Endress+Hauser Liquiline CA80SI User manual

Products Solutions Services
Operating Instructions
Liquiline System CA80SI
Colorimetric analyzer for silica
BA01650C/07/EN/01.18
71405419
2018-11-21
Valid as of version
01.06.06

Liquiline System CA80SI Table of contents
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Table of contents
1 About this document ................ 5
1.1 Warnings ............................ 5
1.2 Symbols .............................. 5
1.3 Symbols on the device ................... 5
1.4 Documentation ........................ 6
2 Basic safety instructions ............ 7
2.1 Requirements for the personnel ............ 7
2.2 Designated use ........................ 7
2.3 Occupational safety ..................... 7
2.4 Operational safety ...................... 7
2.5 Product safety ......................... 9
3 Product description ................ 10
3.1 Product design ........................ 10
3.2 Measuring system ..................... 11
3.3 Equipment architecture ................. 12
4 Incoming acceptance and product
identification ..................... 14
4.1 Incoming acceptance ................... 14
4.2 Product identification ................... 14
4.3 Scope of delivery ...................... 15
5 Certificates and approvals ......... 16
5.1  mark ............................. 16
5.2 cCSAus ............................. 16
6 Installation ....................... 17
6.1 Installation conditions .................. 17
6.2 Mounting the analyzer on a wall .......... 20
6.3 Installing version with analyzer stand ....... 21
6.4 1-/2-channel version: Installing pressure
relief valve and filter ................... 22
6.5 4-/6-channel version: Installing panel with
pressure relief valves and filters ........... 24
6.6 4-/6-channel version: Installing panel with
sample channel switching ............... 25
6.7 Post-installation check .................. 26
7 Electrical connection .............. 27
7.1 Connection conditions .................. 27
7.2 Connecting the analyzer ................. 27
7.3 Connecting the sensors and additional
modules ............................ 29
7.4 Hardware settings ..................... 36
7.5 Ensuring the degree of protection .......... 37
7.6 Post-connection check .................. 37
8 System integration ................ 39
8.1 Web server .......................... 39
8.2 Service interface ...................... 40
8.3 Fieldbuses ........................... 41
9 Operation options ................. 43
9.1 Structure and function of the operating
menu .............................. 43
9.2 Access to the operating menu via the local
display ............................. 43
10 Commissioning .................... 46
10.1 Preparatory steps ...................... 46
10.2 Switching on the measuring device ......... 50
10.3 Setting the operating language ............ 50
10.4 Configuring the measuring device .......... 50
10.5 Function check ....................... 51
11 Operation ......................... 53
11.1 General settings ....................... 53
11.2 Analyzer ............................ 65
11.3 Current inputs ........................ 70
11.4 Binary inputs and outputs ............... 71
11.5 Signal outputs ........................ 80
11.6 Additional functions ................... 88
12 Diagnostics and troubleshooting .. 110
12.1 General troubleshooting ................ 110
12.2 Diagnostic information on local display ..... 111
12.3 Diagnostic information via web browser .... 111
12.4 Diagnostic information via fieldbus ........ 111
12.5 Adapting the diagnostic information ...... 112
12.6 Overview of diagnostic information ....... 114
12.7 Pending diagnostic messages ............ 119
12.8 Diagnostics list ...................... 120
12.9 Logbooks ........................... 120
12.10 System information ................... 125
12.11 Sensor information ................... 126
12.12 Simulation .......................... 126
12.13 Device test .......................... 127
12.14 Resetting ........................... 129
12.15 Operating time information ............. 129
12.16 Firmware history ..................... 130
13 Maintenance .................... 131
13.1 Maintenance schedule ................. 131
13.2 Cleaning ........................... 132
13.3 Replacing reagents ................... 132
13.4 Replacing the hoses ................... 133
13.5 Replacing filter mats .................. 134
13.6 Replacing the dispensers ............... 134
13.7 Replacing the magnetic stir bar .......... 135

