modifications or changes, especially such that affect the safety of the
staff and the environment, are generally not allowed.
The following has to be observed:
Any manipulation of the safety equipment is prohibited! In case of an accident ma-
nipulations of the safety equipment will be interpreted as deliberate!
The operator must only operate the analyzer in a sound and operationally safe con-
dition. The technical condition must always comply with the legal requirements and
regulations.
Prior to every use the analyzer must be checked for damage and sound condition.
Any changes in the analyzer affecting its safety must be reported by the operating
personnel to the operator without delay.
The equipment components must only be connected to supply cables intended and
designed for this purpose.

Safety instructions
multi EA 4000 Version 01.16 13
All safety equipment and interlocks must be well accessible and regularly checked
for proper operation.
3.5 Requirements for the operating personnel
The analyzer multi EA 4000 must only be operated by qualified specialist personnel instruct-
ed in the use of the analyzer. The instruction must also include conveying the content of this
user manual and the user manuals of other system components or add-on equipment.
The analyzer may pose dangers if it is not used by trained personnel, improperly or other
than intended.
Therefore, every person tasked with the operation of the analyzer must have read and un-
derstood this user manual and the user manuals of any additional equipment before carrying
out the respective tasks. This also applies if the respective person has already worked with
or been trained on this kind of analyzer.
It is recommended that the operator have the operating personnel confirm the knowledge of
the content of the user manual in writing. The ultimate responsibility for the accident-free
operation of the analyzer rests with the operator or the specialist personnel authorized by
him.
In addition to the safety at work instructions in this user manual the generally applicable
safety and accident prevention regulations of the respective country of operation must be
observed and adhered to. The operator must ascertain the latest version of these regula-
tions.
The user manual must be accessible to the operating and service personnel at any time!
The following has to be observed:
The analyzer must only be commissioned, operated and serviced by trained person-
nel instructed in technical safety.
The operation or servicing of the analyzer by minors or individuals under the influ-
ence of alcohol, drugs or medication is not permitted.
It must be ensured that only authorized personnel works at the analyzer.
The operating personnel must be familiar with the dangers arising from measuring
liquids. The appropriate protective equipment must be used.
Prior to pauses or at the end of the work appropriate skin cleaning and protection
measures must be carried out.
Eating, drinking, smoking or handling open flames in the operating room of the ana-
lyzer is prohibited!
3.6 Safety instructions, transport and installation
The analyzer is always installed by the customer service department of Analytik Jena AG or
its authorized and trained specialist personnel. Independent assembly and installation are
not permitted. Incorrect installation can create serious hazards.
The following has to be observed:
Insufficiently secured components pose a risk of injury! During transport the compo-
nents of the equipment must be secured in accordance with the instructions in the
user manual.

Safety instructions
14 Edition 01/2016 multi EA 4000
Only transport the analyzer in its original packaging! Ensure that the transport pro-
tections have been fitted and the analyzer is completely empty.
To prevent damaged to health the following must be observed when moving the ana-
lyzer in the laboratory (lifting and carrying):
−For reasons of safety 2 persons are required to transport the analyzer and must
position themselves on both sides of the equipment.
−Because the analyzer does not feature any handles, firmly grip the device from
the bottom and make sure prior to simultaneous lifting the device that the sensi-
tive components at the front are protected by the closed doors.
−The guide values and statutory limits for lifting and carrying loads without auxiliary
equipment must be observed and adhered to.
3.7 Safety instructions – operation
3.7.1 General
The operator of the analyzer must make sure before each commissioning that the condition
of the analyzers including the safety equipment is sound. This applies in particular after each
modification or extension of the analyzer or its repair.
The following has to be observed:
The analyzer must only be operated if all protective equipment (e.g. covers, drip
pans for chemicals and doors) are present, properly installed and fully operational.
The sound condition of the protection and safety equipment must be checked regu-
larly. Any defects must be corrected as soon as they occur.
Protective and safety equipment must never be removed, modified or decommis-
sioned during operation.
Free access to the power switch on the back of the enclosure has to be ensured dur-
ing operation.
The ventilation equipment on the multi EA 4000 and the extension modules must be
in good working condition. Covered vents or ventilation slits etc. may cause the de-
vice to break down or may cause damage to it.
The analyzer must not be switched on without the combustion tube being fitted.
The furnace operates with temperatures of up to 1500 °C. The hot components (fur-
nace, gas sluice, boat) must not be touched during or directly after the operation of
the analyzer.
In manual operation the hot boats must be deposited on the surface of the manual
feed or on some other heat-resistant surface.
During automatic cooling do not interrupt the power supply. In case of prolonged
power failure during operation disconnect the mains plug and open the housing wall
to prevent damage from overheating.
Keep all combustible materials away from the analyzer.

