Metrohm Mira DS Series User manual

Mira DS
Product Manual
8.926.8001EN / 2020-03-01

Metrohm AG
Ionenstrasse
CH-9100 Herisau
Switzerland
Phone [phone]
Fax [phone]
[email protected]
www.metrohm.com
Mira DS
Firmware version 8.0.1.136 or higher
Product Manual
8.926.8001EN /
2020-03-01

Technical Communication
Metrohm AG
CH-9100 Herisau
[email protected]
This documentation has been prepared with great care. However, errors
can never be entirely ruled out. Please send comments regarding possible
errors to the address above.
Copyright
This documentation is protected by copyright. All rights reserved.
Trademark notice
Android™ and Google Play™ are trademarks of Google LLC in the United
States and/or other countries.
Bluetooth® is a registered trademark of Bluetooth SIG, Inc.
HazMasterG3® is a registered trademark of Alluviam LLC.
Windows® is a registered trademark of Microsoft Corporation in the Uni-
ted States and other countries.
All other trademarks are the property of their respective owners.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Table of contents
￭￭￭￭￭￭￭￭ III
Table of contents
1 Overview 1
1.1 Instrument description ......................................................... 1
1.2 Model versions ...................................................................... 1
1.3 Mira Cal software ................................................................. 2
1.4 Third party software ............................................................. 2
1.5 About the documentation ................................................... 3
1.6 Additional Information – Software tutorials ...................... 5
1.6.1 Accessories .............................................................................. 5
2 Safety 6
2.1 Product safety ....................................................................... 6
2.2 Hazard levels ......................................................................... 6
2.3 Intended use ......................................................................... 7
2.4 Residual risks ........................................................................ 8
2.4.1 General dangers at the workplace ........................................... 8
2.4.2 Danger from electrical potential ............................................... 9
2.4.3 Laser safety ............................................................................. 9
2.4.4 Warning stickers on the instrument ........................................ 11
2.5 Responsibility of the operator ........................................... 13
2.6 Personnel requirement ....................................................... 14
3 Overview of the instrument 15
4 Transport and storage 17
4.1 Checking the delivery ......................................................... 17
4.2 Storing the packaging ........................................................ 17
4.3 Storage ................................................................................ 17
5 Installation 18
5.1 Installing HazMasterG3 app for Android ......................... 18
5.2 Installing Mira Cal M for Android ..................................... 19
5.3 Energy supply ...................................................................... 21
5.3.1 Energy supply with batteries .................................................. 21
5.3.2 Energy supply with Mira PowerPack ....................................... 24
5.4 USB connection ................................................................... 30
5.5 Safe shutdown .................................................................... 31

Table of contents ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
IV ￭￭￭￭￭￭￭￭
6 Initial configuration 32
7 Operation and control 33
7.1 Smart tips – Overview ........................................................ 33
7.2 Attaching smart tips ........................................................... 36
7.3 Acquiring data .................................................................... 51
7.4 Acquiring data with the iUA .............................................. 58
7.5 Settings ................................................................................ 61
7.5.1 Operating Procedures menu .................................................. 63
7.5.2 Calibrate Device section ......................................................... 67
7.5.3 View Libraries menu .............................................................. 69
7.5.4 System Settings menu ............................................................ 70
7.6 Samples ............................................................................... 82
8 Maintenance 84
8.1 Maintenance agreement .................................................... 84
8.2 Cleaning the product .......................................................... 84
9 Disposal 86
10 Technical specifications 87
10.1 Ambient conditions ............................................................ 87
10.2 Interfaces ............................................................................. 88
10.3 Energy Supply ..................................................................... 88
10.4 Dimensions and materials .................................................. 88
10.5 Operating specifications .................................................... 89

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 1
1 Overview
1.1 Instrument description
Metrohm Instant Raman Analyzers (Mira) are handheld, high-power
Raman spectrometers designed for rapid, nondestructive identification of
unknown chemical samples, both liquid and solid. Barely larger than a
smartphone, the Mira spectrometers are the only handheld Raman spec-
trometers currently on the market with Orbital Raster Scan (ORS) technol-
ogy.
1.2 Model versions
Mira DS instruments are available in the following versions:
Table 1 Model versions
2.926.0010 Mira DS Basic
￭Mira DS
￭With Long Working Distance
Attachment Lens (LWD)
￭With Calibration Standard
￭With Cable USB (OTG) Mini B
plug – USB A plug, 1.8 m
￭And other accessories (see
page 5)
Laser class 3B
2.926.0020 Mira DS Advanced
￭Mira DS
￭With Right Angle Attachment
￭With Universal Attachment
￭With Calibration Standard
￭With Cable USB (OTG) Mini B
plug – USB A plug, 1.8 m
￭And other accessories (see
page 5)
Laser class 3B
2.926.0030 Mira DS Flex
￭Mira DS
￭Without sampling attachments
￭With Calibration Standard
￭With Cable USB (OTG) Mini B
plug – USB A plug, 1.8 m
￭And other accessories (see
page 5)
Laser class 3B
If you are located in the United States you might observe different article
numbers, i.e. 2.926.0025.

