Agilent Technologies 5100 ICP-OES Operating instructions

Agilent 5100 and 5110
ICP-OES
Site Preparation Guide

2 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Notices
© Agilent Technologies, Inc.
2014, 2016
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Manual Part Number
G8010-90001
Edition
Second edition, March 2016
Agilent Technologies, Australia (M)
Pty Ltd
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Mulgrave, Victoria, 3170
Australia
www.agilent.com
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Safety Notices
A CAUTION notice denotes a hazard.
It calls attention to an operating
procedure, practice, or the like that, if
not correctly performed or adhered to,
could result in damage to the product
or loss of important data. Do not
proceed beyond a CAUTION notice
until the indicated conditions are fully
understood and met.
A WARNING notice denotes a
hazard. It calls attention to an
operating procedure, practice, or the
like that, if not correctly performed or
adhered to, could result in personal
injury or death. Do not proceed
beyond a WARNING notice until the
indicated conditions are fully
understood and met.
WARNING
CAUTION

Request for Installation
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 3
Request for Installation
All preparations have been completed. Please arrange for the
installation to be completed as soon as possible. I understand that if
the installation site is not prepared in accordance with the enclosed
instructions, additional installation charges may apply.
Company name:
Company address:
Name:
Position:
Telephone:
Preferred installation date:
Signed:
Date:

Site Preparation Checklist
4 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Site Preparation Checklist
Your site must meet all requirements before you request installation.
Complete each requirement listed in the table. After completing each
requirement, place a check in the appropriate check box. Ensure you
compare the boxes with the shipping list supplied with the boxes.
Requirements 
Principal installation area is in compliance with all relevant safety regulations. 
Laboratory temperature is maintained between 15-30°C (59-86°F) 
Laboratory is free of excessive particulate matter. 
Cooling air system is set up (if required). 
Workbench requirements are met. 
Sufficient bench space is available for all components. 
Bench can support system weight. 
Personal computer with Microsoft Windows 7 Professional 64-bit SP1 installed and printer is set up, if
purchased separately.

Entrance to the lab is at least 1050 mm (41.3 in) wide for packaged instrument, or 800 mm (31.5 in) wide for
unpackaged instrument.

Exhaust system is suitable. 
Specified electrical supply and power outlets are installed. 
Gas supply (at specified purity), regulator, and gas lines are installed for argon and any allowed optional
gases.

Water cooling/circulation system and power connections are set up, if system is not purchased from
Agilent.

Waste container appropriate for the chemical waste is prepared. 
Accessories
SPS 4 Autosampler 
SPS 3 Sample Preparation System 
Advanced valve system (AVS) 4, 6, or 7 Switching Valve 
SVS 2+ Productivity Package 
VGA Vapor Generation Accessory 
5 Channel Peristaltic Pump 
Air Inlet Duct Filter 
External Inlet Duct Adapter 
Multimode Sample Introduction System (MSIS) 
Argon Saturator Accessory (ASA) 

Contents
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 5
Contents
Request for Installation 3
Site Preparation Checklist 4
1. Safety Practices and Hazards 9
General 9
Plasma 10
Heat, Vapors and Fumes 11
Compressed Gas Hazards 11
Electrical Hazards 12
Other Precautions 12
Warning Symbols 14
CE Compliance 15
Electromagnetic Compatibility 16
EN55011/CISPR11 16
ICES/NMB-001 17
South Korean Class A EMC declaration 17
2. Introduction 19
Installation Guidelines 19
3. Laboratory Environment 21
Environmental Conditions 21
Installation category 21
Pollution level 21

Safety Practices and Hazards
6 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Temperature Control 22
Cleanliness 22
Instrument Cooling Air Supply 23
Workbench 24
Location 25
PC Requirements 28
4. Instrument Shipping Information 29
In-house Transit Routes 29
Insurance after Delivery 31
Weights and Dimensions 31
Transit Damage 33
Seismic Requirements 34
5. Laboratory Facilities 35
Exhaust System 35
Agilent Exhaust System 36
Electrical Power Supplies 39
Electrical Requirements 40
Single phase requirement 40
Power plugs and cords 40
Other Connections 41
Circuit Breaker 41
Gas Supplies 41
Storage Cylinder Instructions 43
Water Chiller System 44
Location 46