Safety instructions
multi EA 4000 Version 01.16 15
3.7.2 Safety instructions - Protection against explosion and fire
The analyzer must not be operated in an explosive environment. Smoking or handling open
flames in the operating room of the analyzer is prohibited!
The operating personnel has to be familiar with the location of the fire-fighting equipment in
the operating room of the analyzer.
3.7.3 Safety instructions - electrical equipment
Work on electrical components of the analyzer may only be carried out by a qualified electri-
cian in accordance wit the applicable electrical engineering rules. Life-threatening electrical
voltages may occur in the interior of the analyzer!
The following has to be observed:
Extension modules or system components must always be connected to or discon-
nected from the analyzer in a deactivated condition.
Before opening the analyzer it must be switched off from the equipment switch and
the mains connector must be disconnected from the mains outlet!
The analyzer must not be switched on without the combustion tube being fitted.
Any work on the right-hand side component of the analyzer may only be carried out
by the customer service of Analytik Jena AG and specially authorized technicians.
The electrical components must be checked regularly by a qualified electrician. Any
defects, such as loose connections, faulty or damaged cables, must be repaired
without delay.
The analyzer must be switched off immediately at the power switch (on the equip-
ment backplate) and the power supply disconnected from the mains if there is any
interference with the electric components.
3.7.4 Safety instructions for compressed gas containers and
systems
The carrier gases (argon and/or oxygen) are taken from compressed gas containers or local
compressed gas systems. The required purity of the gas must be ensured (→see chapter
"Technical data" p.9)!
Work on compressed gas containers and systems must only be carried out by individuals
with specialist knowledge and experience in compressed gas systems.
The following has to be observed:
For gas cylinder or gas plant operation, the safety instructions and guidelines which
are valid at the operating location must be strictly complied with.
High pressure hoses and pressure reducers may only be used for the assigned gas-
es.
Pipes, hoses, screw connections and pressure reducers for oxygen must be kept
free from grease.
All pipes, hoses and screw connections must be checked regularly for leaks and ex-
ternally visible damage. Leaks and damaged must be repaired without delay.
Prior to inspections, service and repairs the valves must be closed and the analyzer
vented!

Safety instructions
16 Edition 01/2016 multi EA 4000
After successful repair and service of the components of the compressed air con-
tainers or system the analyzer must be checked for sound operation prior to recom-
missioning!
Independent assembly and installation are not permitted!
3.7.5 Handling of auxiliary and operating materials
The operator is responsible for the selection of substances used in the process as well as for
their safe handling. This is particularly important for radioactive, infectious, poisonous, corro-
sive, combustible, explosive and otherwise dangerous substances.
When handling dangerous substances local safety codes and guidelines must be observed.
The following general notes do not replace the specific local regulations or the regulations in
the EC safety data sheets of the manufacturers for the auxiliary and operating materials.
The following has to be observed:
The relevant regulations and the notes in the EC safety data sheets of the manufac-
turers have to be observed and complied with regards to storage, handing, use and
disposal for all auxiliary and operation materials used during operation or mainte-
nance of the analyzer.
Auxiliary and operation materials may never be placed in containers or vessels for
food. The approved containers for the relevant material are to be used and these
have to be labeled accordingly. The notes on the labels have to be observed!
Protective goggles and rubber gloves have to be worn when handing reagents. The
notes on the labels have to be observed.
Biological samples have to be handled according to local guidelines regarding the
handling of infectious material.
Caution when handing quartz glass and glass parts. Risk of broken glass and there-
fore risk of injury!
Auxiliary and operating materials as well as their containers may not be disposed in
domestic waste or enter the sewage system or the soil. The applicable regulations
for disposal of these materials must be meticulously observed.
Ensure good room ventilation in working rooms.
Handling concentrated acids
The following acids may be used during analysis:
concentrated sulfuric acid as desiccant during Cl detection
highly concentrated acetic acid and nitric acid for the preparation of the electrolytes
during Cl detection
ortho-phosphoric acid during TIC detection
hydrochloric acid during TOC detection
Always observe the appropriate regulations and the notes in the EC safety data sheets of the
manufacturers with regard to storage, use and disposal.
When handling the above-mentioned concentrated acids, observe in particular the following
notes:
The concentrated acid can cause burns and irritation!
Always wear goggles and protective gloves when handling concentrated acids!
Ensure adequate ventilation in the laboratory rooms.

