Metrohm MIRA XTR DS User manual

MIRA XTR DS
2.926.01XX
Product manual
8.0926.8005EN / 2021-09-15

Metrohm Raman
407 South 2nd Street
Laramie, WY 82070
USA
[phone]
[email protected]
www.metrohm.com
MIRA XTR DS
2.926.01XX
Firmware version 8.0.3.40 or higher
Product manual
8.0926.8005EN /
2021-09-15

Technical Communication
Metrohm Raman
Laramie, WY 82070
This documentation has been prepared with great care. However, errors
can never be entirely ruled out. Please send comments regarding possible
errors to the address above.
Copyright
This documentation is protected by copyright. All rights reserved.
Trademark notice
Android™ and Google Play™ are trademarks of Google LLC in the United
States and/or other countries.
Bluetooth® is a registered trademark of Bluetooth SIG, Inc.
HazMasterG3® is a registered trademark of Alluviam LLC.
Windows® is a registered trademark of Microsoft Corporation in the Uni-
ted States and other countries.
All other trademarks are the property of their respective owners.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Table of contents
MIRA XTR DS
￭￭￭￭￭￭￭￭ III
Table of contents
1 Overview 1
1.1 Instrument description ......................................................... 1
1.2 Model versions ...................................................................... 1
1.3 MIRA software ...................................................................... 2
1.4 Third party software ............................................................. 2
1.5 About the documentation ................................................... 3
1.6 Additional Information – Software tutorials ...................... 5
1.7 Accessories ............................................................................ 5
2 Safety 6
2.1 Intended use ......................................................................... 6
2.2 Responsibility of the operator ............................................. 6
2.3 Personnel requirement ......................................................... 7
2.4 Safety instructions ................................................................ 7
2.4.1 Danger from electrical potential ............................................... 7
2.4.2 Laser safety ............................................................................. 7
2.4.3 Warning stickers on the instrument .......................................... 9
2.4.4 Warning sticker on the autofocus stand-off attachment ......... 11
2.5 Design of warning messages ............................................. 11
2.6 Meaning of warning signs ................................................. 12
3 Functional description 14
3.1 Overview of the instrument ............................................... 14
4 Delivery and storage 16
4.1 Delivery ................................................................................ 16
4.2 Packaging ............................................................................ 16
4.3 Storage ................................................................................ 16
5 Installation 17
5.1 Installing HazMasterG3 app for Android ......................... 17
5.2 Installing MIRA Cal M for Android .................................... 18
5.3 Energy supply ...................................................................... 20
5.3.1 Energy supply with batteries .................................................. 20
5.3.2 Energy supply with MIRA PowerPack ..................................... 23
5.4 USB connection ................................................................... 29

Table of contents ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
IV ￭￭￭￭￭￭￭￭
MIRA XTR DS
5.5 Safe shutdown .................................................................... 29
6 Initial configuration 31
7 Operation and control 32
7.1 Smart Tips – Overview ....................................................... 32
7.2 Attaching Smart Tips .......................................................... 36
7.3 Acquiring data .................................................................... 52
7.4 Acquiring data with the iUA .............................................. 60
7.5 Acquiring data with the AFSO ........................................... 63
7.6 Settings ................................................................................ 67
7.6.1 Operating Procedures menu .................................................. 69
7.6.2 Calibrating the instrument ..................................................... 74
7.6.3 Viewing, enabling and disabling libraries ................................ 76
7.6.4 System Settings menu ............................................................ 76
7.7 Viewing and editing samples in the scan log .................. 90
7.8 Safe shutdown .................................................................... 92
8 Maintenance 93
8.1 Cleaning the product surface ............................................ 93
9 Disposal 95
10 Technical specifications 96
10.1 Ambient conditions ............................................................ 96
10.2 Interfaces ............................................................................. 97
10.3 Energy Supply ..................................................................... 97
10.4 Dimensions and materials .................................................. 97
10.5 Operating specifications .................................................... 98

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 1
1 Overview
1.1 Instrument description
Metrohm Instant Raman Analyzers (MIRA) are handheld, high-power
Raman spectrometers designed for rapid, nondestructive identification of
unknown chemical samples, both liquid and solid. Barely larger than a
smartphone, MIRA spectrometers are the only handheld Raman spectrom-
eters currently on the market with Orbital Raster Scan (ORS) technology.
1.2 Model versions
MIRA XTR DS instruments are available in the following versions:
Table 1 Model versions
2.926.0110 MIRA XTR DS Basic
MIRA XTR DS Basic is a starter pack-
age that contains the basic compo-
nents required for operating MIRA
XTR DS.
Check Metrohm Website for included
parts.
Laser class 3B
2.926.0120 MIRA XTR DS Advanced
MIRA XTR DS Advanced includes a
wide range of attachments suitable
for standard applications in the field
of first responders, military and secur-
ity officials.
Check Metrohm Website for included
parts.
Laser class 3B
NOTICE
To purchase additional Accessories (see chapter 1.7, page 5).