Mira Cal software ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
2￭￭￭￭￭￭￭￭
NOTICE
You can purchase other attachments or accessories separately from
Metrohm AG Accessories (see chapter 1.6.1, page 5).
1.3 Mira Cal software
Mira Cal DS software
In order to configure a Mira DS instrument, the following software is
needed:
Table 2 Model versions
6.06071.020 Mira Cal DS USB Stick
To download the latest version of Mira Cal DS software and firmware,
click on the following link:
https://www.metrohm.com/en/support-and-service/software-center/mira-
cal/
Mira Cal M mobile app
In order to analyze and manage samples acquired on a Mira DS instru-
ment, the Mira Cal M mobile app can be installed on an Android™
device optionally.
To install the latest version of the Mira Cal M mobile app, see "Installing
Mira Cal M for Android", page 19.
1.4 Third party software
HazMasterG3® software
HazMasterG3 is a CBRNE/IED and HME investigative tool for use in tradi-
tional incident response situations. It delivers insights and guidance for
167,000+ chemical agents (toxic industrial chemicals (TICs), toxic industrial
materials (TIMs), chemical warfare agents (CWAs), precursors, trade
names, etc.).
HazMasterG3 is compatible with Mira DS sample data and can be installed
on an Android or Windows® device optionally.
Table 3 Model versions
6.6071.640 HazMasterG3 Software
The HazMasterG3 software is optional. To purchase the HazMasterG3
software, click on the following link:

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 3
https://www.metrohm.com/en-us/products-overview/66071640
1.5 About the documentation
NOTICE
Please read through this documentation carefully before putting the
product into operation.
The document contains important safety information and warnings
which you must follow in order to ensure safe operation of the instru-
ment. Metrohm is not responsible for damages and safety hazards
that occur from using the instrument in a manner that is not specified
in the user manual.
Symbols and conventions
The following icons and formatting may appear in this documentation:
Cross-reference to figure legend
The first number refers to the figure number, the sec-
ond to the product part in the figure.
Instruction step
Carry out these steps in the sequence shown.
Method Designations for names of parameters, menu items,
tabs and dialog windows in the software.
File ▶ New Menu or menu item
Work area /
Properties
Menu paths in order to arrive at a particular position
in the software.
[Next] Button or key
Proprietary information statement
This manual contains the valuable proprietary information of Metrohm
Raman, Inc. and its affiliates, including all designs and related material,
and such information is disclosed in confidence. It is intended solely for
the information and use of the persons operating and maintaining the
equipment described herein. No part of this manual may be reproduced,
copied, translated, incorporated in any other material, disclosed or trans-
mitted in any form or by any means, whether electronic, mechanical, pho-
tocopying, recording, or otherwise to any other persons for any other pur-
pose without the express written permission of Metrohm Raman, Inc. To