Table of contents Liquiline System CA80SI
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13.8 Decommissioning .................... 135
14 Repair ........................... 138
14.1 Spare parts ......................... 138
14.2 Return ............................. 138
14.3 Disposal ........................... 138
15 Accessories ...................... 139
15.1 Consumables for CA80SI ............... 139
15.2 Sensors ............................ 139
15.3 Additional functionality ................ 142
15.4 Measuring cable ..................... 143
15.5 Software ........................... 144
15.6 Other accessories ..................... 144
16 Technical data ................... 145
16.1 Input .............................. 145
16.2 Output ............................ 146
16.3 Current outputs, active ................. 146
16.4 Relay outputs ........................ 147
16.5 Protocol-specific data .................. 148
16.6 Power supply ........................ 150
16.7 Performance characteristics ............. 155
16.8 Environment ........................ 156
16.9 Process ............................ 156
16.10 Mechanical construction ............... 156
Index ................................. 158

Liquiline System CA80SI About this document
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1 About this document
1.1 Warnings
Structure of information Meaning
LDANGER
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid the dangerous situation will result in a fatal or serious
injury.
LWARNING
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid the dangerous situation can result in a fatal or serious
injury.
LCAUTION
Causes (/consequences)
If necessary, Consequences of
non-compliance (if applicable)
‣Corrective action
This symbol alerts you to a dangerous situation.
Failure to avoid this situation can result in minor or more serious injuries.
NOTICE
Cause/situation
If necessary, Consequences of
non-compliance (if applicable)
‣Action/note
This symbol alerts you to situations which may result in damage to
property.
1.2 Symbols
Symbol Meaning
Additional information, tips
Permitted or recommended
Not permitted or not recommended
Reference to device documentation
Reference to page
Reference to graphic
 Result of a step
1.3 Symbols on the device
Symbol Meaning
Reference to device documentation
Caution: Hazardous voltage

About this document Liquiline System CA80SI
6 Endress+Hauser
1.4 Documentation
The following instructions complement these Operating Instructions and are available on
the product pages on the Internet:
• Brief Operating Instructions Liquiline System
• Operating Instructions Memosens, BA01245C
– Software description for Memosens inputs
– Calibration of Memosens sensors
– Sensor-specific diagnostics and troubleshooting
• Guidelines for communication via fieldbus and web server
– PROFIBUS, SD01188C
– Modbus, SD01189C
– Web server, SD01190C
– EtherNet/IP, SD01293C
• Documentation on other devices in the Liquiline platform:
– Liquiline CM44xR (DIN rail device)
– Liquiline System CAT8x0 (sample preparation)
– Liquistation CSFxx (sampler)
– Liquiport CSP44 (sampler)

Liquiline System CA80SI Basic safety instructions
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2 Basic safety instructions
2.1 Requirements for the personnel
• Installation, commissioning, operation and maintenance of the measuring system may
be carried out only by specially trained technical personnel.
• The technical personnel must be authorized by the plant operator to carry out the
specified activities.
• The electrical connection may be performed only by an electrical technician.
• The technical personnel must have read and understood these Operating Instructions
and must follow the instructions contained therein.
• Faults at the measuring point may only be rectified by authorized and specially trained
personnel.
Repairs not described in the Operating Instructions provided must be carried out only
directly at the manufacturer's site or by the service organization.
2.2 Designated use
The Liquiline System CA80SI is a wet-chemical analyzer for almost continuous
determination of the silica concentration in ultrapure water and boiler feedwater.
The analyzer is designed for use in the following applications:
• Ultrapure water
• Boiler feedwater
• Steam and condensate analysis
• Reverse osmosis
• Desalination systems
Use of the device for any purpose other than that described, poses a threat to the safety of
people and of the entire measuring system and is therefore not permitted. The
manufacturer is not liable for damage caused by improper or non-designated use.
2.3 Occupational safety
As the user, you are responsible for complying with the following safety conditions:
• Installation guidelines
• Local standards and regulations
• Regulations for explosion protection
Electromagnetic compatibility
• The product has been tested for electromagnetic compatibility in accordance with the
applicable European standards for industrial applications.
• The electromagnetic compatibility indicated applies only to a product that has been
connected in accordance with these Operating Instructions.
2.4 Operational safety
Before commissioning the entire measuring point:
1. Verify that all connections are correct.
2. Ensure that electrical cables and hose connections are undamaged.
3. Do not operate damaged products, and protect them against unintentional operation.
4. Label damaged products as defective.