MIRA software ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
2￭￭￭￭￭￭￭￭
1.3 MIRA software
MIRA Cal DS software
In order to configure a MIRA DS or MIRA XTR DS instrument, the follow-
ing software is needed:
Table 2 Model versions
6.06071.020 MIRA Cal DS USB Stick
To download the latest version of MIRA Cal DS software and firmware,
click on the following link:
https://www.metrohm.com/en/support-and-service/software-center/mira-
cal/
MIRA Cal M mobile app
MIRA Cal M allows the user to analyze, manage, or share samples
acquired on MIRA DS or MIRA XTR DS instruments. MIRA Cal M mobile
app can be installed on an Android™ device optionally (see "Installing
MIRA Cal M for Android", page 18).
1.4 Third party software
HazMasterG3® software
HazMasterG3 is a CBRNE/IED and HME investigative tool for use in tradi-
tional incident response situations. It delivers insights and guidance for
167,000+ chemical agents (toxic industrial chemicals (TICs), toxic industrial
materials (TIMs), chemical warfare agents (CWAs), precursors, trade
names, etc.).
HazMasterG3 is compatible with MIRA DS and MIRA XTR DS sample data
and can be installed on an Android or Windows® device optionally.
Table 3 Model versions
6.6071.640 HazMasterG3 Software
The HazMasterG3 software is optional. To purchase the HazMasterG3
software, click on the following link:
https://www.metrohm.com/en-us/products-overview/66071640

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 3
1.5 About the documentation
NOTICE
Please read through this documentation carefully before putting the
product into operation.
The document contains important safety information and warnings
which you must follow in order to ensure safe operation of the instru-
ment. Metrohm is not responsible for damages and safety hazards
that occur from using the instrument in a manner that is not specified
in the user manual.
Symbols and conventions
The following icons and formatting may appear in this documentation:
Cross-reference to figure legend
The first number refers to the figure number, the sec-
ond to the product part in the figure.
Instruction step
Carry out these steps in the sequence shown.
Method Designations for names of parameters, menu items,
tabs and dialog windows in the software.
File ▶ New Menu or menu item
Work area /
Properties
Menu paths in order to arrive at a particular position
in the software.
[Next] Button or key
Proprietary information statement
This manual contains the valuable proprietary information of Metrohm
Raman, Inc. and its affiliates, including all designs and related material,
and such information is disclosed in confidence. It is intended solely for
the information and use of the persons operating and maintaining the
equipment described herein. No part of this manual may be reproduced,
copied, translated, incorporated in any other material, disclosed or trans-
mitted in any form or by any means, whether electronic, mechanical, pho-
tocopying, recording, or otherwise to any other persons for any other pur-
pose without the express written permission of Metrohm Raman, Inc. To
obtain such permission, or to obtain additional copies of this manual,
please contact Metrohm Raman, Inc.

About the documentation ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
4￭￭￭￭￭￭￭￭
Continuous improvements
To remain the leader of the industry, Metrohm Raman, Inc. has a policy of
continuous improvement of its products. As such, all products, product
specifications, data and operating instructions are subject to change with-
out notice.
Liability disclaimer
Metrohm Raman, Inc. and its affiliates take steps to assure that their pub-
lished specifications and manuals are correct. Nevertheless, errors do
occur. Metrohm Raman, Inc. and its affiliates reserve the right to correct
any such errors and disclaim all liability resulting therefrom. The equip-
ment described in this manual is warranted in accordance with the terms
of Metrohm Raman, Inc.’s warranty. However, actual performance of such
equipment is dependent upon factors such as system configuration, cus-
tomer data and operator control. Since implementation by customers of
the equipment may vary, the suitability of specific equipment configura-
tions and applications must be determined by the customer and is not
warranted by Metrohm Raman, Inc. or its affiliates.
Export control statement
These items are controlled by the U.S. Government and authorized for
export only to the country of ultimate destination for use by the ultimate
consignee or end-user(s) identified on the invoice. They may not be resold,
transferred, or otherwise disposed of, to any other country or to any per-
son other than the authorized ultimate consignee or end-user(s), either in
their original form or after being incorporated into other items, without
first obtaining approval from the U.S. Government or as otherwise author-
ized by U.S. law and regulations.
No liability for certain damages
Metrohm Raman, Inc., its affiliates, and anyone else involved in the
design, manufacture, or delivery of the accompanying product (including
hardware and software) shall not be liable, under any circumstances, for
any loss of profits or any special, incidental, consequential, exemplary, or
punitive damages whatsoever (including, without limitation, damages
resulting from cost of replacement, loss of use, loss of data, loss of royal-
ties, loss of profits, loss of revenue, loss of business, loss of prospective
economic advantage, or failure or delay in performance) arising out of the
use of or inability to use such product, even if Metrohm Raman, Inc. or its
affiliates have been notified of the possibility of such damages.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 5
1.6 Additional Information – Software tutorials
Refer to the following manuals for information about the software:
￭Tutorial MIRA Cal DS: 8.105.8069EN
￭Tutorial MIRA Cal M: 8.0105.8023EN
Insert the product number into the search field on
https://www.metrohm.com to find the manuals.
1.7 Accessories
Up-to-date information on the scope of delivery and on optional accesso-
ries can be found on the Metrohm website. Download this information as
follows:
Downloading the accessories list
1Go to https://www.metrohm.com.
2Enter the article number of the product (e.g. 2.1001.0010) into the
search field.
The search result is displayed.
3Click on the product.
Detailed information regarding the product is shown on various tabs.
4On the Included parts tab, click the link to download the PDF.
The PDF file with the accessories data is loaded.
NOTICE
Metrohm recommends downloading the accessories list from the
Internet and keeping it for reference purposes.

