Endress+Hauser Analytik Jena PlasmaQuant MS Series User manual

Installation Guide
PlasmaQuant MS series
ICP MS

2
Analytik Jena GmbH
Konrad-Zuse-Str.1
07745 Jena Germany
Phone + 49 3641 / 77 70
Fax + 49 3641 / 77 92 79
Email [e-mail]
Analytik Jena GmbH
Konrad-Zuse-Str. 1
07745 Jena Germany
Phone + 49 3641 / 77-7407 (Hotline)
Email [e-mail]
http://www.analytik-jena.com
PlasmaQuant is in Germany a registered trademark of Analytik Jena GmbH.
Microsoft and Windows are registered trademarks of Microsoft Corp.
The identification with ® or TM is omitted in this manual.
01.17 (A)
Analytik Jena GmbH
© Copyright 2017, Analytik Jena GmbH
Manufacturer
Service
General information
Copyrights and
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Edition
Implementation of the
Documentation

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Contents
Installation Guide................................................................................................................. 1
PlasmaQuant MS series ICP MS......................................................................................... 1
1Safety Practices and Hazards ...................................................................................... 5
1.1 Safety Messages and Symbols........................................................................... 5
1.1.1 Warning Symbols ........................................................................................... 6
1.2 Color Coding........................................................................................................ 6
1.3 Information Symbols.......................................................................................... 7
1.4 General Safety Hazards...................................................................................... 7
1.4.1 Plasma ............................................................................................................ 7
1.4.2 Electricity ........................................................................................................ 8
1.4.3 Compressed Gas ............................................................................................. 9
1.4.4 Heat, Ozone, Vapors, and Fumes................................................................ 10
1.4.5 Hazardous Materials.................................................................................... 10
1.4.6 Radio Frequency Radiation ......................................................................... 11
1.4.7 Ultraviolet Radiation.................................................................................... 11
1.5 ICP-MS Equipment Caution Notices................................................................ 11
1.6 Regulatory Compliance .................................................................................... 12
1.6.1 Federal Communications Commission Advisory (U.S. Only)..................... 12
1.6.2 Spurious and Harmonic Radiation Compliance.......................................... 12
1.6.3 CE Compliance.............................................................................................. 13
1.7 Maintaining Records ........................................................................................ 13
2Introduction................................................................................................................ 14
3Installation Overview................................................................................................. 15
4System Interconnection............................................................................................. 16
5Unpacking the Instrument......................................................................................... 17
5.1Shipping Kit ...................................................................................................... 18
6Instrument Setup ....................................................................................................... 20
6.1 Installing the Rotary Pump.............................................................................. 20
6.2 Installing the Sample Introduction System..................................................... 21
6.2.1 Installation of the torch ............................................................................... 22
6.2.2 Installation of the nebulizer ........................................................................ 24
6.2.3 Installation of the spray chamber............................................................... 25
6.2.4 Installation of the transfer tube.................................................................. 26
6.2.5 Installation of the peristaltic pump tubing................................................. 28
6.2.6 Installation of the ASPQ 3300 autosampler .............................................. 31
6.2.7 Installation of the CETAC ASX-560 autosampler ...................................... 35