About the documentation ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
4￭￭￭￭￭￭￭￭
obtain such permission, or to obtain additional copies of this manual,
please contact Metrohm Raman, Inc.
Continuous improvements
To remain the leader of the industry, Metrohm Raman, Inc. has a policy of
continuous improvement of its products. As such, all products, product
specifications, data and operating instructions are subject to change with-
out notice.
Liability disclaimer
Metrohm Raman, Inc. and its affiliates take steps to assure that their pub-
lished specifications and manuals are correct. Nevertheless, errors do
occur. Metrohm Raman, Inc. and its affiliates reserve the right to correct
any such errors and disclaim all liability resulting therefrom. The equip-
ment described in this manual is warranted in accordance with the terms
of Metrohm Raman, Inc.’s warranty. However, actual performance of such
equipment is dependent upon factors such as system configuration, cus-
tomer data and operator control. Since implementation by customers of
the equipment may vary, the suitability of specific equipment configura-
tions and applications must be determined by the customer and is not
warranted by Metrohm Raman, Inc. or its affiliates.
Export control statement
These items are controlled by the U.S. Government and authorized for
export only to the country of ultimate destination for use by the ultimate
consignee or end-user(s) identified on the invoice. They may not be resold,
transferred, or otherwise disposed of, to any other country or to any per-
son other than the authorized ultimate consignee or end-user(s), either in
their original form or after being incorporated into other items, without
first obtaining approval from the U.S. Government or as otherwise author-
ized by U.S. law and regulations.
No liability for certain damages
Metrohm Raman, Inc., its affiliates, and anyone else involved in the
design, manufacture, or delivery of the accompanying product (including
hardware and software) shall not be liable, under any circumstances, for
any loss of profits or any special, incidental, consequential, exemplary, or
punitive damages whatsoever (including, without limitation, damages
resulting from cost of replacement, loss of use, loss of data, loss of royal-
ties, loss of profits, loss of revenue, loss of business, loss of prospective
economic advantage, or failure or delay in performance) arising out of the
use of or inability to use such product, even if Metrohm Raman, Inc. or its
affiliates have been notified of the possibility of such damages.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Overview
￭￭￭￭￭￭￭￭ 5
1.6 Additional Information – Software tutorials
Refer to following software tutorials for more information:
￭Mira Cal DS software tutorial: 8.105.8069EN
￭Mira Cal M mobile app tutorial: 8.0105.8023EN
1.6.1 Accessories
Up-to-date information on the scope of delivery and optional accessories
for your product can be found on the Internet. You can download this
information using the article number as follows:
Downloading the accessories list
1Enter https://www.metrohm.com/ into your Internet browser.
2Enter the article number of the product (e.g. 2.1001.0010) into the
search field.
The search result is displayed.
3Click on the product.
Detailed information regarding the product is shown on various tabs.
4On the Included parts tab, click Download the PDF.
The PDF file with the accessories data is created.
NOTICE
When you receive your new product, we recommend downloading
the accessories list from the Internet, printing it out and keeping it for
reference purposes.

Product safety ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
6￭￭￭￭￭￭￭￭
2 Safety
2.1 Product safety
This product exhibited no flaws in terms of technical safety at the time it
left the factory. To preserve this status and ensure non-hazardous opera-
tion of the product, the following instructions must be observed carefully.
2.2 Hazard levels
The following warning messages indicate the severity of the danger and
its possible effects.
DANGER
Immediate danger of life
Irreversible injuries that will result in death.
Warns of dangerous situations or unsafe actions that will most cer-
tainly cause severe injuries or death.
Lists measures to avoid hazard.
WARNING
Severe health hazards
Serious injuries that could result in death.
Warns of dangerous situations or unsafe actions that could result in
serious injuries or death.
Lists measures to avoid hazard.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 7
CAUTION
Health hazards or severe property damage
Warns of dangerous situations or unsafe actions that could result in
moderate injuries or considerable property damage.
Lists measures to avoid hazard.
2.3 Intended use
Metrohm products are used for the analysis and handling of chemicals
and other materials.
Usage therefore requires the user to have basic knowledge and experience
in handling chemicals. Knowledge with respect to the application of the
fire prevention measures prescribed for laboratories is also mandatory. Be
sure to take proper safety precautions when working with chemicals
Adherence to this technical documentation and compliance with the
maintenance specifications make up an important part of intended use.
Any utilization in excess of or deviating from the intended use is regarded
as misuse.
Specifications regarding the operating values and limit values of individual
products are contained in the "Technical specifications" section, if relevant.
Exceeding and/or not observing the mentioned limit values puts people
and components at risk. The manufacturer assumes no liability for damage
due to non-observance of these limit values.
The EU declaration of conformity loses its validity if modifications are car-
ried out on the instruments and/or the components.

Residual risks ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
8￭￭￭￭￭￭￭￭
2.4 Residual risks
2.4.1 General dangers at the workplace
Generally, the regulations and provisions of the regulatory institutions and
authorities in the field of work apply.
The instructions regarding the following areas have to be followed when
using the products:
￭Work safety
￭Handling mechanical installations
￭Handling electricity
￭Handling hazardous and environmentally damaging substances
￭Handling hazardous and environmentally damaging liquids
￭Disposing hazardous and environmentally damaging substances
If they are not followed, this may result in:
￭Disturbing, injuring and/or killing of people
￭Malfunction and/or damage to instruments and infrastructure
￭Damage and/or contamination of the environment
WARNING
General dangers at workplace
If the safety measures are not followed, working in a laboratory bears
a high risk of injury, which can endanger life and health.
￭Only professionally trained and qualified specialist personnel may
operate the products.
￭Follow the applicable provisions concerning work safety and all
regulations on wearing protective clothing.
￭Use suitable tools to perform your work.
￭Check the fill level of waste bottles or waste canisters and analysis
vessels, and make sure they do not overflow.
￭Use protective grounding when working with highly flammable
substances and gases.