Intended use ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
6￭￭￭￭￭￭￭￭
2 Safety
2.1 Intended use
Metrohm products are used for the analysis and handling of chemicals
and other materials.
Usage therefore requires the user to have basic knowledge and experience
in handling chemicals. Knowledge with respect to the application of the
fire prevention measures prescribed for laboratories is also mandatory. Be
sure to take proper safety precautions when working with chemicals
Adherence to this technical documentation and compliance with the
maintenance specifications make up an important part of intended use.
Any utilization in excess of or deviating from the intended use is regarded
as misuse.
Specifications regarding the operating values and limit values of individual
products are contained in the "Technical specifications" section, if relevant.
Exceeding and/or not observing the mentioned limit values puts people
and components at risk. The manufacturer assumes no liability for damage
due to non-observance of these limit values.
The EU declaration of conformity loses its validity if modifications are car-
ried out on the instruments and/or the components.
2.2 Responsibility of the operator
The operator must ensure that basic regulations on occupational safety
and accident prevention in chemical laboratories are observed. The opera-
tor has the following responsibilities:
￭Instruct personnel in the safe handling of the product.
￭Train personnel in the use of the product according to the user docu-
mentation (e.g. install, operate, clean, eliminate faults).
￭Train staff on basic occupational safety and accident prevention regula-
tions.
￭Provide personal protective equipment (e.g. protective glasses, gloves).
￭Provide suitable tools and equipment to carry out the work safely.
The product may be used only when it is in perfect condition. The follow-
ing measures are required to ensure the safe operation of the product:
￭Check the condition of the product before use.
￭Remedy defects and malfunctions immediately.
￭Maintain and clean the product regularly.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 7
2.3 Personnel requirement
Only qualified personnel may operate this product. A qualified person is a
user who has thoroughly reviewed this document and has a comprehen-
sive understanding of the operations of the instrument.
The instrument is used for the analysis of chemical compounds, some of
which may be hazardous. The user must be capable of recognizing and
avoiding possible dangers, and be aware of standards, laws and regula-
tions governing the handling of such chemicals.
2.4 Safety instructions
2.4.1 Danger from electrical potential
WARNING
Electric shock from electrical potential
A considerable danger of injury exists in connection with touching
live parts.
￭Never open the housing of the instrument when the power cord is
connected. You can not service or replace any parts inside the
housing.
￭Only personnel who have been issued Metrohm qualification may
perform service and repair work on electric and electronic parts.
￭The electrical safety of the instrument is ensured as part of the
international standard IEC 61010.
2.4.2 Laser safety
Nominal ocular hazard distance (NOHD)
The following information refers to the nominal ocular hazard distance
(NOHD) for MIRA DS and MIRA XTR DS instruments in accordance with
EN 60825-1, "Safety of laser products", see "Operating specifications",
page 98.