Contents
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 7
Waste Fluid Container 47
Guidelines for Software Installation 47
6. Accessories and Options 49
Sample Preparation System (SPS 4) Autosampler 49
Sample Preparation System (SPS 3) Autosampler 49
Environmental Conditions 49
Advanced Switching Valve—AVS 4, AVS 6 or AVS 7 Switching
Valve 50
SVS 2+ Productivity Package Accessory 50
5-Channel Peristaltic Pump 51
External Inlet Duct Adapter 51
Vapor Generation Accessory (VGA) Recommended Gases 51
Multimode Sample Introduction System (MSIS) 52
Argon Saturator Accessory (ASA) 52
Appendix A: Power Cords 53

Safety Practices and Hazards
8 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
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Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 9
1. Safety Practices and Hazards
General
Unless otherwise specified, statements in this manual apply to both
the Agilent 5100 and 5110 ICP-OES instruments.
Operation of an Agilent ICP-OES involves the use of compressed
gases, high voltage radio frequency energy and hazardous materials
including corrosive fluids and flammable liquids. Careless, improper
or unskilled use of this spectrometer or chemicals used with it can
cause death or serious injury to personnel, and/or severe damage to
equipment and property. Only trained personnel should use this
instrument.
The spectrometer incorporates interlocks and covers that are
designed to prevent inadvertent contact with any potential hazards.
If the instrument is used in any manner not specified by Agilent, this
protection provided by the equipment may be impaired. It is good
practice to develop safe working habits that do not depend upon the
correct operation of the interlocks for safe operation. It is essential
that no interlock or cover is bypassed, damaged or removed.
The safety practices described below are provided to help the user
operate the instrument safely. Read each safety topic thoroughly
before attempting to operate the instrument and always operate the
spectrometer in accordance with these safety practices.

Safety Practices and Hazards
10 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Plasma
The plasma is extremely hot (about 7,500 °C) and radiates dangerous
levels of radio frequency (RF) and ultraviolet (UV) energy. The work
coil operates at 1,500 V RMS and about 27 MHz. Exposure to the RF
and UV energy can cause severe skin damage and cataracts of the
eyes, while close contact with the operating plasma can result in
severe heat burns to the skin, and an electrical discharge that can
jump a considerable distance and may cause death, severe electric
shock or sub-surface skin burns.
The plasma must never be operated unless:
the plasma compartment door is closed, with the locking lever
fully latched; and
the space above the chimney and air intake is clear of objects.
The shielding around the torch compartment is designed to reduce
UV, visible and RF radiation to safe levels while still permitting easy
access to, as well as installation and viewing of, the torch. The
spectrometer has an interlock system that is designed to extinguish
the plasma if either the mains supply fails, the handle on the torch
compartment door is opened, or the torch loading handle is open. Do
not attempt to bypass the interlock system.
Before opening the torch compartment door, always extinguish the
plasma by pressing SHIFT + F5 on the keyboard or by clicking the
‘Plasma Off’ icon on the ICP Expert software toolbar.
The torch and its surroundings remain hot for up to five minutes
after the plasma is extinguished. Touching this area before it has
cooled sufficiently may result in burns. Allow the torch and torch
compartment to cool before carrying out any work in this area, or
wear heat-resistant gloves.
The plasma system has been carefully designed to operate safely and
effectively when using torches and related components that conform
to Agilent’s design criteria. Use of non-approved components in the
plasma compartment may render the system inoperative and/or
hazardous. It may also invalidate the warranty on the instrument.
Use only torches and related components supplied or authorized by
Agilent.

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 11
Heat, Vapors and Fumes
Heat, ozone, vapors and fumes generated by the plasma can be
hazardous, and must be extracted from the instrument by means of
an exhaust system. Ensure that an exhaust system of the appropriate
type is fitted (see Page 36). The system must be vented to the outside
air in accordance with local regulations and never within the
building. Regularly check the exhaust system by smoke test to ensure
that the exhaust system is functioning correctly. The exhaust fan
must always be switched on before igniting the plasma.
Compressed Gas Hazards
All compressed gases (other than air) can create a hazard if they leak
into the atmosphere. Even small leaks in gas supply systems can be
dangerous. Any leak (except that of air or oxygen) can result in an
oxygen-deficient atmosphere, which can cause asphyxiation. The
area in which cylinders are stored and the area surrounding the
instrument must be adequately ventilated to prevent such gas
accumulations.
Gas cylinders must be stored and handled strictly in accordance with
local safety codes and regulations. Cylinders must be used and stored
only in a vertical position and secured to an immovable structure or
a properly constructed cylinder stand. Move cylinders only by
securing them to a properly constructed trolley.
Use only approved regulator and hose connectors (refer to the gas
supplier’s instructions). Keep gas cylinders cool and properly
labeled. (All cylinders are fitted with a pressure relief device that will
rupture and empty the cylinder if the internal pressure is raised
above the safe limit by excessive temperatures.) Ensure that you have
the correct cylinder before connecting it to the instrument.
The primary gas to be used with the spectrometer is argon, which is
the conductive gas for the plasma. Argon or nitrogen can be used as
the polychromator purge gas. Other gases may be required for future
options and accessories. Use only ‘instrument grade’ gases with your
spectrometer.
If using cryogenic gases (for example, liquid argon), prevent severe
burns by wearing suitable protective clothing and gloves.

