IKA C 7000 User manual

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30 807 01 a ,.$WERKE
,.$®Calorimeter System C 7000
with Cooler C 7002
23(5$7,1*,16758&7,216 (1
86$
Reg.-No. 4343-01
Vers. 07 09.07
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IKA-WERKE C 7000 Ver. 07 09.07
&(±.21)250,7b76(5./b581* '(
Wir erklären in alleiniger Verantwortung, dass dieses Produkt den Bestimmungen
der Richtlinien 89 / 336 / EG und 2006 / 95 / EG entspricht und mit folgenden Nor-
men und normativen Dokumenten übereinstimmt: DIN EN IEC 61 010-1 und DIN EN
IEC 61 326-1.
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We declare under our sole responsibility that this product corresponds to the regula-
tions 89 / 336 / EEC and 2006 / 95 / EEC and conforms with the standards or stan-
dardized documents: DIN EN IEC 61 010-1 and DIN EN IEC 61 326-1.
'e&/$5$7,21'(&21)250,7e&( )5
Nous déclarons sous notre responsabilité que se prodiut est conforme aux régle-
mentations 89 / 336 / CEE et 2006 / 95 / CEE et en conformité avec les normes ou
documents normalisés suivant: DIN EN IEC 61 010-1 et DIN EN IEC 61 326-1.
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Declaramos por nuestra responsabilidad propia que este producto corresponde a
las directrices 89 / 336 / CEE y 2006 / 95 / CEE y que cumple las normas o docu-
mentos normativos siguientes: DIN EN IEC 61 010-1 y DIN EN IEC 61 326-1.
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Dichiariamo, assumendone la piena responsabilità, che il prodotto è conforme alle
seguenti direttive 89 / 336 / CCE e 2006 / 95 / CCE, in accordo ai seguenti regola-
menti e documenti: DIN EN IEC 61 010-1 e DIN EN IEC 61 326-1.
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IKA-WERKE C 7000 Ver. 07 09.07
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This symbol identifies information WKDWLVRIDEVROXWHLPSRUWDQFHWRHQVXUH\RXU
KHDOWKDQGVDIHW\ Failure to observe this information may be detrimental to your
health or may result in injuries.
This symbol identifies information WKDWLVRILPSRUWDQWWRHQVXUHSUREOHPIUHH
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damage to the calorimeter system.
This symbol identifies information that is important to ensure problem-free operation
of calorimetric measurements and for working with the calorimeter system. Failure to
observe this information may result in inaccurate measurement results.
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IKA-WERKE C 7000 Ver. 07 09.07
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2.1 Notes on using the operating instructions......................................... 2-1
2.2 Warranty......................................................................................... 2-1
2.3 Warranty and Liability...................................................................... 2-2
2.4 System Features ............................................................................. 2-3
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3.1 Transport and Storage Conditions.................................................... 3-1
3.2 Installation Location ........................................................................ 3-1
3.3 Unpacking....................................................................................... 3-2
3.4 Delivery Scope ............................................................................... 3-2
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4.1 Calorimeter C 7000 ......................................................................... 4-1
4.2 Cooler C 7002................................................................................. 4-2
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5.1 Determining the Gross Calorific Value.............................................. 5-1
5.2 Corrections ..................................................................................... 5-4
5.3 Complete Combustion ..................................................................... 5-5
5.4 Calibration ...................................................................................... 5-6
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6.1 Connecting the mains lead .............................................................. 6-1
6.2 Connecting peripherals.................................................................... 6-1
6.3 Switching the system on.................................................................. 6-2
6.4 Display and control elements........................................................... 6-2
6.5 Menu structure................................................................................ 6-4
6.6 Configuration of the C 7000 Calorimeter .......................................... 6-6
6.7 Examples of entries......................................................................... 6-8
6.8 Switching off ................................................................................. 6-11
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7.1 Recommendations for calibration..................................................... 7-2
7.2 Notes on samples............................................................................ 7-5
7.3 Preparation for measurement .......................................................... 7-7
7.4 Carrying out a measurement.......................................................... 7-13
7.5 Manual recording of the C value .................................................... 7-14
7.6 Cleaning and checking decomposition vessels ............................... 7-15
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8.1 Output and treatment of test data .................................................... 8-1
8.2 Evaluation of tests........................................................................... 8-4
8.3 Test simulation................................................................................ 8-6
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9.1 Maintenance ................................................................................... 9-1
9.2 Recommendations for cleaning........................................................ 9-1
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10.1 Messages from the C 7000 Calorimeter ......................................... 10-1
10.2 Fault without signal from Calorimeter............................................. 10-4
10.3 Signals from the C 7002 Cooler ..................................................... 10-4
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11.1 Accessories .................................................................................. 11-1
11.2 Consumables ................................................................................ 11-1
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12.1 Technical data for C 7000 Calorimeter........................................... 12-1
12.2 Technical data for C 7002 Cooler................................................... 12-1
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IKA-WERKE C 7000 Ver. 07 09.07
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In order to be able to use the appliance properly and safely, every user must first
read the operating instructions and observe the safety instructions contained
therein. Take care of these operating instructions and keep them in a place where
they can be accessed by everyone.