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 9
2.4.2 Danger from electrical potential
WARNING
Electric shock from electrical potential
A considerable danger of injury exists in connection with touching
live parts.
￭Never open the housing of the instrument when the power cord is
connected. You can not service or replace any parts inside the
housing.
￭Only personnel who have been issued Metrohm qualification may
perform service and repair work on electric and electronic parts.
￭The electrical safety of the instrument is ensured as part of the
international standard IEC 61010.
2.4.3 Laser safety
NOTICE
NOHD
The following information refers to NOHD for Mira DS instruments in
accordance with EN 60825-1, "Safety of laser products".
The nominal ocular hazard distance (NOHD) is listed in the technical
specifications of Mira DS, see page 89.

Residual risks ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
10 ￭￭￭￭￭￭￭￭
WARNING
Risk of injury by laser radiation
Serious eye injuries by laser radiation.
￭Follow the safety measures and instructions.
￭Instruments must be used by trained personnel only.
￭Instruments of the laser class 3B must be used in protected and
labeled rooms only.
￭Appropriate protective eyewear according to the technical specifi-
cations (see page 89) must be used when working with open
laser beams (smart tips of the laser class 3B).
￭Observe the nominal ocular hazard distance (NOHD).
￭Follow the provisions of the IEC 60825-1 standard "Safety of laser
products" and the regulations for the use of laser systems in your
country.
You can purchase protective laser glasses (6.7560.010) from Metrohm AG
Accessories (see chapter 1.6.1, page 5).
Laser Classification depending on Smart Tips
Attached Smart Tip Laser Class 1 Laser Class
3B
Right Angle Attachment X
Universal Attachment X
Intelligent Universal Attachment X
Standoff Attachment X
Contact Ball-Probe X
Calibration Standard X
Vial Holder X
Tablet Holder X
Short Working Distance Attach-
ment Lens (SWD)
X
Long Working Distance Attach-
ment Lens (LWD)
X
Extra Long Working Distance
Attachment Lens (XLWD)
X
SERS Attachment X

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 11
Tablet Holder, Vial Holder and Calibration Standard have an interlock
mechanism for measurement. This mechanism prevents laser radiation
from emerging.
Laser stops immediately if:
￭The lid of the smart tip is opened.
￭Attached smart tip is disconnected from the instrument.
WARNING
Risk of injury by laser radiation
Serious eye injuries by laser radiation.
￭SERS Attachment (6.07506.040) does not have an interlock mech-
anism.
Laser light can emerge from the laser aperture when the door is
open.
￭Please use caution and ensure that the instrument is powered off
before opening this door for decontamination.
2.4.4 Warning stickers on the instrument
The instrument is equipped with stickers that warn of potential hazards.
These warning stickers are listed and explained below.

Residual risks ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
12 ￭￭￭￭￭￭￭￭
1Laser aperture 2Laser aperture sticker
3Laser specification / serial number (bot-
tom of instrument)
4Laser class
5Type plate 6Bluetooth label
Emergence of laser
￭Laser aperture

￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭ Safety
￭￭￭￭￭￭￭￭ 13
Laser specifications
1
2
3
4
6
5
1Max Power: 100 mW 2Wavelength: 785 nm
3Complies with
21 CFR 1040.1 & 1040.11 except for
deviations pursuant to
Laser Notice No. 50, dated
June 24, 2007
4Complies with IEC 60825-1:2014
5Serial number 6Manufacturing date: month / day / year
Laser class
The following laser classification is used for all Mira instruments.
￭Invisible laser radiation
￭Avoid exposure to beam
￭Class 3B laser product
2.5 Responsibility of the operator
￭Eliminate defects or damage which impair operating safety without
delay.
￭Eliminate malfunctions which could impair safety without delay.
￭The rules, regulations and instructions listed in the present document
are not the only valid ones. Comply with the applicable statutory rules,
government agency directives and regulations.
￭Unauthorized modification of the products excludes any and all liability
on the part of the manufacturer for any damage resulting from this as
well as for any consequential damage. No modifications, attachments
or conversions which could impair safety may be carried out on the
products without the approval of the manufacturer.
￭Spare parts must meet the technical requirements established by the
manufacturer. Original spare parts always meet these requirements.
￭Personnel must be familiar with this safety-relevant information and it
must be available for consultation at all times.

Personnel requirement ￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭￭
14 ￭￭￭￭￭￭￭￭
2.6 Personnel requirement
Only qualified personnel may operate the present product.
Qualified personnel are people authorized by the safety responsible to
carry out the necessary operations. They are capable of recognizing and
avoiding possible dangers. These people are qualified due to their profes-
sional training, experience and/or instruction. They know the relevant
standards, laws, provisions, accident prevention regulations and the com-
pany conditions.