Safety Practices and Hazards
12 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Electrical Hazards
The spectrometer system and some accessories contain electrical
circuits, devices and components operating at dangerous voltages.
Contact with these circuits, devices and components can cause death,
serious injury or painful electric shock. Panels or covers which are
retained by screws on the spectrometer and accessories may be
opened only by Agilenttrained, Agilent-qualified or Agilentapproved
field service engineers (unless specified otherwise). Consult the
manuals or product labels supplied with your personal computer
(PC), monitor, printer and water-cooling system to determine which
parts of those systems are operator-accessible.
Connecting the Agilent ICP-OES to a power source that is not
equipped with a protective earth contact creates a shock hazard for
the operator and can damage the instrument. Likewise, interrupting
the protective conductor inside or outside the Agilent ICP-OES or
defeating the power cord ground creates a shock hazard for the
operator and can damage the instrument.
Other Precautions
Use of the spectrometer system and accessories may involve
materials, solvents and solutions which are flammable, corrosive,
toxic or otherwise hazardous. Careless, improper or unskilled use of
such materials, solvents and solutions can create explosion hazards,
chemical burn hazards, fire hazards, toxicity and other hazards that
can result in death, serious personal injury or damage to equipment.
Apply all necessary precautions including use of lab coats, safety
goggles and other appropriate forms of personal protection. All
wastes should be disposed of in accordance with local regulatory
requirements.
Operation of an ICP-OES involves analysis of solutions that have
been prepared in or digested with acids, or in some cases, samples
that have been prepared in organic solvents.
In case of uncertainty about a specific fluid, that fluid should not be
used until confirmation by the manufacturer that it will not present a
hazard.

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 13
The acid concentration in the sample that is measured is variable,
depending upon the digestion steps and acid types used. Instrument
users should be aware of the hazards associated with use of the acids
used for sample preparation and apply all necessary precautions
including use of lab coats, safety goggles and other appropriate forms
of personal protection. The acid wastes should be disposed of in
accordance with local regulatory requirements.
The type, volatility and concentration of the organic solvents used in
the sample that is measured is variable, depending upon the selected
solvent and the sample preparation involved. Instrument users
should be aware of the hazards associated with use of the organic
solvents used for sample preparation, and apply all necessary
precautions including ensuring adequate ventilation during use, and
use of lab coats, safety goggles and other appropriate forms of
personal protection. The organic wastes should be disposed of in
accordance with local regulatory requirements.
Air flow to the cooling fans of the spectrometer and accessories must
be unobstructed. Do not block the ventilation grills on the
spectrometer and accessories. Consult the manuals supplied with
your PC, monitor, printer and water-cooling system for their specific
ventilation requirements.
Great care should be taken when working with glass or quartz parts
to prevent breakage and cuts. This is especially important when
attaching plastic tubing to the nebulizer, inserting the nebulizer into
the spraychamber, or removing and replacing pieces of broken torch.
The spectrometer weighs approximately 106 kg (234 lb). To avoid
injury to personnel or damage to the instrument or property, always
use a forklift or other suitable mechanical lifting device to move the
instrument.
Use only Agilent-supplied spares with your instrument.
Only trained operators should use the instrument.

Safety Practices and Hazards
14 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Warning Symbols
The following is a list of symbols that appear in conjunction with
warnings on the spectrometer. The hazard they describe is also
shown. The beginning of the warning text is noted by a warning icon:
WARNING
A triangular symbol indicates a warning. The meanings of the
symbols that may appear alongside warnings in the documentation
or on the instrument itself are as follows:
Broken glass Chemical hazard Electrical shock
Extreme cold hazard
Eye hazard
Fire hazard
Heavy weight
(danger to feet)
Heavy weight
(danger to hands)
Hot surface
Noxious gases
RF radiation
The following symbol may be used on warning labels attached to the
instrument. When you see this symbol, refer to the relevant operation
or service manual for the correct procedure referred to by that
warning label.