Basic safety instructions Liquiline System CA80SI
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During operation:
‣If faults cannot be rectified:
products must be taken out of service and protected against unintentional operation.
LCAUTION
Analyzer in operation and during maintenance activities
Risk of injury and infection from medium
‣Before you release any hoses, make sure that no actions, such as the pumping of
sample, are currently running or are due to start shortly.
‣Wear protective clothing, goggles and gloves or take other suitable measures to protect
yourself.
‣Wipe up any spilt reagent with a disposable tissue and rinse with clear water. Then dry
the cleaned areas with a cloth.
LCAUTION
Risk of injury from door stop mechanism
‣Always open the door fully to ensure the door stop engages properly.

Liquiline System CA80SI Basic safety instructions
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2.5 Product safety
2.5.1 State of the art
The product is designed to meet state-of-the-art safety requirements, has been tested, and
left the factory in a condition in which it is safe to operate. The relevant regulations and
European standards have been observed.
Devices connected to the analyzer must comply with the applicable safety standards.
2.5.2 IT security
We only provide a warranty if the device is installed and used as described in the
Operating Instructions. The device is equipped with security mechanisms to protect it
against any inadvertent changes to the device settings.
IT security measures in line with operators' security standards and designed to provide
additional protection for the device and device data transfer must be implemented by the
operators themselves.

Product description Liquiline System CA80SI
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3 Product description
3.1 Product design
1
8
6
2
3
4
7
5
5
A0035815
 1 Example of Liquiline System CA80SI 1-/2-channel version
1 Controller
2 Sample channel switching (2-channel version)
3 Valve manifold
4 Dispensers
5 Reagent bottle
6 Bottle tray
7 Peristaltic pump for dosing the standard
8 Cover (in front of overflow cuvette and photometer)
12
3
A0036004
 2 Example of Liquiline System CA80SI: sample channel switching, 6-channel version
1 Sensor-actuator-distributor
2 Panel
3 Sample inlets

Liquiline System CA80SI Product description
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3
1
2
A0036338
 3 Example of Liquiline System CA80SI 4-/6-channel version: Panel with pressure relief valve and filter
1 Pressure relief valve
2 Panel
3 Filter
3.2 Measuring system
A complete measuring system comprises:
• Liquiline System CA80 analyzerSI in the configuration ordered
• reagents and standard solution (to be ordered separately)
• Filter and pressure relief valve (enclosed separately with angle brackets in 1-/2-channel
version, mounted on panel in 4-/6-channel version)
• Panel for sample channel switching: 4 /6 sample inlets (4-/6-channel version)
SP1 SP2 D
FR
FI
F
Cu
W
A0036342
 4 1-/2-channel version: Measuring
system with upstream pressure
relief valves and filters
D Sample outlet
FI Filter
FR Flow controller
PL Pressure relief valve
SPx Sample inlet
F
D
SP4SP3SP2SP1 SP5 SP6
FR
FI
A0036343
 5 4-/6-channel version: Measuring system with upstream
pressure relief valves and filters on panel and external sample
channel switching on panel
D Sample outlet
F Flow sensor
FI Filter
FR Flow controller
PL Pressure relief valve
SPx Sample inlet

Product description Liquiline System CA80SI
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3.3 Equipment architecture
3.3.1 Slot and port assignment
The electronics configuration follows a modular concept:
• Several slots are provided for electronics modules.
• These slots are numbered consecutively in the housing. Slots 0 and 1 are always reserved
for the basic module.
• Each electronics module has one or more inputs and outputs or relays. Here they are all
collectively known as "ports".
• Ports are numbered consecutively per electronics module. The software recognizes the
ports automatically.
• Outputs and relays are named according to their function, e.g. "current output", and are
displayed with the slot and port numbers in ascending order.
Example:
"Current output 2:1" shown on the display means: slot 2 (e.g. AOR module) : port 1
(current output 1 of the AOR module)
• Inputs are assigned to measuring channels in the ascending order of "slot:port number"
Example:
– "SP1: shown on the display means:
Sampling point SP1 is assigned to analyzer measuring channel 1.
– "CH1: 1:1 pH glass" shown on the display for sensors means:
Channel 1 (CH1) is slot 1 (basic module) : port 1 (input 1) and a pH glass sensor is
connected here.