The C 7000 calorimeter system may only be used to determine the gross calorific
value of solid and liquid materials in accordance with DIN 51900 and ISO 1928. For
this purpose, use only original IKAdecomposition vessels C 7010 and C 7012. For
further details please see the operating instructions of the decomposition vessels
C 7010 and C 7012.
The maximum amount of energy input into the decomposition vessel must not ex-
ceed - (select the weight of the sample accordingly). The permissible oper-
ating pressure of EDU 0SD must not be exceeded. The maximum permissi-
ble operating temperature must not exceed &.
Do not fill the decomposition vessel too full of the sample. Only fill the decomposi-
tion vessel with oxygen up to a maximum pressure of EDU 0SD. Monitor the
adjusted pressure on the pressure reducer. Perform a check before every combus-
tion to ensure there are no leaks combustion (please observe the operating instruc-
tions of the decomposition vessels C 7010 and C 7012, chapter ”Leakage test”).
Many substances tend to combust in an explosive manner (for example because of
the formation of peroxide). This may cause the decomposition vessel to burst.
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Substances of which the combustion behavior is not known must be examined for
their combustion behavior before combustion in the decomposition vessel C 7010 or
C 7012 (danger of explosion). If you are burning XQNQRZQVDPSOHV, leave the room
or NHHSDVDIHGLVWDQFHEHWZHHQ you and the calorimeter.
Benzoic acid must only be burned in the form of pellets! Combustible dust and pow-
der must be compressed into pellets before combustion. Oven-dry dust and powder
such as wood chips, hay, straw, etc. burn in an explosive manner! They must be
moistened first! Readily combustible liquids with a low vapor pressure must not be
come in direct contact with the cotton thread (for example tetramethyl dihydrogen
disiloxan)!
In addition, toxic residues of combustion are possible in the form of gasses, ash or
precipitates on the inner wall of the decomposition vessel, for example.
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IKA-WERKE C 7000 Ver. 07 09.07
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When handling combustion samples, combustion residues and auxiliary materials,
the appropriate safety requirements must be observed. The following are examples
of substances that may cause dangers:
–corrosive
–easily flammable
–capable of exploding
–contaminated with bacteria
–toxic
When working with oxygen, observe the appropriate requirements.
Danger warning: As a compressed gas, oxygen promotes combustion, supports
combustion intensively and may react violently with combustible substances.
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Keep all gas lines and screw connections that carry oxygen free from grease.
Observe the accident prevention requirements applicable to the activity and the
work station.
Close the main valve on the oxygen supply when work is complete.
Only carry out maintenance work when the system is depressurised.
When using crucibles made of stainless steel, their condition should be carefully
checked after every experiment.
A reduction in the thickness of the material may cause the crucible to burn and may
damage the decomposition vessel. For reasons of safety, crucibles must not be
used any more after a maximum of 25 combustion procedures.
The decomposition vessel C 7010 and C 7012 are manufactured in accordance with
the regulation for pressure vessels 97/ 23/ EC. This can be recognized from the &(
V\PERO with the identifying number of the testing station named. The decomposition
vessel is a pressure device of Category III. The decomposition vessel has been
subjected to an EC prototype test. The CE declaration of conformity represents our
guarantee to you that this decomposition vessel complies with the pressure device
described in the EC prototype test certificate. The decomposition vessel has been
subjected to a pressure test at a test pressure of EDU and a leak test with oxy-
gen at 30 bar.
Decomposition vessels are H[SHULPHQWDXWRFODYHV and must be tested by a SUR
IHVVLRQDOO\WUDLQHGSHUVRQ each time before they are used.
An individual application is understood here to mean a series of experiments that
are performed under roughly the same conditions in terms of pressure and tem-
perature Experiment autoclaves must be operated in special chambers (C 7000).
The decomposition vessel must be subject to repeated tests (internal tests and
pressure tests) by a person with professional training. The intervals between tests
must be determined by the operator based on experience, operating manner and
the material used in the decomposition vessel.
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The WKUHDGLQJ on the body of the decomposition vessel and cap screw in particular
are subject to a high level of mechanical stress and must therefore be monitored
regularly for ZHDUDQGWHDU.