Safety instructions ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
8￭￭￭￭￭￭￭￭
WARNING
Eye injury by laser radiation
Laser radiation can cause serious eye injuries.
￭Follow the safety measures and instructions.
￭Instruments must be used by trained personnel only.
￭Instruments of the laser class 3B must be used in protected and
labeled rooms only.
￭When working with open laser beams (Smart Tips of the laser
class 3B) appropriate protective glasses must be used, see chapter
"Operating specifications" in the MIRA device manuals.
￭Observe the nominal ocular hazard distance (NOHD).
￭Follow the provisions of the IEC 60825-1 standard "Safety of laser
products" and the regulations for the use of laser systems in your
country.
You can purchase protective laser glasses (6.7560.010) from Metrohm AG
Accessories (see chapter 1.7, page 5).
Laser classification depending on Smart Tips
Attached Smart Tip Laser Class 1 Laser Class
3B
Right Angle Attachment X
Universal Attachment X
Intelligent Universal Attachment X
Stand-off Attachment X
Autofocus Stand-off Attachment X
Contact Ball-Probe X
Calibration Standard X
Vial Holder X
Tablet Holder X
Short Working Distance Attach-
ment Lens (SWD)
X
Long Working Distance Attach-
ment Lens (LWD)
X
Extra Long Working Distance
Attachment Lens (XLWD)
X

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 9
Attached Smart Tip Laser Class 1 Laser Class
3B
SERS Attachment X
Tablet Holder, Vial Holder and Calibration Standard have an interlock
mechanism for measurement. This mechanism prevents laser radiation
from emerging. The laser stops immediately if:
￭The lid of the Smart Tip is opened.
￭The attached Smart Tip is disconnected from the instrument.
WARNING
Risk of injury by laser radiation
Serious eye injuries by laser radiation.
￭SERS Attachment (6.07506.040) does not have an interlock mech-
anism.
Laser light can emerge from the laser aperture when the door is
open.
￭Please use caution and ensure that the instrument is powered off
before opening this door for decontamination.
See also
Operating specifications (chapter 10.5, page 98)
2.4.3 Warning stickers on the instrument
The instrument is equipped with laser warning stickers, which are
explained below.

Safety instructions ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
10 ￭￭￭￭￭￭￭￭
Figure 1 Warning stickers on the left side and rear of the instrument
1Laser aperture sticker
Emergence of laser
2Laser classification sticker
Laser classification of the instrument: laser
class 3B
Invisible laser radiation
Avoid exposure to beam
Laser specifications
1
2
3
4
6
5
Figure 2 Sticker at the bottom of the instrument
1Max Power: 100 mW 2Wavelength: 785 nm

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 11
3Complies with
21 CFR 1040.1 & 1040.11 except for
deviations pursuant to
Laser Notice No. 50, dated
June 24, 2007
4Complies with IEC 60825-1:2014
5Serial number 6Manufacturing date: month / day / year
2.4.4 Warning sticker on the autofocus stand-off attachment
1Wavelength: 515 nm Class 2 2Wavelength: 850 nm Class 1
3Compliance information
Complies with FDA performance standards
for laser products except for deviations pur-
suant to Laser Notice No. 56, dated May 8,
2019.
4Manufacturing date
5Serial number
2.5 Design of warning messages
There are 4 hazard levels for warning messages. The following signal
words are used for classifying the hazard levels in warning messages:
￭DANGER indicates a hazardous situation which, if not avoided, will
result in serious injury or death.
￭WARNING indicates a hazardous situation which, if not avoided,
could result in serious injury or death.
￭CAUTION indicates a hazardous situation which, if not avoided, could
result in minor or moderate injury.
￭NOTICE indicates a hazardous situation which, if not avoided, could
result in property damage.
Warning messages differ in design (color and warning sign) depending on
the hazard level:

Meaning of warning signs ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
12 ￭￭￭￭￭￭￭￭
DANGER
Type and source of danger
Consequences when not observing the notice: An irreversible injury
that may result in death is very probable.
￭Measures to avoid the danger
WARNING
Type or source of danger
Consequences when not observing the notice: A serious injury that
may result in death is probable.
￭Measures to avoid the danger
CAUTION
Type or source of danger
Consequences when not observing the notice: A minor to moderate
injury is probable.
￭Measures to avoid the danger
2.6 Meaning of warning signs
This documentation uses the following warning signs:
Table 4 Warning sign according to ISO 7010
Warning sign Meaning
General warning sign
Warning of electrical voltage
Warning of hand injuries
Warning of sharp object

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 13
Warning sign Meaning
Warning of hot surface
Warning of biological hazard
Warning of toxic materials
Warning of flammable materials
Warning of corrosive substances
Warning of optical radiation
Warning of laser beams
Depending on the intended use of the product, the corresponding warn-
ing sign stickers must be placed on the product.

Overview of the instrument ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
14 ￭￭￭￭￭￭￭￭
3 Functional description
3.1 Overview of the instrument
Figure 3 MIRA XTR DS – Front
1Battery compartment 2Type B mini USB connector
3On/off switch 4Touch screen
5Magnetic smart tip fixture / laser aper-
ture