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3.3.2 Terminal diagram
The unique terminal name is derived from:
Slot no. : Port no. : Terminal
Example, NO contact of a relay
Device with 4 inputs for digital sensors, 4 current outputs and 4 relays
• Base module BASE-E (contains 2 sensor inputs, 2 current outputs)
• 2DS module (2 sensor inputs)
• 2AO module (2 current outputs)
• 4R module (4 relays)
1 2 34
43 42 41 43 42 41 43 42 41 43 42 41
Relay 1
Relay 2
Relay 3
Relay 4
Slot
Slot 4 Port 1 Pin 41
BASE-E 2DS 4R 2AO
A0025105
 6 Creating a terminal diagram using the example of the NO contact (terminal 41) of a relay

Incoming acceptance and product identification Liquiline System CA80SI
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4 Incoming acceptance and product
identification
4.1 Incoming acceptance
1. Verify that the packaging is undamaged.
 Notify the supplier of any damage to the packaging.
Keep the damaged packaging until the issue has been resolved.
2. Verify that the contents are undamaged.
 Notify the supplier of any damage to the delivery contents.
Keep the damaged goods until the issue has been resolved.
3. Check that the delivery is complete and nothing is missing.
 Compare the shipping documents with your order.
4. Pack the product for storage and transportation in such a way that it is protected
against impact and moisture.
 The original packaging offers the best protection.
Make sure to comply with the permitted ambient conditions.
If you have any questions, please contact your supplier or your local Sales Center.
NOTICE
Incorrect transportation can damage the analyzer
‣Always use a lifting truck or a fork-lift to transport the analyzer.
4.2 Product identification
4.2.1 Nameplate
Nameplates can be found:
• On the inside of the door on the bottom right, or on the front in the bottom right-hand
corner
• On the packaging (adhesive label, portrait format)
The nameplate provides you with the following information on your device:
• Manufacturer identification
• Order code
• Extended order code
• Serial number
• Firmware version
• Ambient and process conditions
• Input and output values
• Measuring range
• Activation codes
• Safety information and warnings
• Certificate information
• Approvals as per version ordered
‣Compare the information on the nameplate with the order.
4.2.2 Product identification
Product page
www.endress.com/ca80si

Liquiline System CA80SI Incoming acceptance and product identification
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Interpreting the order code
The order code and serial number of your product can be found in the following locations:
• On the nameplate
• In the delivery papers
Obtaining information on the product
1. Open the product website.
2. At the top of the page, select the link Product tools.
 An additional sidebar opens up.
3. Select Online Tools followed by Access device specific information.
 An additional window opens.
4. Enter the order code from the nameplate into the search field. Then select Show
details.
 Details of each feature (selected option) of the order code are displayed.
4.2.3 Manufacturer address
Endress+Hauser Conducta GmbH+Co. KG
Dieselstraße 24
D-70839 Gerlingen
4.3 Scope of delivery
Scope of delivery
• 1 analyzer in the version ordered with optional hardware
• 1 print version of Brief Operating Instructions in the language ordered
•Accessories (irrespective of number of channels):
– Wall holder unit
– Magnetic stir bar (for installation in cuvette)
– 10 ml dispenser with hose (for draining cuvette and sample channel)
– SD card (optional)
– Supply hose
– Sample outlet hose (for sample overflow)
– Outlet hose (for overflow at cuvette)
Accessories (dependent on number of channels):
1-channel 2-channel 4-channel 6-channel
Filters and
pressure relief
valves
1 filter, 1 pressure
relief valve with
angle bracket
2 filters, 2 pressure
relief valves with
angle brackets
Panel with 4 pre-
installed filters and 4
pre-installed pressure
relief valves
Panel with 6 pre-
installed filters and 6
pre-installed pressure
relief valves
Sample channel
switching
in analyzer in analyzer pre-installed on panel pre-installed on panel
‣If you have any queries:
Please contact your supplier or local sales center.