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6.3 Instrument Tool Box ........................................................................................ 47
6.4 Connecting the Argon...................................................................................... 47
6.5 Connecting the Mains Power .......................................................................... 48
6.5.1 Connecting the Instrument to Mains Power.............................................. 49
6.6 Connecting the Exhaust Ducting..................................................................... 51
6.7 Connecting the Leybold SV40 PFPE Rotary Pump......................................... 51
6.8 Installing the ASpect MS Software ................................................................. 53
6.9 Connecting the PC and Loading the USB Driver ............................................ 60
6.10 Enabling the Service Diagnostics Software .................................................... 63
6.11 Connecting the Water Cooling System ........................................................... 64
7Vacuum System Startup ............................................................................................ 68
8ASpect MS Software Setup ....................................................................................... 69
9Instrument Optimization .......................................................................................... 71
9.1 Starting and Warming Up the Instrument ..................................................... 71
9.2 Calibrations....................................................................................................... 73
9.3 Plasma Alignment............................................................................................ 74
9.4 Resolution and Trim ........................................................................................ 75
9.5 Mass Calibration .............................................................................................. 77
9.6 Setting the Detector Voltage........................................................................... 78
10 Method Optimization........................................................................................... 80
10.1 Typical Optimization Parameters ................................................................... 80
10.2 Optimizing the Ion Optics................................................................................ 83
10.2.1 How to Perform an Auto Optimization.................................................. 83
10.3 Method Optimization Troubleshooting.......................................................... 85
11 Performance ......................................................................................................... 86
11.1 Analytical Performance Specifications ........................................................... 86
11.1.1 Sensitivity................................................................................................. 86
11.1.2 Background.............................................................................................. 87
11.1.3 Oxide Ratio .............................................................................................. 87
11.1.4 Doubly-Charged Ratio............................................................................. 87
11.1.5 Precision (RSD %) ................................................................................... 88
11.1.6 Resolution................................................................................................ 88
11.1.7 iCRC Check ............................................................................................... 88
11.1.8 Boost Check ............................................................................................. 89
11.2 Test Solutions................................................................................................... 90
12 Appendix A - Routine Maintenance.................................................................... 92

PlasmaQuant MS Series Safety Practices and Hazards
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1Safety Practices and Hazards
The Analytik Jena PlasmaQuant MS (ICP-MS) and accessories have been carefully
designed so that when used properly it is an accurate, fast, flexible, and safe analytical
system. If the equipment is used in a manner not specified by the manufacturer, the
protection provided by the equipment may be impaired. Information on safety
practices appears throughout the documentation provided with all instruments and
accessories. Before using or servicing the instrument or accessories, you must
thoroughly read these safety practices. Observe all relevant safety practices at all
times.
Operation of the ICP-MS involves the use of compressed gases, high voltage radio
frequency energy, and hazardous materials, including corrosive fluids and flammable
liquids. When installed and used properly, the ICP-MS and its accessories provide an
accurate, fast, flexible, and safe analytical system. If you install and use the equipment
in a manner not specified by the manufacturer, the protection provided by the
equipment may be impaired. This can cause death or serious injury to personnel, or
severe damage to equipment and property.
This chapter describes the general and specific hazards you will encounter as you
interact with the ICP-MS and prescribes safety practices that can help protect you and
your equipment. Before installing and using the instrument or accessories, you must
thoroughly read these safety practices. Observe all relevant safety practices at all
times.
The safety practices described below are provided to help you operate the instrument
safely.
The spectrometer incorporates interlocks and covers which are designed to prevent
inadvertent contact with any of the potential hazards. It is good practice, however, to
develop safe working habits which do not depend upon the correct operation of the
interlocks for safe operation. It is essential that no interlock is bypassed, damaged, or
removed.
NOTE
The safety information presented in this manual is for the ICP-MS. Refer to the
manuals of the other Products/Accessories to ensure their safe and efficient
operation. Address any questions you have about the safe and proper use of the
instrument to Analytik Jena.
1.1 Safety Messages and Symbols
Safety messages and symbols are on the instrument, accessories, and throughout all
documentation. To prevent injury or equipment damage, pay attention to all labels,
lights, and symbols and read all messages.
The service manual uses the following symbols and signal words to indicate hazards or
instructions.

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WARNING
Indicates a potentially hazardous situation which might cause fatal or very serious
injuries (deformities).
CAUTION
Indicates a potentially hazardous situation which might cause light or minor
injuries.
NOTICE
Provides indications of potential material and environmental damage.
Notes (without symbol or signal word) are used to give advice or additional
information.
1.1.1 Warning Symbols
Certain specific hazards on and inside the ICP-MS cabinet are directly identified with
labels and multilingual warnings. Observe these precautions when working near the
relevant components.
WARNING
Yellow triangles are used on warnings attached to the instrument. When you see a
warning symbol, refer to the relevant safety information associated with that warning.
1.2 Color Coding
Indicator lights appearing on the ICP-MS instrument and accessories have been color-
coded to represent the status of the instrument or accessory:
Green: Indicates the instrument is in normal or standby condition.
Orange: Indicates a potential hazard is present.
Red: Warns of danger or an emergency.