The condition of the seals must be checked for functionality must be ensured by
means of a test for leaks (please observe the Operating Instructions for the decom-
position vessel).
Pressure tests and service tasks on the decomposition vessel must only be per-
formed by persons with professional training.
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IKA-WERKE C 7000 Ver. 07 09.07
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A person with professional training as defined in these operating instructions is
someone
1. whose training, knowledge and experience gained through practical activities
ensures that that person will perform the tests in a proper manner.
2. who is sufficiently reliable
3. who is not subject to any instructions in terms of testing activity
4. who is equipped with suitable testing equipment if necessary
5. who can provide suitable proof demonstrating compliance with the requirements
listed in 1.
National regulations and laws for operating pressure containers must be observed!
Anyone who operates a pressure container must maintain it in proper condition,
must monitor it and perform necessary maintenance and repair tasks without delay,
and must take measures appropriate for the circumstances to ensure safety.
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GDQJHUWKRVHZRUNLQJZLWKLWRUWKLUGSDUWLHV You can obtain a copy of the pres-
sure vessel regulation from Carl Heymann Verlag or Beuth Verlag.
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Artisan Technology Group - Quality Instrumentation ... Guaranteed | (888) 88-SOURCE | www.artisantg.com

IKA-WERKE C 7000 Ver. 07 09.07
Artisan Technology Group - Quality Instrumentation ... Guaranteed | (888) 88-SOURCE | www.artisantg.com

IKA-WERKE C 7000 Ver. 07 09.07
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In this section you will learn how to make the most effective use of these Operating
Instructions so as to be able to work safely with the calorimeter system.
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Work through Sections 1 ... 10 in numerical order.
Section 3 "Transport, Storage, Installation Location" is particularly relevant to
system reliability and ensuring high accuracy of measurements. Section 4 describes
the system components and Section 5 contains the basic principles of calorimetry.
Once you have carried out the procedures described in Section 6 "Commissioning",
and Section 7 "Preparing and Carrying Out Measurements" the calorimeter is ready
for use.
In Section 8 the evaluation of calorific value measurements and the possibility of test
simulation are explained.
Section 9 gives important information on care and maintenance, and Section 10
explains the display messages and gives advice on troubleshooting and the
correction of simple problems.
Information on accessories, consumables, and the technical data for the unit are
given in Sections 11 and 12. Section 13 contains the index.
The figures c, d,eetc. in the following chapters indicate actions that must always
be carried out in the sequence given.
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In accordance with IKA warranty conditions, the warranty period is 12 months. For
claims under the warranty please contact your local dealer. You may also send the
machine direct to our works, enclosing the delivery invoice and giving reasons for
the claim. You will be liable for freight costs.
The warranty does not cover wearing parts, nor does it apply to faults resulting from
improper use or insufficient care and maintenance contrary to the instructions in this
operating manual.
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IKA-WERKE C 7000 Ver. 07 09.07
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Please read through these Operating Instructions attentively. IKAonly accepts
responsibility for the safety, reliability and performance of the device if:
•the unit has been used in accordance with the operating instructions;
•only persons authorised by the manufacturer have carried out maintenance or
repair work on the unit, and
•only original parts and original accessories have been used for repairs.
The calorimeter must only be opened by your Technical Service Department.
If servicing is required, we recommend that you take advantage of your Technical
Service Department.
Otherwise, please make yourself familiar with the relevant safety and accident
prevention regulations.
IKAaccepts no liability for damage or costs that arise due to accidents, misuse of
the unit, or unauthorised changes, repairs or modifications.
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IKA-WERKE C 7000 Ver. 07 09.07
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The C 7000 calorimeter is used for the routine determination of the gross calorific
value of solid and liquid substances. The system accessories ensure that it can be
individually adapted to laboratory tasks (see also Section 11).
The system has the following important features:
•patented double-drying measuring procedure;
•short measurement time, ca. 3 minutes for one determination;
•well over a hundred determinations per day and calorimeter are possible;
•automated measurement reduces routine tasks;
•fully-integrated, independent, microprocessor-controlled calorimeter;
•film key panel provides convenient operation and protection against laboratory
conditions;
•integrated fault detection with plain-text display;
•simple, well-proven operation;
•parallel port for direct connection of printer;
•memory for 100 tests;
•automatic acceptance of data from connected balance;
•calculation of calorific value under various conditions;
•four different calculation modes:
standard, with and without titration,
carbon, with and without titration;
•online data transfer to an external PC;
•automatic recognition of up to 8 decomposition vessels;
•maximum energy input from decomposition vessel: 30.000 J:
this corresponds to a temperature increase in the decomposition vessel
of about 25 K.