Certificates and approvals Liquiline System CA80SI
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5 Certificates and approvals
5.1  mark
The product meets the requirements of the harmonized European standards. As such, it
complies with the legal specifications of the EU directives. The manufacturer confirms
successful testing of the product by affixing to it the  mark.
5.2 cCSAus
The product meets the requirements as per "CLASS 2252 06 - Process Control Equipment"
and "CLASS 2252 86 - Process Control Equipment". It is tested to Canada and USA
standards: CAN/CSA-C22.2 No. 61010-1-12 UL Std. No. 61010-1 (3rd Edition).

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6 Installation
LCAUTION
Incorrect transportation can cause injury and damage the device
‣Always use a lifting truck or a fork-lift to transport the analyzer. Two people are
needed for the installation.
‣Lift the device by the recessed grips.
6.1 Installation conditions
The device can be installed in the following ways:
• Mounted on a wall
• Mounted on a base
6.1.1 Dimensions
530 (20.87)463 (18.23)
793 (31.22)
A0028820
 7 Liquiline System CA80 closed version, dimensions in mm (in)
417 (16.42)
793 (31.22)
530 (20.87)
A0030419
 8 Liquiline System CA80 open version, dimensions in mm (in)

Installation Liquiline System CA80SI
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930 (36.61)
654 (25.74)
1723 (67.83)
A0028821
 9 Liquiline System CA80 with base, dimensions in mm (in)
41
(1.61)
86 (3.39)
11 (0.43)
56
(2.20)
38
(1.50)
A0036334
 10 CA80SI 1-/2-channel version: Filter (left), pressure-reducing valve (right), dimensions in mm (in)
12
(0.47)
40 (1.57)
50 (1.97)
A0036665
 11 Dimensions of angle bracket for filter
--- Fasteners (2 x M5)

Liquiline System CA80SI Installation
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54 (2.13)
49 (1.93) 15,5
(0.61)
63,5 (2.5)
A0036664
 12 Dimensions of angle bracket for pressure relief valve
--- Fasteners (2 x M5)
196 (7.72)
355 (13.98)
8 (0.31)
95
(3.74)
335 (13.19)
176 (6.93)
A0036389
 13 CA80SI 4-/6-channel version: Panel with pressure-reducing valves and filters, dimensions in mm (in)
230 (9.06)
255 (10.04) 8 (0.31)
74
150
(5 91)
235
(9.25) (2.91)
A0036390
 14 CA80SI 4-/6-channel version: Panel with sample channel switching, dimensions in mm (in)
6.1.2 Installation site
Note the following when erecting the device:
1. If mounting on a wall, make sure that the wall has sufficient load-bearing capacity
and is fully perpendicular.
2. If mounting on a base, erect the device on a level surface.
3. Protect the device against additional heating (e.g. from a heating system).
4. Protect the device against mechanical vibrations.
5. Protect the device against corrosive gases, e.g. hydrogen sulfide (H2S) and chlorine
gases.
6. Ensure that sample outlet hose "D" and outlet hose "W" can drain freely , without any
siphoning effects.
7. Make sure air can circulate freely at the front of the housing.
8. Open analyzers (i.e. analyzers that are supplied without a door) may only be erected
in closed areas or in a protective cabinet or similar facility.

Installation Liquiline System CA80SI
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6.1.3 Spacing requirements when mounting
Spacing required for installing analyzer
≥330(12.99)
≥100 (3.94)
A0036774
 15 Minimum spacing required for mounting. Engineering unit
mm (in).
≤116 °
A0036775
 16 Maximum opening angle
Spacing required for installing wall-mount version
750 (29.53)
120 (4.72)
Ø 11 (0.43)
Ø 10.7 (0.42)
A0036779
 17 Holder unit dimensions. Engineering unit mm (in)
6.2 Mounting the analyzer on a wall
LCAUTION
Incorrect installation can cause injury and damage the device
‣If mounting on a wall, check that the analyzer is fully hooked into the wall holder unit
at the top and bottom, and secure the analyzer to the upper wall holder unit using the
securing screw.
The mounting materials required to secure the device to the wall are not supplied.
‣The mounting materials to secure the device to the wall (screws, wall plugs) must be
provided by the customer onsite.