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1.3 Information Symbols
The following symbols appear on the ICP-MS instrument to provide additional
information:
Symbol Information
I Power ON
O Power OFF
Fuse
Single Phase Alternating Current (AC)
Direct Current (DC)
Indicates that the product complies with the requirements of one or more EU
Directives
OUT position of a bi-stable push switch
IN position of a bi-stable push switch
Plasma ON
Plasma OFF
ON for part of equipment.
OFF for part of equipment
Indicates that the product complies with the requirements of the Federal
Communications Commission
Table 1-1 Information symbols
1.4 General Safety Hazards
This section describes the general hazards encountered with the ICP-MS instrument
and the safety practices to observe to avoid harm.
1.4.1 Plasma
The plasma is very hot (>5,000 °C) and radiates dangerous levels of radio-frequency
(RF) and ultraviolet (UV) energy. The work coils operate routinely at 2000 Root Mean
Square Voltage (VRMS) (and even higher at ignition) at 27.12 MHz. Exposure to the
RF and UV energy can cause severe skin damage and cataracts of the eyes, while close
contact with the operating plasma can result in severe heat burns to the skin and an
electrical discharge which can jump a considerable distance and cause death, severe
electric shock, or sub-surface skin burns which will not heal.

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Shielding around the plasma compartment is designed to reduce UV, visible, and RF
radiation to safe levels while still permitting easy access to the torch when
maintenance is required. The spectrometer has an interlock system which is designed
to extinguish the plasma if either plasma compartment latch is opened or if any of the
cooling water, argon gas, or air flow rates drop below the required minimum level.
DO NOT attempt to bypass the interlock system. Before opening the plasma
compartment lid, ALWAYS extinguish the plasma from the software.
The torch, interface, and their surroundings remain hot for several minutes after
the plasma is extinguished. Touching this area before it has cooled sufficiently may
result in burns. Allow the torch, cones, coils, interface, and torch compartment to
cool before carrying out any work in this area, or wear heat resistant gloves.
The plasma system has been carefully designed to operate safely and effectively
when using torches and related components which conform to Analytik Jena's
design criteria. Use of non-approved components in the plasma compartment may
render the system inoperative and/or hazardous. Use only torches and related
components supplied or authorized by Analytik Jena.
1.4.2 Electricity
The ICP-MS and some accessories contain electrical circuits, devices, and components
operating at dangerous voltages. Contact with these circuits, devices, and components
can cause death, serious injury, or painful electrical shock.
The safety classification is given as Class 1 (EN 61010-1).
Panels or covers which are fastened by screws on the instrument and accessories
must be opened ONLY by an Analytik Jena trained, qualified, or approved field
service engineer. Consult the documentation or product labels supplied with your
accessories, computer, and other peripherals to determine which parts are
operator-accessible.
Application of the wrong supply voltage can create a fire hazard and a potentially
serious shock hazard, and could seriously damage the ICP-MS system, accessories,
and any attached ancillary equipment. Consult the documentation supplied with
your accessories, computer, and other peripherals for their specific voltage
requirements.
Replace blown fuses with fuses of the size and rating as stipulated in the label
adjacent to the fuse holder or in the documentation. Always ensure that the
instrument is turned off and disconnected from the main supply before attempting
any fuse replacement.
NEVER use power cords with faulty or frayed insulation.
Never override or disable the instrument interlocks. Failure to observe this warning
could expose you to high voltage, resulting in death or serious injury.