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IKA-WERKE C 7000 Ver. 07 09.07
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IKA-WERKE C 7000 Ver. 07 09.07
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During transport and storage, the system must be protected against mechanical
shock, vibration, dust deposits, and corrosive atmospheres. In addition, the relative
humidity should not exceed 80%.
In case of repair the device has to be cleaned and free from any materials which
may constitute a health hazard.
If you require servicing, return the appliance in its original packaging. Storage
packaging is not sufficient. Please also use suitable transport packaging.
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When installing the unit, observe the national and local regulations for the operation
of pressure vessels that apply at the site selected.
To ensure high accuracy of measurement, a constant ambient temperature is an
important precondition. For this reason, the chosen installation location should fulfil
the following conditions:
•not exposed to direct sunlight;
•no drafts (e.g. not beside a window, door or air-conditioning vent);
•sufficiently far from heating radiators and other heat sources;
•room temperature must be between 18 °C and 30 °C: to ensure good meas-
urement quality, there should be no variation in temperature;
•the system must be installed on a horizontal surface;
•If the C 7002 cooler is to be used, a water supply with a supply pressure of less
than 9 bar is required near the installation location, or a suitable cold water sup-
ply (e.g. IKAKV 500).
For operation of the system, a power supply corresponding to the typeplates of
system components must be available at the installation location. An oxygen supply
with a pressure gauge, which can supply 99.95% pure oxygen, quality 3.5 at a pres-
sure of 30 bar is also required. A shut-off valve for the oxygen supply must be in-
stalled. Observe the instructions on handling oxygen given in Section 1 "For your
safety”.
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IKA-WERKE C 7000 Ver. 07 09.07
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Please unpack system components carefully and check for any signs of damage. It
is important that any transport damage is noted during unpacking. If necessary, the
damage must be assessed immediately by the transport company (post, railway or
transport contractor).
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Main unit C 7000 including
-Mains cable
- Electrical fuses
- Benzoic acid C 723
- Carrying and venting handle
C 7010.8
for decomposition vessel
- Operating instruction
1x 1x
Decomposition vessel C 7010 1x -
Decomposition vessel C 7012 - 1x
Oxygen filling station C 48 1x 1x
Cooler C 7002 including
-Mains cable
- Electrical fuses
- Connection cable to calorimeter
- 2 Water hoses with quick-connect
couplings
1x 1x
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IKA-WERKE C 7000 Ver. 07 09.07
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1
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1 Display
2 Key pad
3 Control section
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1 Contrast control for display
2 Typeplate
3 Connection for cooler
C 7002
4 PC connection, RS 232
5 Balance connection RS 232
6 Printer connection,
Centronics
7 Fuses
8 Socket for mains cable
with main fuse
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IKA-WERKE C 7000 Ver. 07 09.07
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Commands and test parameters are entered in interactive mode using the key pad,
and entries can be seen in the display.
To enter parameters, there is a membrane-type key pad in the removable control
section of the calorimeter. There is also an illuminated two-line display with 40 char-
acters in each line. The display contrast can be individually adjusted using the con-
trol on the rear of the unit.
During a test, all phases of the measurement process are controlled and monitored,
and the display shows the current state of the system and test data.
In the measuring cell, calorimetric tests are carried out. They involve burning a sam-
ple of combustible material under precisely defined conditions. In the decomposition
vessel, there are four temperature sensors, which record its temperature.
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1 Display giving the
temperature differ-
ence from the meas-
uring cell in percent
2 Button for manually
opening and closing
the cooling jaws
3 Cooling jaws
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IKA-WERKE C 7000 Ver. 07 09.07
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The cooler is used to cool the decomposition vessel quickly after a test. For this
purpose, the cooler C 7002 is connected using the cable supplied to the calorimeter
C 7000 (see illustrations Cooler C 7002 Rear view, Position 2, and C 7000 Rear
view, Position 3). During the cooling operation, the decomposition vessel is cooled
to the temperature of the measuring cell. For accurate calibration and measurement,
this condition must be fulfilled.
For cooling, the decomposition vessel is placed between the cooling jaws. Peltier
elements are used for cooling. They are controlled completely automatically. Water
is employed for removal of heat. Internal controls ensure the water consumption is
kept especially low. In stand-by mode, the water is switched off automatically. The
cooler does not start ist pre-cooling phase until a main test has started.
Please see Section 6.2 "Connection of Peripherals" for more information about in-
stallation of the cooler.
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1 Mains connection
with main fuse
2 Connection to
C 7000
3 Cooling water con-
nections with quick-
connect couplings
☞
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