Safety instructions
multi EA 4000 Version 01.16 17
The above-mentioned concentrated acids must not enter the sewage system, sur-
face water or ground water! The applicable regulations for disposal must be meticu-
lously observed.
Only store the concentrated acids in their original containers! Observe the notes on
the labels.
IMPORTANT
In case of chemical burns from acid immediately carry out the following first aid measures:
for skin burns:
Immediately remove contaminated clothing and shoes, dab affected skin areas with
polyethylene glycol 400 then rinse thoroughly with plenty of water.
for eye burns:
Rinse the eyes with open eye lid several minutes with running water (min. 10
minutes), then immediately consult a physician (even if there are no apparent symp-
toms).
for burns of the respiratory organs:
Bring the affected person into fresh air.
if swallowed:
Give plenty of water to drink (possibly several liters). Avoid vomiting (perforation
risk). Do not attempt neutralization.
Always immediately consult a physician after carrying out the first aid
measures!
Handling other substances for the preparation of electrolytes
For the preparation of the electrolyte solutions thymol, thymol blue, gelatin and methanol are
used. Always observe the appropriate regulations and the notes in the EC safety data sheets
of the manufacturer with regard to the storage, use and disposal of the substances.
Methanol
When handling methanol observe in particular the following notes:
Methanol is toxic when inhaled, swallowed and in contact with the skin! There is a
danger of irreversible damage!
Always wear goggles and protective gloves when handling methanol!
Provide eye wash bottles at the workplace.
Ensure adequate ventilation in the laboratory rooms.
Methanol is easily flammable! Keep methanol away from sources of ignition and take
measures against electrostatic charges.
Methanol must not enter the sewage system, surface water or ground water! The
applicable regulations for disposal must be meticulously observed.
Only store the methanol well sealed in its original container! Observe the notes on
the labels.

Safety instructions
18 Edition 01/2016 multi EA 4000
IMPORTANT
In case of damage from methanol carry out the following first aid measures without delay
(ensure your own protection first):
after skin contact:
Remove the contaminated clothing, rinse the affected skin areas with plenty of wa-
ter.
after eye contact:
Rinse the eyes with the eye lids open with plenty of water, then immediately consult
an optician.
after inhalation:
Bring the affected person into fresh air. In case of respiratory failure apply artificial
ventilation immediately, supply oxygen where necessary. Consult a physician imme-
diately.
after swallowing:
Give plenty of water to drink (possibly several liters). Induce vomiting. Give ethanol
to drink (e. g. 1 glass of a 40% alcoholic drink). Consult a physician and point out
methanol.
Always immediately consult a physician after carrying out the first aid measures!
Thymol
When handling thymol observe in particular the following notes:
Thymol is hazardous to health when swallowed (chemical burns)!
Provide eye wash bottles at the workplace.
Ensure adequate ventilation in the laboratory rooms.
Thymol is toxic to water-borne organisms and can cause long-term damage in wa-
terways!
Thymol must not enter the sewage system, surface water or ground water! The ap-
plicable regulations for disposal must be meticulously observed.
Only store thymol sealed in its original container! Observe the notes on the labels.