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1.4.3 Compressed Gas
All compressed gases (other than air) can create a hazard if they leak into the
atmosphere. Even small leaks in gas supply systems can be dangerous. Any leak
(except that of air) can result in an oxygen deficient atmosphere which can cause
asphyxiation. The area in which cylinders are stored and the area surrounding the
instrument must be adequately ventilated to prevent such gas accumulations.
Gas cylinders must be stored and handled strictly in accordance with local safety
codes and regulations. Cylinders must be used and stored only in a vertical position
and secured to an immovable structure or a properly constructed cylinder stand.
Move cylinders only by securing them to a properly constructed cart.
Use only approved regulator and hose connectors (refer to the gas supplier’s
instructions). Keep gas cylinders cool and properly labeled. All cylinders are fitted
with a pressure relief device that will rupture and empty the cylinder if the internal
pressure is raised above the safe limit by excessive temperatures. Ensure that you
have the correct cylinder before connecting it to the instrument.
The principal gas used by the ICP-MS instrument is argon. The ONLY integrated
collision reaction cell (iCRC) gases to be used by the ICP-MS instrument are
hydrogen and helium. Some models (Elite) may be fitted for N2or O2connections
depending on options selected. Do NOT connect any other gases than those
specified to the correct inlet fittings. Use only instrument-grade gases with your
spectrometer.
If using cryogenic gases (for example, liquid argon), prevent severe burns by
wearing suitable protective clothing and gloves.
Never locate gas cylinders near an ignition source or in a position subjected to
direct heat.
The ICP-MS instruments may be used with hydrogen gas in the iCRC system for certain
applications. Hydrogen gas has several unique safety considerations which all
operators of this instrument should be aware of if this gas is being used.
It is combustible over a wide range of concentrations. At atmospheric pressure,
hydrogen is combustible at concentrations from 4% to 74.2% by volume.
Hydrogen has very low ignition energy, and burns with no luminous flame. A
hydrogen fire may be invisible under bright ambient light.
The temperature increases with gas expansion, and if it is allowed to expand
rapidly from high pressure, hydrogen gas can self-ignite.
There are numerous safety features designed into the ICP-MS instrument to prevent a
serious leak or accumulation of hydrogen gas, but appropriate safety precautions must
always be taken when working with any flammable pressurized gas. Your local
workplace safety authority may have additional requirements and regulations for the
use of combustible gases.
Always test for leaks after any changes to or maintenance of the hydrogen supply
system (e.g., changing the gas cylinder or reconnecting the supply line to the back
of the ICP-MS).
Hydrogen Safety

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In the event of a power failure, hydrogen gas may continue to flow from the supply
even if the ICP-MS is completely off. Always manually shut off the hydrogen gas
supply valve when there is no power to the ICP-MS.
Instead of using pressurized gas cylinders as a source of hydrogen, consider using a
hydrogen gas generator instead. These devices only produce the required amount of
hydrogen “on demand” while the ICP-MS is in operation, and there is no storage of
hydrogen gas when the system is not being used. Gas generators are available from
Analytik Jena as optional equipment, as well as from most major industrial/scientific
gas suppliers.
The ICP-MS is available with an accessory that introduces a small flow of oxygen into
the plasma for certain specific applications (the direct analysis of organic solvents). As
with hydrogen gas, oxygen has several specific safety precautions that end users
should be aware of.
Oxygen gas is a powerful oxidizer which will rapidly accelerate combustion of many
materials.
Oxygen cylinders should be handled with care because serious explosions have
resulted from contact between oil and high pressure oxygen. Oil or grease should
never be used on connections to an oxygen cylinder or gas line carrying oxygen.
Oxygen is incompatible with all flammable materials and should be stored
separately.
Never allow oil, greases, and other readily-combustible substances to come in
contact with oxygen cylinders, valves, regulators, and fittings.
1.4.4 Heat, Ozone, Vapors, and Fumes
Heat, ozone, vapors, and fumes generated by the plasma can be hazardous, and must
be extracted from the instrument by an exhaust system. Ensure that an exhaust
system of the appropriate type is fitted to the instrument. The system must be vented
to the outside air in accordance with local regulations, and never within the building.
Regularly check the exhaust system to ensure that it is functioning correctly.
Always switch the exhaust fan on BEFORE igniting the plasma.
1.4.5 Hazardous Materials
Use of the ICP-MS and accessories may involve materials, solvents, and solutions
which are flammable, corrosive, toxic, or otherwise hazardous. Careless, improper, or
unskilled use of such materials, solvents, and solutions can cause explosions, fire,
toxicity, and other hazards that can cause death, serious personal injury, and/or
damage to equipment and property.
Always ensure that laboratory safety practices governing the use, handling, and
disposal of hazardous materials are strictly observed. These safety practices should
include the wearing of Personal Protective Equipment (PPE), including appropriate
safety clothing and hand/eye protection.
Oxygen Safety