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 15
The following symbols appear on the instrument for your
information.
I Mains power on
0 Mains power off
Single phase alternating current
Protective ground terminal.
Socket for Agilent accessory serial cable
Socket for Ethernet LAN cable
Socket for Agilent accessory USB cable
Indication of correct orientation of gas filter flow direction
CE Compliance
Your Agilent ICP-OES instrument has been designed to comply with
the requirements of the Electromagnetic Compatibility (EMC)
Directive and the Machinery Directive (MD) of the European Union.
Agilent has confirmed that each product complies with the relevant
Directives by testing a prototype against the prescribed EN
(European Norm) standards.

Safety Practices and Hazards
16 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
Proof that a product complies with these directives is indicated by:
the CE Marking appearing on the rear of the product, and
the documentation package that accompanies the product
containing a copy of the Declaration of Conformity. The
Declaration of Conformity is the legal declaration by Agilent that
the product complies with the directives listed above, and shows
the EN standards to which the product was tested to
demonstrate compliance.
Electromagnetic Compatibility
EN55011/CISPR11
Group 1 ISM equipment: group 1 contains all Industrial, Scientific
and Medical (ISM) equipment in which there is intentionally
generated and/or used conductively coupled radio- frequency energy
which is necessary for the internal functioning of the equipment
itself.
Class A equipment is equipment suitable for use in all
establishments other than domestic and those directly connected to a
low voltage power supply network which supplies buildings used for
domestic purposes.
This device complies with the requirements of CISPR11, Group 1,
Class A as radiation professional equipment. Therefore, there may be
potential difficulties in ensuring electromagnetic compatibility in
other environments, due to conducted as well as radiated
disturbances.
Operation is subject to the following two conditions:
1This device may not cause harmful interference.
2This device must accept any interference received, including
interference that may cause undesired operation.
If this equipment does cause harmful interference to radio or
television reception, which can be determined by turning the
equipment off and on, the user is encouraged to try one or more of
the following measures:
1Relocate the radio or antenna.
2Move the device away from the radio or television.

Safety Practices and Hazards
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 17
3Plug the device into a different electrical outlet, so that the device
and the radio or television are on separate electrical circuits.
4Make sure that all peripheral devices are also certified.
5Make sure that appropriate cables are used to connect the device
to peripheral equipment.
6Consult your equipment dealer, Agilent Technologies, or an
experienced technician for assistance.
Changes or modifications not expressly approved by Agilent
Technologies could void the user’s authority to operate the
equipment.
ICES/NMB-001
This ISM device complies with Canadian ICES- 001.
Cet appareil ISM est conforme à la norme NMB-001 du Canada.
South Korean Class A EMC declaration
A 급기기 ( 업무용 방송통신기자재 )
This equipment is Class A suitable for professional use and is for use
in electromagnetic environments outside of the home.
이 기기는 업무용 (A 급 ) 전자파적합기기로서 판 매자 또는 사용자는
이 점을 주
의하시기 바라 며 , 가정외의 지역에서 사용하는 것을 목적으 로
합니다 .
After all safety regulations have been met, check the checklist box: Principal installation
area is in compliance with all relevant safety regulations.

Safety Practices and Hazards
18 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
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Introduction
Agilent 5100 and 5110 ICP-OES Site Preparation Guide 19
2. Introduction
This publication contains the information required to successfully
prepare a site for an Agilent ICP-OES system installation.
On completion of the site preparation, fill in the checklist on Page 4,
(striking out those entries not applicable), and send this checklist to
your local Agilent agent or Agilent sales and service office. As soon
as it is received, Agilent or its agent will contact you to arrange a
convenient time for installation.
If you have difficulty in preparing for the installation, and for details
of operator training courses, please contact your Agilent sales or
field service representative.
Installation Guidelines
Allow a minimum of one day for the installation of the Agilent
ICP-OES system by an Agilent field service engineer.
The installation will include the following:
Spectrometer installation
Water chiller connection
Instrument software installation and registration
Accessory installation
Spectrometer installation performance tests
Basic customer training
Maintenance overview

Introduction
20 Agilent 5100 and 5110 ICP-OES Site Preparation Guide
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